Ultrastable Au nanocatalyst supported on surface-modified TiO2 nanocrystals

The surfaces of TiO2 nanocrystals were modified with amorphous aluminum-oxide layers using a surface sol-gel process to control the interaction between supports and metal particles. Ultrastable Au nanocatalysts were prepared by the deposition of Au nanoparticles on the surface-modified TiO2 nanocrystals using a deposition-precipitation (DP) method. The TEM analysis showed that the Au nanoparticles on the surface-modified nanocrystal supports were highly stable with a sinter-resistant capability during high-temperature calcination. The HRTEM analysis revealed that the surface of the TiO2 nanocrystals was covered by an amorphous aluminum-oxide layer and the Au nanoparticles were primarily anchored to this amorphous layer. This amorphous aluminum-oxide layer played an extremely important role in the stabilization of the supported Au nanoparticles without affecting catalytic activities. The surface modification of nanocrystal supports highlights new opportunities in tailoring the stability and activity of supported nanocatalyst systems.     

东莞南城区能源厂组合式挡土墙失稳分析及处理措施

挡土墙病害和破坏形式主要有:滑移、倾覆、墙身开裂等,并且主要考虑一级或单级挡墙的破坏。本文通过对东莞南城区能源厂重叠式组合挡土墙失稳观察,提出其破坏形式除了一般挡土墙具有的常见病害———倾覆之外,还伴随有该类挡土墙特有的灾害———流土的发生,本文从定量、定性两方面对该失稳挡墙进行了具体分析,最后,根据分析结果对该挡墙提出了具有针对性的处理措施。通过对该挡土墙的分析总结,为今后该类挡土墙的设计、施工提出了极具借鉴价值的建议。     

High‐Efficiency Encapsulation of Pt Nanoparticles into the Channel of Carbon Nanotubes as an Enhanced Electrocatalyst for Methanol Oxidation

Pt‐based nanostructures serving as anode catalysts for the methanol oxidation reaction (MOR) have been widely studied for many years. Nevertheless, challenging issues such as poor reaction kinetics and the short‐term stability of the MOR are the main drawbacks of such catalysts and limit their applications. Herein, we have developed a facile approach to encapsulate Pt nanoparticles (NPs) inside the nanochannels of porous carbon nanotubes (CNTs; Pt‐in‐CNTs) as a new enhanced electrocatalytic material. The as‐prepared CNTs offer simultaneously ordered diffusion channels for ions and a confinement effect for the NPs, which both facilitate the promotion of catalytic kinetics and avoid the Ostwald ripening of Pt NPs, thus leading to high activity and durable cycle life as an anode catalyst for MOR. This work provides a new approach for enhancing the stability and activity by optimizing the structure of the catalyst, and the Pt‐in‐CNTs represent the most durable catalysts ever reported for MOR.     

结构关心截面内力、位移混合调整计算的影响矩阵法

在大跨径桥梁等结构的设计和施工控制中,经常要通过调整某些截面的位移或内力,来使另一些关心截面的内力或位移达到指定值。计算被调截面的位移或内力问题较复杂,本文提出这种计算的影响矩阵法,并就考虑结构几何非线性时的计算问题,提出探讨性建议。     

正负折射率交替一维光子晶体窄带梳状滤波器

利用传输矩阵法计算了正负折射率交替一维光子晶体的带隙特性。结果表明这种光子晶体具有宽而平坦的禁带,窄而尖锐的通带。这种带隙特性是受到布拉格散射、法布里-珀罗谐振和n-=0禁带共同影响的结果,通带位置决定于法布里-珀罗谐振。在理论分析基础上设计出密集波分复用用窄带梳状滤波器,给出信道间隔为0.8nm的梳状滤波器的仿真结果。仿真结果表明这种梳状滤波器具有信道间隔窄、禁带平坦、通带极窄的特点。信道间隔可以通过改变一维光子晶体单元周期光学厚度调节。     

具有旋量场的量子虫洞

本文利用Hawking-Page的边界条件讨论了具有费米场的量子虫洞,导出了相应的Wheeler-DeWitt方程,计算了虫洞波函数,由虫洞波函数的分析,发现虫洞在a=0处出现几率密度为零,虫洞基态最可几半径为Planck尺度.     

关于图B（m,n,p）的优美性

在［１］［２］中已证明“除去三种特殊情形，连结两个顶点的三条独立路所成简单图Ｂ（ｍ，ｎ，ｐ）是优美图”，并猜想：对除去的三种情形，Ｂ（ｍ，ｎ，ｐ）也是优美的。本文证实了上术猜想。这样一来，也就证明了［３］中的猜想：有－ｈ－链弦的圈是优美的（ｈ≥２）。     

WDM 光网络中一种新的备用路由算法

文章基于负载均衡和禁忌搜索提出一种新的备用路由算法,实现了优化解搜索及对链路负载方差和拥塞的优化.路由选择后,采用首次命中按长通道优先原则为各光通道分配波长.在环网和网状网静态业务模式下对不同路由算法进行了仿真,仿真结果表明,新算法能充分利用网络资源安排最佳路由,有效降低了对波长的需求.     

基于IQ调制器产生载波抑制单边带信号的偏置控制技术

为了延长信号传输距离、方便探测及降低噪声,并最大可能地保留信号能量,可通过移相法实现载波抑制单边带(SSB-CS)信号输出,采用导频法控制商用铌酸锂双平行(IQ)调制器可达到上述目标.实验结果表明:所提方法在2～18 GHz范围内,输出信号的载边比和边边比均大于20 dB;该方法能在不使用IQ调制器内置光电二极管(PD...