Silver-doped calcium phosphate nanopowders prepared by electrostatic spraying

Silver-doped calcium phosphate nanopowders were successfully prepared by the cost-effective electrostatic spray-pyrolysis process. The properties of the silver-doped nanopowder annealed at 500°C for 30 min were investigated through X-ray diffraction analysis, field emission scanning electron microscope, and Fourier transform infrared spectroscopy. The silver-doped nanopowders with 70–90 nm particle size showed an antibacterial performance against Escherichia coli.     

A momentum construction for circle-invariant Kähler metrics

Examples of Kähler metrics of constant scalar curvature are relatively scarce. Over the past two decades, several workers in geometry and physics have used symmetry reduction to construct complete Kähler metrics of constant scalar curvature by ODE methods. One fruitful idea--the ``Calabi ansatz'--is to begin with an Hermitian line bundle over a Kähler manifold, and to search for Kähler forms in some disk subbundle, where is the logarithm of the norm function and is a function of one variable.

Our main technical result (Theorem A) is the calculation of the scalar curvature for an arbitrary Kähler metric  arising from the Calabi ansatz. This suggests geometric hypotheses (which we call ``-constancy') to impose upon the base metric  and Hermitian structure  in order that the scalar curvature of  be specified by solving an ODE. We show that -constancy is ``necessary and sufficient for the Calabi ansatz to work' in the following sense. Under the assumption of -constancy, the disk bundle admits a one-parameter family of complete Kähler metrics of constant scalar curvature that restrict to on the zero section (Theorems B and D); an analogous result holds for the punctured disk bundle (Theorem C). A simple criterion determines when such a metric is Einstein. Conversely, in the absence of -constancy the Calabi ansatz yields at most one metric of constant scalar curvature, in either the disk bundle or the punctured disk bundle (Theorem E).

Many of the metrics constructed here seem to be new, including a complete, negative Einstein-Kähler metric on the disk subbundle of a stable vector bundle over a Riemann surface of genus at least two, and a complete, scalar-flat Kähler metric on  .

     

Reverse-phase HPLC separation of D-amygdalin and neoamygdalin and optimum conditions for inhibition of racemization of amygdalin

In boiling aqueous solution, D-amygdalin usually begins to convert into neoamygdalin in 3 min and more than 30% of the initial D-amygdalin is found as neoamygdalin after 30 min. In this report, we establish methods for simple HPLC analysis and the inhibition of D-amygdalin conversion. D-Amygdalin and its conversion product, neoamygdalin, were clearly separated on reverse-phase column chromatography by an optimized eluent of 10 mM sodium phosphate buffer (pH 3.8) containing 6% acetonitrile. Linearity for analyzing D-amygdalin and neoamygdalin was observed in the range from 0.05 to 0.5 mM. The detection limits for D-amygdalin and neoamygdalin were ca. 5 microM per injected amount. We found that D-amygdalin conversion was completely inhibited by adding 0.05% citric acid to the aqueous solution before boiling. To prevent the loss of pharmaceutical potency of Tonin, we applied this method to measure the conversion rate of D-amygdalin. We confirmed that D-amygdalin conversion in Tonin is effectively inhibited by acidic boiling solution with 0.1% citric acid.     

A micromachined silicon depth probe for multichannel neural recording

A process of making a new type of silicon depth-probe microelectrode array is described using a combination of plasma and wet etch. The plasma etch, which is done using a low temperature oxide (LTO) mask, enables probe thickness to be controlled over a range from 5 to 90 mu. Bending tests show that the probe's mechanical strength depends largely on shank thickness. More force can be applied to thicker shanks while thinner shanks are more flexible. One can then choose a thickness and corresponding mechanical strength using the process developed. The entire probe shaping process is performed only at low temperature, and thus is consistent with the standard CMOS fabrication. Using the probe in recording from rat's somatosensory cortex, we obtained four channel simultaneous recordings which showed clear independence among channels with a signal-to-noise ratio performance comparable with that obtained using other devices.     

Catalytic Intermolecular Pauson - Khand Reactions in Supercritical Ethylene

Ethylene is not only a substrate, but also a solvent: Catalytic intermolecular Pauson - Khand reactions of terminal alkynes were carried out in supercritical ethylene to provide 2-substituted cyclopentenones in moderate to high yields [Eq. (1)]. Under these conditions, even a low pressure of CO (5 atm) is sufficient for the reaction to take place.     

