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61.
Essential oil from the aerial part of Plectranthus marrubatus J. K. Morton (Lamiaceae), obtained by hydrodistillation was analyzed by gas chromatography/mass spectrometry (GC/MS) and evaluated for antimicrobial and free radical scavenging activities. Twenty-four compounds representing 99% of the total oil were identified. The major constituents were thymol, p-cymene and gamma-terpinene. The oil was tested against 21 bacterial and 4 fungal strains using the disc diffusion method and found to be active against a broad spectrum of pathogens including Gram-positive and Gram-negative bacteria as well as some fungal strains. The minimum inhibitory concentrations (MICs) of the oil against the bacterial strains tested ranged from 10 to 800 microg/mL, and from 400 to 800 microg/mL against the fungal strains employed. The in vitro antioxidant activity was assessed using 2,2-diphenyl-l-picrylhydrazil (DPPH) and showed a low EC50 value of 0.15 microl/mL. The study provides evidence for the broad-spectrum antimicrobial and antioxidant effect of Plectranthus marrubatus essential oil, and a possible explanation for its traditional use in the treatment of cold, fever, stomach disorder, diarrhea and as a skin cleaner. 相似文献
62.
We present nonlinear phenomena produced from spoof surface plasmon polariton (SSPP) modes. Below the THz spectrum, artificially textured conducting metastructures on a subwavelength scale generate surface-bound modes and are called SSPP modes, similar to surface plasmon polariton (SPP) modes in the visible spectrum. Even though nonlinear effects in the THz domain are negligible, subwavelength metallic gap structures are ideal candidates to realize nonlinear behavior in the THz domain because of slow light propagation, strong electromagnetic confinement, and a high quality factor Q. In particular, when SSPP structures are combined with Kerr nonlinear materials, nonlinear-bistable curves can be observed below the THz spectrum. 相似文献
63.
Quantitative roughness and microstructural analysis of as-deposited and swift heavy ion (SHI) (107 MeV Ag and 58 MeV Ni) irradiated 10 and 20 nm thick Au films were performed by atomic force microscopy (AFM). Power spectral density (PSD) analysis was done from the AFM images. The energies chosen for the two different ions eliminated the velocity effect of SHI in materials modification. The rms roughness estimated from the AFM data did not show either monotonic increase or decrease with ion fluences. Instead, it increased at low fluences and decreased at high fluences for 20 nm thick film. In 10 nm film, the roughness first increased with ion fluence, then decreased and again increased at higher fluences. Though the 10 and 20 nm films exhibited very different patterns of rms roughness variation with ion fluence, the pattern of variation in both cases was identical for Ni and Ag beams. The PSD analysis for both 10 and 20 nm films (pristine and irradiated) showed similar variation of low frequency roughness with ion fluence as that of the rms roughness. In the high frequency regime, PSD analysis suggests that surface morphology of the irradiated samples is governed by the combined effect of evaporation-recondensation and diffusion dominated processes. 相似文献
64.
In this paper, we introduce the possibilistic mean value and variance of continuous distribution, rather than probability distributions. We propose a multi-objective Portfolio based model and added another entropy objective function to generate a well diversified asset portfolio within optimal asset allocation. For quantifying any potential return and risk, portfolio liquidity is taken into account and a multi-objective non-linear programming model for portfolio rebalancing with transaction cost is proposed. The models are illustrated with numerical examples. 相似文献
65.
D. Sen J. Bahadur S. Mazumder 《The European Physical Journal B - Condensed Matter and Complex Systems》2009,71(1):75-84
Present work involves extraction of single-scattering profile from
small-angle scattering data, affected by multiple scattering, using an
existing model-independent algorithm [Mazumder et al., Physica B 241–243,
1222 (1998), Mazumder et al., J. Appl. Crystallogr. 36, 840 (2003)]. It is shown that
implementation of the algorithm becomes effective by representing the
multiple scattering profiles in terms of a set of basis function whose form
of Hankel transformed pair is known analytically. In the present paper, the
methodology has been presented by introducing a Gaussian basis set and has
been tested for various simulated profiles. The performance of this
methodology has also been tested for scattering profiles having complex
internal features and moderate statistical noise. Subsequently, the same has
been applied for experimental small-angle neutron scattering data. 相似文献
66.
