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81.
In the course of searching bioactive natural products from the plant genus Aglaia, we selected two species, A. cordata and A. testicularis, for further chemical study. Totally twenty natural compounds were obtained and structurally elucidated with which eleven of them were discovered for the first time. Among these compounds, lignans, rocaglamides,aglains and bisamides were the main constituents of the two plant species. The results from a bioactive screening indicated that some of the lignans possess potent antibacterial and antifungal activity. 相似文献
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Jian Ping LI* Ping LIU Yu Lu WANG College of Chemistry & Environmental Science Henan Normal University Xinxiang Key Laboratory of Environmental Science Technology of High Education of Henan Province Xinxiang 《中国化学快报》2003,14(7)
Azo compounds are widely utilized as analytic reagents and dyes1, they can also be used in material of non-linear optics, material of optics information storing in laser disks, and dyes with oil solubility in photochromy in modern technology2. Recently, many noteworthy studies have shown that some azo compounds possess excellent optical memory and photoelectric properties3,4. For example, polymer scaffolds bearing azobenzene-potential are useful for optical information storage, azo-dye doped… 相似文献
85.
Propargylic alcohols are versatile precursors to many organic molecules including natural products and pharmaceutical compounds.[1] In our continuing interest in the development of practical methods for synthesis of ferrocene derivatives, we decided to investigate the efficiencies of ferrocenylacetylene addition to aromatic aldehydes under t-BuOKcatalyzed condition.[2] Interestingly, we found that the usually reliable coupling reaction between terminal alkyne of type 1 and aromatic aldehydes of type 2 does not furnish the expected propargylic alcohols, but that the isomeric aryl enones 3are found in high yield and very short reaction time (10~20 min). This provided a promising protocol for preparation of ferrocenyl chalcones in a practical, economical and mild sense compared with the traditional method. To the best of our knowledge, this unusual reaction was first observed for the addition of ferrocenylacetylene to aldehyde in a base-catalyzed manner (Eq. 1). 相似文献
86.
MEN Xiu-Qin WANG Jin-Xian SHI Xiao-Ning WANG Ke-Hu 《有机化学》2003,23(Z1):307-307
Carbon-carbon double bond-forming reactions have always been great importance in organic synthesis. Manymethods have been described for C =C bond formation. We[1] have reported the new method of C =C bond formation of nickel catalyzed organozinc with aromatic aldehydes in the presence of Me3SiC1. 相似文献
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88.
Information is the core of Air traffic con-trol system (ATCS).In this paper,objective information theory is extended to depict,model and measure the information exemplified in ATCS.The sextuple model is presented with information ontology,state occurrence time,state set,carrier,reflection time,and reflection set.The metric system is given to quantitively measure the information with extensity,detailedness,continuity,richness,containability,delay,pervasiveness,authenticity,and adaptability.The results show that the proposed method is potential to find out actual indexes in ATCS for flight safety. 相似文献
89.
为了解决光学材料多功能耦合与集成的光谱诉求及其材料设计冲突难题,本文提出一种基于[TiAlN/Ag]2/TiAlN序构复合薄膜开展可见光透射诱导与红外辐射抑制的协同设计方法,诠释序构薄膜材料多功能耦合的新原理与新机制,并对其光学兼容性能测试表征。研究表明,构筑的[TiAlN(厚度30 nm)/Ag(厚度15 nm)]2/TiAlN(厚度30 nm)序构复合薄膜具备带通状选择性透射与中远红外低辐射的光学特性,可较好实现透视、遮阳、低辐射控温与红外隐身多功能兼容效果,在军用车辆、绿色建筑等特种玻璃的辐射控温与红外隐身领域有应用潜力。 相似文献
90.
铌酸锂(LN)单晶薄膜具有较高的机电耦合系数(k2 eff>30%),其水平剪切(SH)声学模式常被应用于开发具有大机电耦合系数的薄膜声学谐振器和超宽带滤波器。但LN 的频率温度系数较大(TCF > -50×10-6/℃),这不仅会降低滤波器的可用有效带宽,同时也会限制器件的功率处理能力。采用3D周期有限元模型对基于X 切LN/SiO2/Si结构SH 声表面波(SH-SAW)谐振器进行了优化研究。研究结果表明,当SH-SAW 传播角ψ=-10°~-20°、LN和SiO2 膜厚分别为hLN=0.1λ 和hSiO2 =0.2λ(λ 为叉指换能器周期)、铝电极金属化率η=0.4、电极相对厚度hAl/λ=5%~10%时,SH-SAW 谐振器的 k2 eff 约为30%,且其TCF<-20×10-6/℃,有望用于开发新一代的低温漂、超宽带5G SAW 滤波器。 相似文献