Analysis on motion of Earth’s center of mass observed with CHAMP mission

Geocenter motion (GCM) is one important topic for constructing and maintaining the terrestrial reference frame and its applications. GCM is studied from CHAMP with the multi-step approach in this paper. Geometric orbits of CHAMP in 2001–2006 are precisely determined with the kinematic method only from the satellite-borne GPS zero-difference data. Then a GCM time series is estimated from the precise kinematic orbits based on the theory of satellite dynamics to fit the CHAMP’s real geometric orbits. We compare the series with the geocenter series used in ITRF2005. Then the GCM series are analyzed with Fourier transform and wavelet transformation. The mean motions within 6 years in TX, TY and TZ directions are respectively 0.8 mm, 2.2 mm, and 7.9 mm. The trends of GCM in the three directions are 0.495 mm/a, −0.004 mm/a, and 1.309 mm/a, respectively. The long-term movement (2001–2006) indicates that the crustal figure is changing. The seasonal variations are the main component which may be excitated by the mass redistribution of Earth’s fluid layer, e.g. ocean, atmosphere and continental water. The inter-annual variations are also found in the GCM series measured with CHAMP. Supported by the International S&T Cooperation Program of China (Grant No. 2006DFA21980), the National Hi-tech R&D Program of China (Grant No. 2006AA12z303), the National Natural Science Foundation of China (Grant No. 40774009), and the Natural Science Foundation of Shandong Province, China (Grant No. Y2003E01)     

Cloning and functional characterization of a Caenorhabditis elegans muscarinic acetylcholine receptor

A cDNA clone encoding a muscarinic acetylcholine receptor (mAChR) has been isolated from the nematode Caenorhabditis elegans. The nematode mAChR, consisted of 585 amino acids, displays a high degree of amino acid sequence homology to other invertebrate and vertebrate mAChRs. Excluding a highly variable middle portion of the third intracellular loop, the C. elegans mAChR shares about 51% amino acid sequence identity with a Drosophila mAChR and 42-44% identity with human m1-m5 mAChR subtypes. Comparison of the cDNA sequence with the corresponding genomic sequence reveals that the C. elegans mAChR gene contains ten introns, eight of them in the coding region. Pharmacological profiles of the C. elegans mAChR expressed in Chinese hamster ovary (CHO) cells were shown to be similar to those of mammalian counterparts, indicating that ligand binding domains of the receptor have been conserved during evolution. When this cloned receptor was expressed in Xenopus oocytes, acetylcholine evoked a transient Cl- current. Furthermore, activation of the receptor with oxotremorine, acetylcholine or carbachol resulted in the stimulation of phosphatidylinositol metabolism in CHO cells, suggesting that the receptor is coupled to phospholipase C activation.     

A vertical-type a-Si:H back-to-back Schottky diode for high-speedcolour image sensor

A glass/ITO/a-Si:H/Cr photodiode with a voltage selectable spectral response was fabricated. The diode consists of two back-to-back Schottky junctions. As the bias at the Cr side changes from 1.5 to -1.5 V, three color peak responses can be found, i.e., 480 nm (blue) at V =0.5 V, 530 nm (green) at 1.5 V, and 620 nm (red) at -1.5 V. The basic idea consists of using the different bias voltages to change the location and depth of the photon collection region in which photons with different wavelengths are mainly collected. The photoresponse time was measured under a red LED light injection with an intensity of 150 μW. The typical photoresponse time for red is 60 ns under -1.5-V bias. These basic studies show that the vertical-type Cr/a-Si:H/ITO back-to-back Schottky diode is a good candidate for a high-speed colour image sensor     

Quasi-optical integrated antenna and receiver front end

A quasioptical receiver front end applicable to both microwave and millimeter-wave receiver arrays is presented. Two planar microwave integrated circuit (MIC) quasioptical receiver circuit designs that integrate a coupled slot antenna, a Schottky-diode balanced mixer, and a local oscillator on the same substrate are described. The even-mode/odd-mode characteristics of the coupled slotlines are used to achieve intrinsic RF/LO and RF/IF isolation. To demonstrate circuit feasibility, X-band scaled models of the circuit unit using a Gunn-diode oscillator on an Epsilam-10 substrate, and MESFET local oscillator on a R/T Duroid substrate were built and tested. Results of these tests are included     

A relaxed primal-dual path-following algorithm for linear programming

In this paper, we provide an easily satisfied relaxation condition for the primaldual interior path-following algorithm to solve linear programming problems. It is shown that the relaxed algorithm preserves the property of polynomial-time convergence. The computational results obtained by implementing two versions of the relaxed algorithm with slight modifications clearly demonstrate the potential in reducing computational efforts.Partially supported by the North Carolina Supercomputing Center, the 1993 Cray Research Award, and a National Science Council Research Grant of the Republic of China.