Extinction Behavior of Dry Snow in the 18-to 90-GHz Range

The extinction properties of several dry snow types were examined in the 18-to 90-GHz range. The snow types ranged from newly fallen snow to refrozen snow, and the density and mean grain size varied from 0.17 to 0.39 g/cm3 and from 0.2 to 1.6 mm, respectively. From measurements of the transmission loss as a function of sample thickness at a temperature of -15°C, the extinction coefficient and the surface scattering loss (due to surface roughness at the front and back surfaces of the snow slab) were determined for each snow type. The experimental values were compared against theoretical results computed according to the strong fluctuation theory. In general, good agreement with the experimental data was obtained at 18, 35, and 60 GHz when the grain size used in the theoretical calculations was chosen to be slightly smaller than the observed snow-particle size. However, the extinction coefficient of large-grained refrozen snow as predicted by the strong fluctuation theory is much larger at 90 GHz than the values determined experimentally. The attenuation in snow was observed to increase only slightly with increasing temperature in the -35 to -1°C range.     

Combined Routeing and Scheduling for the Transportation of Containerized Cargo

A tractor-trailer problem, with full load, from the class of combined routeing and scheduling problems is described. Distinctive features of the problem are: movements must be carried out within certain time windows; subsets of movements are linked in the sense that they must be executed in a certain order; and different priorities are attached to different movements. A new bidirectional sequential constructive heuristic is developed for the solution of this problem. The method constructs routes and schedules for the available tractor fleet. The algorithm attempts to minimize the total time for all the movements by minimizing the time taken up by unproductive movements (so-called deadhead) and waiting time between movements. Some practical aspects of the implementation of the approach are discussed.     

Algebre de Lie attachee a la structure presque-tangente

Résumé On se propose d'étudier l'algèbre de Lie des champs de vecteurs qui laissent invariante la structure presque tangente sur le fibré tangent. On montre que cette algèbre de Lie est égale à son algèbre dérivée et on détermine toutes ses dérivations. On en déduit que cette algèbre de Lie caractérise la structure différentiable de la variété de base du fibré tangent.     

Chromatographic purification and radio-immunoassay,or diethylstilbestrol residues in meat

A rapid, reliable and sensitive method is reported for the detection of residues of diethylstilbestrol (DES) in meat samples. Enzymatic digestion of the muscle tissue followed by ether extract yields a raw extract which, depending on its fat content, can be partitioned in an alkali/chloroform mixture or passed through a Sephadex LH-20 column. To avoid false positive results in the radio-immunoassay, this extract is purified further by high-performance liquid chromatography on an RP-18 column. The detection limit is 0.07 ng g^?1.     

Kinetics and mechanism of the thermal reactions of endo- and exo-5-cyanobicyclo[2.2.2]oct-2-ene and methyl-substituted derivatives in the gas phase

The thermal reactions of endo- and exo-5-cyanobicyclo-[2.2.2]oct-2-ene and their trans- and cis-6-methyl-substituted derivatives have been investigated in the gas phase between 518 and 630 K. Each product decomposes by two parallel first-order retro-Diels-Alder reactions, a main one with formation of cyclohexa-1,3-diene and a minor one with elimination of ethene. Slight isomerizations are also observed. The kinetic results can be explained in terms of a biradical mechanism. The rate-determining step is shown to depend on the amount of resonance energy in the biradical. Heats of formation and entropies of the bicyclo[2.2.2]oct-2-enes studied are estimated.     

Conformational analysis of 1,2-difluoroethane, an ab-initio investigation

Contrary to expectation, the gauche conformer of 1,2-difluoroethane is more stable than the trans conformer in the gas phase. In order to understand the underlying causes of the “gauche effect”, a complete geometry relaxation was performed for the gauche and trans conformers of 1,2-difluoroethane with the 4-21G, 4-31G and 4-31G** basis sets. The 4-31G** optimized geometry of the gauche conformer compares well with the experimental values obtained from a number of electron-diffraction studies. A correction for the correlation energy, calculated by means of second-order Møller—Plesset perturbation theory with the 6-31G** basis set, proves to be essential to obtain a correct estimate of the energy difference between the gauche and trans conformers 1,2-difluoroethane.     

Tone detection and synthetic speech discrimination in band-reject noise by hearing-impaired listeners

Frequency resolution was evaluated for two normal-hearing and seven hearing-impaired subjects with moderate, flat sensorineural hearing loss by measuring percent correct detection of a 2000-Hz tone as the width of a notch in band-reject noise increased. The level of the tone was fixed for each subject at a criterion performance level in broadband noise. Discrimination of synthetic speech syllables that differed in spectral content in the 2000-Hz region was evaluated as a function of the notch width in the same band-reject noise. Recognition of natural speech consonant/vowel syllables in quiet was also tested; results were analyzed for percent correct performance and relative information transmitted for voicing and place features. In the hearing-impaired subjects, frequency resolution at 2000 Hz was significantly correlated with the discrimination of synthetic speech information in the 2000-Hz region and was not related to the recognition of natural speech nonsense syllables unless (a) the speech stimuli contained the vowel /i/ rather than /a/, and (b) the score reflected information transmitted for place of articulation rather than percent correct.