Cell Selection for Load Balancing in Heterogeneous Networks

The vision of advanced long-term evolution (LTE-A) project is set to ultimate increase of network capacity in heterogeneous networks (HetNets). In HetNets with small cell configuration, a considerable majority of user devices is eventually connected to the macrocell base station (MBS), while small base stations (BSs), such as femtocell access points (FAPs), are still without any user. This results in unbalanced load and reduces the data rate of macrocell user equipment (MUE). In this paper, a method is proposed for load balancing among FAPs, while desired throughput is achieved. The proposed method uses the estimated received signal strength from different BSs and adjusted pilot signals. Under the critical signal to interference plus noise ratio (SINR) condition, a list of candidate FAPs is prepared. The updated candidate list henceforth does not include the least visited FAPs, which in turn leads to lower unnecessary handoffs. Once the BS with the highest number of free RBs and the highest pilot signal power is selected, FAP allocates the RBs with higher SINRs (qualified RBs) to user. In the case of FAP unavailability, the algorithm compels users to connect to the MBS with adequate qualified RBs. The performance of the proposed method was evaluated under a variety of FAPs density, and the number and velocity of users in terms of throughput and Jain’s fairness index. The results evidence affordable improvements in the throughput and Jain’s index in comparison with other methods.     

Ultra-high-Q optical filter based on photonic crystal ring resonator

In this study, a photonic crystal ring resonator with a triangular lattice is used to design an optical filter. The proposed structure is able to filter the central wavelength of 1548 nm with a transmission coefficient of over 95%. Moreover, this structure has an ultra-high-quality factor (Q) of about 1290. With altering the features of the structure including the refractive index, the lattice constant and the radius of the rods in the resonator core, their effects on the central wavelength of the filter, transmission coefficient, quality factor and bandwidth are investigated. The plane wave expansion and finite-difference time-domain methods are used to extract photonic band gap and investigate the photonic behavior of the proposed structure, respectively.     

Performance improvement for recommender systems using ontology

Recommender systems have emerged in the e-commerce domain and have been developed to actively recommend appropriate items to online users. The use of recently developed hybrid recommendation systems has helped overcome the main drawbacks of Content-Based Filtering (CBF) and Collaborative Filtering (CF). In hybrid recommendation systems that combine CF and CBF, the CF part uses two methods, including memory- and model-based approaches. Both approaches have some advantages and disadvantages for item recommendation. Sparsity has been one of the main difficulties associated with these approaches, whereas recommendation with high accuracy has been one of the important advantages of the memory-based approach. However, this approach is not scalable for current recommendation systems as their databases include huge numbers of items and users. In contrast, the model-based approach generates recommendations with low accuracy but is scalable for large databases in e-commerce recommender systems. Accordingly, to address this problem and take advantage of both approaches, in this work, we propose a new hybrid recommendation method and evaluate it using a real-world dataset. The aim is to improve efficiency and accuracy by designing a heuristic hybrid recommender method that combines memory-based and model-based approaches. Specifically, we use ontology in the CF part and improve ontology structure by eliminating uniformity of edges of the hierarchical relation between concepts (IS-A relation) in item ontology in the CBF part. Ontology structure is considered for improving accuracy; according to this, a new method for measuring semantic similarity that is more accurate than the traditional methods is presented. This new method can enhance the accuracy of CF and CBF in our method. In addition, the number of searches required to find similar clusters and neighbor users of the target user is decreased significantly using ontology, enhanced clustering and the new proposed algorithm. We evaluate the proposed method using a real-world dataset. The experimental results show that our method is more scalable and accurate than the benchmark k-Nearest Neighbor (k-NN) and model-based recommendation methods.     

Efficient cluster head selection using Naïve Bayes classifier for wireless sensor networks

Data mining and approaches based on it have always been of approaches that have been considered in solving problems in the field of computer, but on some issues, this approach has been neglected. The area of wireless sensor networks and specifically the issue of optimal determining of the cluster head node are of these issues. To solve the problem of optimal determining of the cluster head node, Naïve Bayes that is the subset of data mining techniques is used in this paper. The results obtained after simulation of the presented algorithm show that the efficiency of this algorithm is significantly higher compared with other approaches that have so far been used to solve this problem, and thus it can be said that using this algorithm will lead to improved outcomes of solving this problem.     

C-H activation in bithiazole ring with thallium(III) ion

Two novel organometallic complex of 2,2′-dimethyl-4,4′-bithiazole (dm4bt) ligand (L) with formula [Tl(dm4bt)₂(NO₃)(H₂O)] (1) and [Tl(dm4bt)₂(NO₃)(DMSO)] (2) have been synthesized and structurally characterized by elemental analysis, FT-IR, ¹H NMR spectra and X-ray crystallography. These complexes also display the first transoid conformation in bithiazole ligands in which C-H bond activation in bithiazole ring is observed with Tl(III) ion.     

