An efficient Approach to Modify the Catalyst Activity for the Hydrogenation of Nitrobenzene

Transition metal complexes have been used extensively for the hydrogenation in homogeneous system probably due to their high catalytic selectivities under mild operating conditions. In order to improve the homogeneous catalyst system, some studies on the homogeneous or soluble polymer-supported bimetallic catalysts have been recently carried out and enhanced activity, better selectivity were observed in selective hydrogenation, hydrodehalogenation, carbonylation, hydroformylation and regioselec…     

齿形中心扩锥对旋流燃烧器气固流动影响的PDA试验研究

1前言旋流燃烧器依靠高温回流区做为稳定的热源，使煤粉气流及时着火并稳定燃烧，燃烧器单独组织燃烧，不互相影响，燃烧器区域的气固流动特性决定了燃烧器的性能。燃烧器的喷口结构对其气因流动特性有重要影响山。本文提出了齿形中心扩锥结构（如图l所示）。2实验方法及结果分析试验采用三维激光粒子动态分析仪（简称三维PDA），实验台系统主要由送风机、吸风机、给粉机、燃烧器模型、试验段、旋风分离器等组成，试验段为一竖直放置的筒体，直径为4800mm，燃烧器模型安装在简体上部中心位置，最外层扩口端部与筒体内壁平齐，沿射流流动方…     

注入型人工晶状体材料的研究进展

注入型人工晶状体具有正常晶状体位置和生理调节功能的双重特性,因此,对其进行合成与制备已成为世界各国科学家研究的热点之一.本文介绍了国内外有关注入型人工晶状体材料的研究进展,重点阐述了硅酮聚合物、光聚合物、聚氨酯共聚物、巯基聚合物这四类注入型人工晶状体材料的结构、基本性能和医用特性,对每种材料的优缺点进行了评述.     

扇的倍图的邻点可区别边色数

设G(V,E)是阶数至少是3的简单连通图,若f是图G的k-正常边染色,使得对任意的uv∈E(G),C(u)≠C(v),那么称f是图G的k-邻点可区别边染色(k-ASEC),其中C(u)={f(uw)│uw∈E(G)},而χa′s(G)=min{k│存在G的一个k-ASEC},称为G的邻点可区别边色数.本文给出扇的倍图D(Fm)的邻点可区别边色数.     

逆向选择下的委托—代理模型分析

分别讨论了在对称信息和逆向选择下,保险代理人的类型是离散和连续情形时激励合同设计问题,得出如下主要结论:保险人在对称信息和逆向选择下要求最高效率的代理人的努力水平相同,且在逆向选择下的支付更多,然而对其他类型的代理人而言,在逆向选择下要求的努力水平和所支付比在对称信息条件下都要少些.     

Molecular Imprinting Fibrous Membranes of Poly（ acrylonitrile-co-acrylic acid） Prepared by Electrospinning

Introduction Overthepastfewdecades,molecularimprinting hasbeendescribedasatechnologyforpreparing“mo leculardoors”whichcanbematchedto“template keys”.Ithasbeenfoundtobeasimpleandeffective approachtointroducespecificrecognitionsitesintosyn theticpolymers…     

Effective VTeO/SBA-15 Catalyst Prepared by Precursor Method for the Selective Oxidation of Propane to Acrolein

Precursor decomposition was used for the preparation of VTeO/SBA-15 catalyst for the selective oxidation of propane to acrolein. The catalyst shows a better performance compared with those prepared by conventional impregnant method. A yield of 9.3% of acrolein was achieved with 2% V loadings at 500 ℃. XRD, N2-adsorption, H2-TPR, Py-IR and XPS measurements were used to unclose the relationship between the structure and performance of the catalyst.     

限域于SBA-15孔道内的活性相聚集形态

针对Pd/SBA-15和MoO3/SBA-15两类催化剂样品,使用N2物理吸附手段对比研究了限域于介孔SBA-15分子筛孔道内活性相Pd与MoO3的聚集形态.结果表明,金属Pd以颗粒状形态分布在SBA-15分子筛孔道内,氧化物MoO3则以层状形态存在.并用高分辨透射电镜验证了此分析结果.     

不对称合成中的手性膦(磷)酸酯(酰胺)催化剂

讨论了手性膦(磷)酰胺及膦(磷)酸酯催化剂在不对称烷基化、不对称缩合、不对称氢化、不对称氰硅化等反应中应用的最新研究进展。参考文献48篇。