Anchoring Properties of Nematic Liquid Crystals Studied Using the Attenuated Total Reflection Method

By using the attenuated total reflection method associated with the excitation of surface plasmons, the tilt angle of the liquid crystal director and its gradient at the surface are measured in a planar nematic cell as a function of the applied voltage. The surface anchoring anisotropy δπ of the liquid crystal and the surface elastic constant k_s, are found to be δπ = 0.288 erg/cm and k_s, = 9·12 × 10^-11 erg, respectively, when the boundary condition suggested by Barbero et al is used. The theoretical and experimental values obtained with this boundary condition and that of Mada are discussed. The results show that the boundary condition proposed by Barbero et al is in better agreement with the experiment.     

Bipyridinophane‐containing conjugated polymers modulated with an intramolecular aromatic C?H/π interaction

Bipyridinophane–fluorene conjugated copolymers have been synthesized via Suzuki and Heck coupling reactions from 5,8‐dibromo‐2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane and suitable fluorene precursors. Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P7 ) exhibits large absorption and emission redshifts of 20 and 34 nm, respectively, with respect to its planar reference polymer Poly[2,7‐(9,9‐dihexylfluorene)‐co‐alt‐1,4‐(2,5‐dimethylbenzene)] ( P11 ), which bears the same polymer backbone as P7 . These spectral shifts originate from intramolecular aromatic C? H/π interactions, which are evidenced by ultraviolet–visible and ¹H NMR spectra as well as X‐ray single‐crystal structural analysis. However, the effect of the intramolecular aromatic C? H/π interactions on the spectral shift in poly[9,9‐dihexylfluorene‐2,7‐yleneethynylene‐co‐alt‐5,8‐(2,11‐dithia[3]paracyclo[3](4,4′)‐2,2′‐bipyridinophane)] ( P10 ) is much weaker. Most interestingly, the quenching behaviors of these two conjugated polymers are largely dependent on the polymer backbone. For example, the fluorescence of P7 is efficiently quenched by Cu²⁺, Co²⁺, Ni²⁺, Zn²⁺, Mn²⁺, and Ag⁺ ions. In contrast, only Cu²⁺, Co²⁺, and Ni²⁺ ions can partially quench the fluorescence of P10 , but much less efficiently than the fluorescence of P7 . The static Stern–Volmer quenching constants of Cu²⁺, Co²⁺, and Ni²⁺ ions toward P7 are of the order of 10⁶ M^?1, being 1300, 2500, and 37,300 times larger than those of P10 , respectively. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 4154–4164, 2006     

VO2-Based Infrared Microbolometer Array

V0₂-based thin film materials on silicon substrates are fabricated by ion beam sputtering and a post-annealing which is different from the conventional fabricating method. An infrared linear microbolometer array with 128 pixels is prepared using as-deposited vanadium dioxide thin films. Optical and electrical properties for V0₂-based microbolometer array are tested.     

An experimentally verified hybrid Cassie-Mayr electric arc modelfor power electronics simulations

This paper presents an electric arc model that can approximately represent both the static and dynamic characteristics of an arc load controlled by a power electronic circuit. The proposed model was developed from the combination and modifications of the classical Cassie and Mayr equations. The model equations have been expressed in a form suitable for incorporation into circuit simulators employing the nodal analysis method of equation solving. The model has been test-implemented in the Saber circuit simulator. Simulated and experimental results appear to be in good agreement     

IEEE standard 802.16: a technical overview of theWirelessMANTM air interface for broadband wirelessaccess

The broadband wireless access industry, which provides high-rate network connections to stationary sites, has matured to the point at which it now has a standard for second-generation wireless metropolitan area networks. The IEEE standard 802.16, with its WirelessMAN^TM air interface, sets the stage for widespread and effective deployments worldwide. This article overviews the technical medium access control and physical layer features of this new standard     

Glass transitions in hydrogen-bonded polymer complexes

Mutual precipitates of poly (N, N-dimethyl acrylamide) and poly (4-hydroxystyrene) were collected from dioxane, methanol, or acetone. The glass transition (T_g) temperatures of the precipitates are higher than the weight-average values. Clear films cast from dimethylformamide solutions have lower T_g values. Complexation also occurred between poly (ethyl oxazoline) and poly (4-hydroxystyrene) in dioxane and between poly (vinyl pyrrolidone) and poly (4-hydroxystyrene) in methanol. Again, the glass transition temperatures of the precipitates are higher than the values for the blend films. The ΔC_p values associated with the glass transitions of the complexes are smaller than those of the blends having the same compositions. Negative excess heat capacities of mixing have been observed for several precipitates.     

动态聚焦电子枪的模拟与实验研究

动态聚焦技术是为了满足大屏幕高分辨率彩色显像管及高分辨率彩色显示管的发展需求而产生的一项新技术。在本文中，作者首先提出了一种动态聚焦电子枪结构，进行了数值计算与分析，制作了动态聚焦电子枪并装管实验。通过对实验样管的测试与分析。证实该枪性能良好，动态聚集效果明显。     

Nb2O5掺杂对ZnO压敏电阻器电性能的影响

本文研究了Ｎｂ＿２Ｏ＿５掺杂以及Ｎｂ＿２Ｏ＿５与ＺｎＯ煅烧对ＺｎＯ压敏电阻器电性能的影响。实验表明，Ｎｂ＿２Ｏ＿５的掺入使压敏电场减少，当Ｎｂ＿２Ｏ＿５含量为０．１％ｍｏｌ时，其压敏电场最小．非线性系数最大。煅烧温度越高，压敏电场越高，非线性系数越大。     

一种简易可靠的射频激光调制器

采用ＰＩＮ电调衰减器、ＴＬ４９４等元件组成了射频（ＲＦ）大功率ＣＯ２激光调制器，调制频率、占空比和调制度单独可调。给出了电路的工作原理和测试结果。     

关于衍射的本性

本文对惠更斯－菲涅耳原理和基尔霍夫衍射积分的概念作了本质上的修改。它比较符合物理实际，并有应用价值。