Mesoscopic density fluctuations in liquid phase sintered silicon carbide have been investigated using small angle neutron
scattering (SANS). The increase in the additives results in the modification in the pore size distribution and to some extent
the total porosity. SANS revealed a mass fractal nature of the agglomerated matrix microstructure. The fractal dimension of
the matrix does not change appreciably with the additives although the upper cut-off value of the fractal decreases significantly
with the increase in the additives. The liquid phase sintering due to the presence of additives helps to achieve higher level
of densification. However, the agglomeration hinders achievement of the fully dense pellets.
相似文献
67.
D. K. Sengupta S. L Jackson A. P. Curtis W. Fang J. I. Malin T. U. Horton Q. Hartman H. C. Kuo S. Thomas J. Miller K. C. Hsieh I. Adesida S. L. Chuang M. Feng G. E. Stillman Y. C. Chang W. Wu J. Tucker H. Chen J. M. Gibson J. Mazumder L. Li H. C. Liu 《Journal of Electronic Materials》1997,26(12):1376-1381
We present experimental results on the growth and characterization of n-type InGaAs/InP quantum-well intersubband photodetectors
for use at 8.93 μm. High-quality InGaAs/InP multiple quantum wells were grown by gas source molecular beam expitaxy, and then
characterized by double-crystal x-ray diffraction and cross-sectional transmission electron microscopy. Based upon the structural
parameters determined by these methods, the photocurrent response spectra were simulated using a six-band effective bond-orbital
model. The theoretical results are in excellent agreement with experimental data. Additional important device characteristics
such as dark current, spectral response, and absolute responsivity are also presented. 相似文献
68.
The discovery of vibrant excited-state dynamics and distinctive photochemistry has established nitrated polycyclic aromatic hydrocarbons as an exhilarating class of organic compounds. Herein, we report the atypical photorearrangement of nitro-perylenediimide (NO2-PDI) to nitrito-perylenediimide (ONO-PDI), triggered by visible-light excitation and giving rise to linkage isomers in the polar aprotic solvent acetonitrile. ONO-PDI has been isolated and unambiguously characterized using standard spectroscopic, spectrometric, and elemental composition techniques. Although nitritoaromatic compounds are conventionally considered to be crucial intermediates in the photodissociation of nitroaromatics, experimental evidence for this has not been observed heretofore. Ultrafast transient absorption spectroscopy combined with computational investigations revealed the prominence of a conformationally relaxed singlet excited-state (SCR1) of NO2-PDI in the photoisomerization pathway. Theoretical transition state (TS) analysis indicated the presence of a six-membered cyclic TS, which is pivotal in connecting the SCR1 state to the photoproduct state. This article addresses prevailing knowledge gaps in the field of organic linkage isomers and provides a comprehensive understanding of the unprecedented photoisomerization mechanism operating in the case of NO2-PDI.The unprecedented photorearrangement of nitro-perylenediimide (NO2-PDI) to nitrito-perylenediimide (ONO-PDI) is shown to occur through a cyclic six-membered transition state triggered by visible-light excitation. 相似文献
69.
Suresh K. Chamarthi Brian Raterman Ria Mazumder Anthony Michaels Veeral M. Oza James Hanje Bradley Bolster Ning Jin Richard D. White Arunark Kolipaka 《Magnetic resonance imaging》2014
Magnetic resonance elastography (MRE) of the liver is a novel noninvasive clinical diagnostic tool to stage fibrosis based on measured stiffness. The purpose of this study is to design, evaluate and validate a rapid MRE acquisition technique for noninvasively quantitating liver stiffness which reduces by half the scan time, thereby decreasing image registration errors between four MRE phase offsets. In vivo liver MRE was performed on 16 healthy volunteers and 14 patients with biopsy-proven liver fibrosis using the standard clinical gradient recalled echo (GRE) MRE sequence (MREs) and a developed rapid GRE MRE sequence (MREr) to obtain the mean stiffness in an axial slice. The mean stiffness values obtained from the entire group using MREs and MREr were 2.72 ± 0.85 kPa and 2.7 ± 0.85 kPa, respectively, representing an insignificant difference. A linear correlation of R2 = 0.99 was determined between stiffness values obtained using MREs and MREr. Therefore, we can conclude that MREr can replace MREs, which reduces the scan time to half of that of the current standard acquisition (MREs), which will facilitate MRE imaging in patients with inability to hold their breath for long periods. 相似文献