β-Tetra-brominated meso-tetraphenylporphyrin: A conformational study and application to the Mn-porphyrin catalyzed epoxidation of olefins with tetrabutylammonium oxone

X-ray crystallographic studies have shown that the free base β-tetra-brominated meso-tetraphenylporphyrin (H₂TPPBr₄) has a slightly ruffled structure with the dihedral angles of 70.1–79.2° between the phenyl groups and the porphyrin mean plane. The N(pyrrole)–N(pyrrolenine) distance is very similar to that of the standard planar porphyrins. The decreased N–H bond length of H₂TPPBr₄ with respect to that of meso-tetraphenylporphyrin (H₂TPP) seems to be due to the weaker intramolecular hydrogen bond of the former relative to the latter caused by the electron-withdrawing effects of the β-bromine substituents. The large red shifts of the Soret and Q(0,0) bands of H₂TPPBr₄ in comparison with those of H₂TPP, in spite of the nearly planar porphyrin core of the compound, also may be explained on the basis of the electron-withdrawing effects of the bromine atoms. Oxidation of styrene, the para-substituted derivatives and cyclooctene with tetrabutylammonium oxone in the presence of catalytic amounts of β-tetra-brominated meso-tetraphenylporphyrinatomanganese(III) acetate immediately gives the epoxide as the sole product. Terminal double bonds and unconjugated ones are less reactive than the conjugated double bonds and show lower selectivities. Catalytic activity of the electron-deficient Mn(H₂TPPBr₄)OAc dramatically depends on the Co-catalytic activity of the nitrogen donors as the axial base. The best axial bases are the nitrogenous donors with mixed σ- and π-donor ability to the metal centre.     

Fluidized-bed Fenton-like oxidation of a textile dye using natural magnetite

Degradation of Acid Orange 7 (AO7) as a model azo dye was investigated in a recirculating pilot fluidized-bed reactor by a Fenton-like process using natural magnetite (NM) and potassium persulfate (K₂S₂O₈). Scanning electron microscopy was performed to characterize the magnetite sample. The heterogeneous Fenton-like process (NM/\({\text{S}}_{2} {\text{O}}_{8}^{2 - }\)) is a modified method owing to its enhanced mass transfer. It can be operated reliably and simply by reducing the produced iron oxide sludge in the conventional Fenton process. Degradation efficiency (DE %) of AO7 by NM/ \({\text{S}}_{2} {\text{O}}_{8}^{2 - }\) process was affected by operational parameters. The DE % of 75 % was obtained for the AO7 treatment (15 mg/L) at the desired conditions, such as pH 5, 0.2 mM \({\text{S}}_{2} {\text{O}}_{8}^{2 - }\), and 0.5 g/L NM after 120 min of reaction time. The dye degradation rate in all the experiments followed the pseudo-second-order kinetic with high correlation coefficients (R ² ≥ 0.98). The low released iron concentration, successive reusability at milder pH and the recirculation mode with the proper mixing are the significant advantages of the NM/\({\text{S}}_{2} {\text{O}}_{8}^{2 - }\) process.     

Electrochemical and photo-assisted electrochemical treatment of the pesticide imidacloprid in aqueous solution by the Fenton process: effect of operational parameters

Research on Chemical Intermediates - The aim of this study was to compare the degradation efficiency (DE%) of imidacloprid as a model pesticide by electro-Fenton (EF) and photoelectro-Fenton...     

Poly(<Emphasis Type="Italic">n</Emphasis>-octyl methacrylate) viscosity index improver: Kinetic study via on-line <Superscript>1</Superscript>H-NMR technique

The free radical solution polymerization of n-octyl methacrylate has been studied in benzene-d ₆ in the presence of 2,2′-azobisisobutyronitrile as thermal initiator. An on-line nuclear magnetic resonance spectroscopy was applied to record the reaction data and to determine the monomer conversion at different times during the polymerization reaction. Effect of monomer and initiator concentration as well as reaction temperature on polymerization rate was studied. The order of the reaction with respect to initiator (0.45) was consistent with the classical kinetic rate equation, while the order of reaction with respect to monomer (1.87) was much greater than unity. An overall activation energy (E _a = 53.8 kJ/mol) was obtained over the temperature range 328?338 K. Also, the efficiency of the synthesized poly(n-octyl methacrylate) for improving the viscosity index of the lube oil was investigated.