基于抛物方程的海陆环境信号时延与到达角估计

针对复杂海陆环境中的无线信号传播预测问题,研究了适用于抛物方程的信号时延与到达角估计方法。将自由空间中抛物方程轴向波前信号视为本地副本信号,然后利用信号的自相关特性,将接收信号与副本信号进行互相关运算,最后通过相关函数的峰值检索,得到脉冲信号在复杂环境中传播的附加时延。采用数值算例,验证了该方法的正确性和有效性。此外,采用多重信号分类算法,由抛物方程构建接收阵列的协方差矩阵,并对其进行特征值分解,然后利用信号子空间和噪声子空间的正交性,实现复杂环境中的信号到达角估计。仿真结果表明,相比于传统的平面波谱方法,该方法具有更高的多径分辨率。基于上述方法,并结合数字地图,在典型的海陆环境中进行了仿真实验,分析了蒸发波导对脉冲信号传播时延和到达角的影响。     

Ferroelectric behaviour of 30nm BaTiO3 ceramics prepared by high pressure assisted sintering

Dense nanocrystalline BaTiO3 ceramics with a homogeneous grain size of 30 nm was obtained by pressure assisted sintering. The ferroelectric behaviour of the ceramics was characterized by the dielectric peak at around 120 ℃, the P-E hysteresis loop and some ferroelectric domains. These experimental results indicate that the critical grain size for the disappearance of ferroelectricity in nanocrystalline BaTiO3 ceramics fabricated by pressure assisted sintering is below 30 nm. The ferroelectric property decreasing with decreasing grain size can be explained by the lowered tetragonality and the ＇dilution＇ effect of grain boundaries.     

双层钙钛矿La1.8Ca1.2Mn2O7磁性相关I-V非线性与电输运性质

采用传统固相反应法制备了双层钙钛矿结构锰氧化物La_1.8Ca_1.2Mn₂O₇陶瓷,并用X射线粉末衍射法,扫描电镜,HL5500PC Hall效应分析仪和综合物性测量系统(PPMS)对其磁、电性质进行了表征.结果表明:经过两次高温烧结可合成具有双层Sr₃Ti₂O₇型四方结构的La_1.8Ca_1.2Mn_2<     

Facile optical resolution of tert-butanethiosulfinate by molecular complexation with (R)-BINOL and study of chiral discrimination of the diastereomeric complexes

An important synthon, tert-butanethiosulfinate (2), has been effectively resolved by forming molecular complexes with (R)-2,2'-dihydroxy-1,1'-binaphthyl (BINOL, 3) in high enantioselectivity (>99 % ee). The present procedure represents the first example of the resolution of thiosulfinate. The mechanism of chiral discrimination is discussed in terms of molecular recognition based on IR and Xray analyses of the diastereomeric complexes during the resolution. In the less-soluble complex, (R)-3 and (R)-2 self-assembled as a linear supramolecule; however, in the more-soluble complex, (R)-3 and (S)-2 formed a simple bimolecular complex by one stronger hydrogen bond. Hydrogen bonding is the major driving force for effective resolution.     

宽调谐窄线宽脉冲钛宝石激光器

介绍了一种采用色散型布儒斯特棱镜扩束器调谐的脉冲钛宝石激光系统，通过泵浦光反馈泵浦，使转换效率提高了～８％；采用色散型布儒斯特棱镜扩束器加光栅（或平面镜）调谐，实现了窄线宽可调谐输出，输出激光能量为２３ｍＪ，转换效率达１９％．调谐范围为６８０～９１３ｎｍ，输出激光线宽小于０．０１ｎｍ。     

Wielandt-Hoffman定理在四元数体上的推广

将矩阵论中重要的Ｗｉｅｌａｎｄｔ－Ｈｏｆｆｍａｎ定理推广到实四元数体上，并给出它的几个应用。     

Effect of carbon nanotubes addition on electrochemical performance and thermal stability of Li4Ti5O12 anode in commercial LiMn2O4/Li4Ti5O12 full-cell

Li₄Ti₅O₁₂ (LTO)/carbon nanotubes (CNTs) composite material is synthesized based on a solid-state method by sand-milling, spray-drying and calcining at 850 ℃ under N₂ flow. The LTO/CNTs samples with 1 wt% and 3 wt% weight ratio of CNTs addition and the pristine LTO sample are prepared. The rate performance and the thermal stability of these samples are investigated based on LiMn₂O₄ (LMO)/LTO full-cell. The results show that theweight ratio of CNTs addition has distinct effect on LTO performances. The composite materials of LTO composited CNTs have better performance at high-rate due to the intercalation enhancement by conductive network of CNTs. At second, the overcharging temperature response of the cell's surface with 1 wt% CNTs addition is the lowest. The particle size distribution is measured and the most uniform particles are obtained with 1 wt% CNTs addition. This trend could explain that the mediumquantity of CNTs is optimal to improve the heat and mass transfer and prevent the problems of crystallite growing interference and aggregation during the calcination process.     

Impact of sugar stereochemistry on natural killer T cell stimulation by bacterial glycolipids

Natural killer T (NKT) cells recognize glycolipids produced by Sphingomonas bacteria, and these glycolipids contain C6-oxidized sugars, either glucuronic acid or galacturonic acid, linked to ceramides. Glycolipids with gluco stereochemistry are the most prevalent. Multiple studies have demonstrated that galactosylceramides are more potent stimulators of NKT cells than their glucose isomers. To determine if this stereoselectivity is retained in the context of the C6-oxidized sugars found in bacterial glycolipids, we prepared two sets of gluco and galacto-glycolipids oxidized at their C6 positions and compared their NKT stimulatory properties. In the context of carboxylic acid groups at C6, gluco stereochemistry gave the more potent responses. We also prepared bacterial glycolipids containing more complex ceramide groups to determine if these chains impact NKT cell responses.     

新疆农业生产要素转移问题初探

本文通过对新疆农业生产函数的分析。讨论了生产要素转移情况。得出:1 新疆的土地资源已经过度使用;2 劳动力资源潜力很大,其转移方向正从流向第三产业转向第二产业;3 新疆农业资金缺乏,部分农业资金被非农业侵占。     

金属有机框架(MOFs)材料在锂离子电池及锂金属电池电解液中的应用

总结了金属有机框架(MOFs)材料在锂离子电池电解液中的研究进展.通过归纳锂离子电池长期存在的一些缺陷,随后将MOFs材料作为离子筛、人造负极保护层、准固态电解质以及用来调节电解液构型,使得锂离子电池的性能得到显著提升.最后,基于MOFs材料本身的特性,还对MOFs材料在电化学储能领域中的后续应用进行了合理地前瞻性展望...