引入离子基团改善聚苯乙烯和热致液晶聚合物的相容性Ⅰ.热性能和形态

ＤＳＣ和ＳＥＭ研究结果表明聚苯乙烯与一种热致液晶聚合物完全不相容。共混体系具有与组分无关的Ｔｇ，并且表现出明显的两相结构。将ＰＳ进行化学改性，随中和盐离子的变化有；酸式，Ｌｉ，Ｎａ，Ｚｎ和Ｍｎ盐五种形式。用ＤＳＣ和ＳＥＭ对ＬＣＰ与ＳＰＳ共混物的热性能和形态进行了分析和表征。     

4，4＇－偶氮二［4－氰基戊酰（对－二甲氨基）苯胺］作为引发剂的嵌段共聚物合成

his paper describes a new polyfimctional inihator, 4,4'-azobis[4-cyanopentanoyl (p-dimethylandno)anilide] (ACPDA), for the the radical polymerization. It was obtained by the rcaction of 4,4'-azobis(4-cyanopentanoyl chloride) with p-amino-N, N-dimethylaniline' ACPDA contains two reaction centres with different reactvities that are azo-group and N, N-dimethylaniline-group. By the controlled different conditions this initator can be utilized to make block polymers.     

Synthesis of novel mesoporous silica spheres with starburst pore canal structure

Novel spherical mesoporous silica materials with uniform diameters and starburst mesopore structures were synthesized by a simple one-step procedure with ethanol as the co-solvent in dilute aqueous solution and their formation mechanism was proposed. The arrangement of the pore canal and the diameter of the sphere could be tailored by altering the concentration of ethanol.     

Synthesis of polypiperazine-amide thin-film membrane on PPESK hollow fiber UF membrane

A new interfacial polymerization (IP) procedure is developed in order to synthesize polypiperazine-amide thin-film membrane on the inner surface of poly(phthalazinone ether sulfone ketone) (PPESK) hollow fiber ultrafiltration (UF) membrane.A hollow fiber composite membrane with good performance was prepared and studied by FT-IR and scanning electron microscopy.     

Fe-Ni-B-O纳米合金的合成及其催化制氢性能的研究

Preparation and catalytic performance of Fe-Ni-B-O nano-alloy having crystal-palpus structure has been studied. Black powder was synthesized by reducing mixture solution of Fe²⁺, Ni²⁺ with KBH₄ as reducing agent and polyethylene glycol as dispersant. Fe-Ni-B-O nano-alloy of crystal-palpus structure was obtained after hydrogen reduction of black powder. TEM shows that crystal-palpus length is 200～400 nm, diameter is 2～4 nm. The analytic results indicate that the total content of Fe and Ni is 86.6%, B is 5.08%. The alloy exhibits excellent catalytic performance. Hydrogen generation rate can approach 100% especially when pH is 8.     

关于meso—四苯基卟啉在冰醋酸中的存在形式

前言卟啉在生物化学、分析化学、药物化学等领域有着广泛研究和重要应用［１～３］。近年来虽然对卟啉类化合物的研究报道很多［４～６］，但对卟啉在酸性介质中的研究很少。较早期的研究工作认为卟啉类化合物在酸性介质中仅以其二酸形式存在［７］。本文实验结果显示ｍｅ...     

Facile cyclic ammonium salt with the smallest size for high performance electric double layer capacitors

A novel cyclic ammonium salt, N,N-dimethylpyrrolidinium tetrafluoroborate (P₁₁-BF₄), was successfully synthesized for the first time. The smallest cyclic structure of P₁₁-BF₄ induced high solubility and conductivity in PC, which can easier enter the micropores of activated carbon and occupy more surface area during charge/discharge process.     

甲基丙烯酸甲酯悬浮聚合实验教学的改进

选用氢氧化镁为分散剂,甲基丙烯酸甲酯(MMA)为单体,进行悬浮聚合反应,研究了分散剂用量、引发剂用量、水和单体比、搅拌速度、反应温度及反应时间对聚合物珠粒大小、均匀程度和产率的影响。结果表明:与目前高分子实验教材普遍选用的以聚乙烯醇(PVA)为分散剂的悬浮聚合反应相比,以氢氧化镁为分散剂,具有操作简单、聚合时间短、体系稳定性高等优点,可代替原有的悬浮聚合反应实验,作为高分子化学实验的教学课程内容。     

ZnxCd1-xS∶Ag纳米晶的合成及其光学性质研究

以巯基丙酸(MPA)为稳定剂, 利用共沉淀法制备了水溶性的Ag掺杂的ZnxCd1-xS合金型纳米晶. Ag掺杂后ZnxCd1-xS纳米晶产生新的发射峰, 并且发光效率得到了有效提高. 通过改变纳米粒子中Zn/Cd比例可有效地调控ZnxCd1-xS∶Ag纳米晶的吸收带隙宽度, 同时可以在425～603 nm之间实现对ZnxCd1-xS∶Ag纳米晶发射峰位的连续调控.     

沐浴海绵Spongia zimocca aubspecles irregularia(Lendenfeld)中的含氮化合物

从沐浴海绵Spongia zimocca aubspecles irregularia(Lendenfeld)分离和处理得到3种含氮化合物,通过波谱法鉴定化学结构,化合物1为新的神经酰胺N-2-(1,3-二羟基-十五烷基)-2′,20′-二十一酰胺,2为神经酰胺(E)-N-2-(1,3-二羟基-4-十八烯基)-十六酰胺,3为醋酸胍.