A notable conversion of a thiolacetate to its corresponding sulfonyl chloride

A direct conversion of a thiolacetate to its corresponding sulfonyl chloride in the presence of acid and base sensitive functional groups is described.     

Parameters to Define the Electron Beam Trajectory of a Double-Tapered Disc-Loaded Wideband Gyro-TWT in Profiled Magnetic Field

In the method of tapering the cross section of the interaction structure for broadbanding a gyro-TWT, the different portions of the interaction length of the tapered-cross-section waveguide become effective for different frequency ranges if the magnetic field and beam parameters are profiled to maintain the condition of electron cyclotron resonance throughout the interaction length. In the present paper, the study of profiling the magnetic field and beam parameters in steps of the stepped analytical model of a double-tapered disc-loaded circular waveguide was made throughout the steps of the model. In the observed profile, the magnetic flux density in a typical step relative to its value in first-step decreases from first-step (gun-end) to end-step (collector-end) of the model considering the up-tapering schemes, in which structure parameters increase from gun-end to collector-end. Also, the transverse beam velocity in a typical step relative to its value in first-step decreases from gun-end to collector-end. However, the Larmor radius in a typical step relative to its value in first-step as well as the hollow-beam radius in a typical step relative to its value in first-step, both increase from gun-end to collector-end in the model considering the up-tapering schemes.     

Active mode leakage reduction using fine-grained forward body biasing strategy

Leakage power minimization has become an important issue with technology scaling. Variable threshold voltage schemes have become popular for standby power reduction. In this work we look at another emerging aspect of this potent problem which is leakage power reduction in active mode of operation. In gate level circuits, a large number of gates are not switching in active mode at any given point in time but nevertheless are consuming leakage power. We propose a fine-grained forward body biasing (FBB) scheme for active mode leakage power reduction in gate level circuits without any delay penalty. Our results show that our optimal polynomial time FBB allocation algorithm results in 70.2% reduction in leakage currents. We also present an exact standard-cell placement driven FBB allocation algorithm that effectively reduces the area penalty using the post-placement area slack and results in 56.5%, 62.8% and 66.1% reduction in leakage currents for 0%, 4% and 8% area slack, respectively. Furthermore, we present a heuristic to solve the standard-cell placement driven FBB allocation problem that is computationally efficient and results in leakage within 2% of that from the exact formulation.     

Accelerating molecular dynamic simulation on graphics processing units

We describe a complete implementation of all‐atom protein molecular dynamics running entirely on a graphics processing unit (GPU), including all standard force field terms, integration, constraints, and implicit solvent. We discuss the design of our algorithms and important optimizations needed to fully take advantage of a GPU. We evaluate its performance, and show that it can be more than 700 times faster than a conventional implementation running on a single CPU core. © 2009 Wiley Periodicals, Inc. J Comput Chem, 2009     

Palladium β-diketonate complex catalyzed synthesis of monosubstituted arylferrocenes

Palladium β-diketonate complexes are reported as efficient catalysts for the selective synthesis of monosubstituted arylferrocenes by a cross-coupling reaction of bis(ferrocenyl)mercury with aryl halides. The present protocol was applicable to aryl halides providing good to excellent yields of the desired products.     

Simulative investigation the impact of optical amplification techniques on single- and dual-electrode MZM and direct modulator's in single-tone RoF system

Since the introduction of erbium-doped fiber amplifier (EDFA) in optical fiber communication systems at 1550 nm, the fiber loss is no longer considered as the limiting factor but the fiber dispersion and chirp parameters play an important role in degrading the performance of optical communication systems. Further, the invention of external modulators of Mach-Zehnder (MS) type minimizes the transmission power penalty due to fiber chromatic dispersion as these modulators are consider almost chirp-free modulators. Also, better suppression of nonlinear distortions consists of harmonic distortions (HDs) and intermodulation distortions (IMDs) were achieved by using Mach-Zehnder external modulator [8]. In this work, a simulation comparison of external- and direct-modulation schemes using different optical amplifiers; SOA and EDFA in single-tone RoF system is reported. A single-tone channel of 20 GHz is transmitted over single-mode fiber (SMF) either externally modulated by using single-electrode (SEMZM) - and dual-electrode (DEMZM) - Mach-Zehnder modulator or by direct-modulation scheme. Better improvements in the measurement of received RF power of a 20 km linked single-tone RoF system are achieved by using SEMZM with EDFA, which means maximum optical link is achieved between Central Office (CO) and Base Station (BS). Further, this scheme provides better BER as compare to other schemes discussed in this paper.     

Synthesis of silver nanoparticle in imidazolium and pyrolidium based ionic liquid reverse micelles: A step forward in nanostructure inorganic material in room temperature ionic liquid field

Two silver salts, silver tetrafluoroborate and silver trifluoromethanesulfonate were dissolved in two different room temperature ionic liquids (RTILs), 1-Butyl-3 methyl imidazolium tetrafluoroborate ([Bmim][BF₄]) and 1-Butyl-1 methyl pyrrolidinium trifluoromethanesulfonate ([Bmpy][Tfms]). Triton x-100 (TX-100) surfactant and cyclohexane as nonpolar medium are used to dissolve these RTILs to create reverse micellar system. Pure reverse micellar system is characterized by dynamic light scattering (DLS) measurement. These pure RTIL reverse micellar systems are used to prepare stable silver nanoparticle solution without using any other auxiliary solvent in the whole process.     

Chaos control of fractional order Rabinovich–Fabrikant system and synchronization between chaotic and chaos controlled fractional order Rabinovich–Fabrikant system

In this article the local stability of the Rabinovich–Fabrikant (R–F) chaotic system with fractional order time derivative is analyzed using fractional Routh–Hurwitz stability criterion. Feedback control method is used to control chaos in the considered fractional order system and after controlling the chaos the authors have introduced the synchronization between fractional order non-chaotic R–F system and the chaotic R–F system at various equilibrium points. The fractional derivative is described in the Caputo sense. Numerical simulation results which are carried out using Adams–Boshforth–Moulton method show that the method is effective and reliable for synchronizing the systems.