Microextraction of phenolic compounds using a fiber coated with a polyaniline-montmorillonite nanocomposite

Microchimica Acta - A highly porous fiber coated polyaniline/montmorillonite clay was prepared for solid-phase microextraction. The nanocomposite was synthesized by in-situ polymerization. The...     

Torsional vibration of functionally graded nano-rod under magnetic field supported by a generalized torsional foundation based on nonlocal elasticity theory

Abstract

This article contains the nonlocal elasticity theory to capture size effects in functionally graded (FG) nano-rod under magnetic field supported by a torsional foundation. Torque effect of an axial magnetic field on an FG nano-rod has been defined using Maxwell’s relation. The material properties were assumed to vary according to the power law in radial direction. The Navier equation and boundary conditions of the size-dependent FG nano-rod were derived by the Hamilton’s principle. These equations were solved by employing the generalized differential quadrature method (GDQM). Presented model has the ability to turn into the classical model if the material length scale parameter is taken to be zero. The effects of some parameters, such as inhomogeneity constant, magnetic field and small-scale parameter, were studied. As an important result of this study can be stated that an FG nano-rod model based on the nonlocal elasticity theory behaves softer and has smaller natural frequency.     

Timeout Period Analysis to Detect Black Hole Attack in Multihop Wireless Ad Hoc Networks

A novel approach is proposed to estimate the timeout period used in wireless ad hoc networks in order to detect misbehaving nodes that make black hole attacks. Timeout period is an acceptable time frame for a node to forward a packet and is used to judge if the node is behaving properly. To avoid misjudgment and false alarms, the accuracy of the estimate of the timeout period is very important. Our method is based on the IEEE 802.11 MAC protocol and Dynamic Source Routing protocol. The main contribution of this paper is proposing a queuing analysis to calculate the mean and maximum delay per hop implementing the 95-percentile of medium access waiting time. In addition, a new technique is introduced that can be applied to determine the mean number of hops in flooding-based ad hoc networks, taking into account edge effects. For each proposed model, analytical results are compared with results obtained from simulations and the validity of the models is confirmed by observing the close relationship between the results.     

A ternary hybrid system based on combination of mesoporous silica,heteropolyacid and double-layered clay: an efficient catalyst for the synthesis of 2,4-dihydro-3H-pyrazol-3-ones and pyranopyrazoles in aqueous medium: studying the effect of the synthetic procedure on the catalytic activity

Research on Chemical Intermediates - SBA/hydrotalcite/heteropolyacid nanocomposite is synthesized via a novel procedure in which the as-prepared heteropolyacid-loaded SBA-15 was impregnated with...     

Integrated Transmission Electron and Single‐Molecule Fluorescence Microscopy Correlates Reactivity with Ultrastructure in a Single Catalyst Particle

Establishing structure–activity relationships in complex, hierarchically structured nanomaterials, such as fluid catalytic cracking (FCC) catalysts, requires characterization with complementary, correlated analysis techniques. An integrated setup has been developed to perform transmission electron microscopy (TEM) and single‐molecule fluorescence (SMF) microscopy on such nanostructured samples. Correlated structure–reactivity information was obtained for 100 nm thin, microtomed sections of a single FCC catalyst particle using this novel SMF‐TEM high‐resolution combination. High reactivity in a thiophene oligomerization probe reaction correlated well with TEM‐derived zeolite locations, while matrix components, such as clay and amorphous binder material, were found not to display activity. Differences in fluorescence intensity were also observed within and between distinct zeolite aggregate domains, indicating that not all zeolite domains are equally active.     

A new design of optical add/drop filters and multi-channel filters based on hexagonal PhCRR for WDM systems

Photonic Network Communications - In this research, using photonic crystal dielectric rods with a triangular lattice constant, a photonic crystal ring resonator (PhCRR) has been designed in order...     

Energy‐efficient void avoidance geographic routing protocol for underwater sensor networks

Underwater wireless sensor networks (UWSNs) consist of a group of sensors that send the information to the sonobuoys at the surface level. Void area, however, is one of the challenges faced by UWSNs. When a sensor falls in a void area of communication, it causes problems such as high latency, power consumption, or packet loss. In this paper, an energy‐efficient void avoidance geographic routing protocol (EVAGR) has been proposed to handle the void area with low amount of energy consumption. In this protocol, a suitable set of forwarding nodes is selected using a weight function, and the data packets are forwarded to the nodes inside the set. The weight function includes the consumed energy and the depth of the candidate neighboring nodes, and candidate neighboring node selection is based on the packet advancement of the neighboring nodes toward the sonobuoys. Extensive simulation experiments were performed to evaluate the efficiency of the proposed protocol. Simulation results revealed that the proposed protocol can effectively achieve better performance in terms of energy consumption, packet drop, and routing overhead compared with the similar routing protocol.     

Cell Selection for Load Balancing in Heterogeneous Networks

The vision of advanced long-term evolution (LTE-A) project is set to ultimate increase of network capacity in heterogeneous networks (HetNets). In HetNets with small cell configuration, a considerable majority of user devices is eventually connected to the macrocell base station (MBS), while small base stations (BSs), such as femtocell access points (FAPs), are still without any user. This results in unbalanced load and reduces the data rate of macrocell user equipment (MUE). In this paper, a method is proposed for load balancing among FAPs, while desired throughput is achieved. The proposed method uses the estimated received signal strength from different BSs and adjusted pilot signals. Under the critical signal to interference plus noise ratio (SINR) condition, a list of candidate FAPs is prepared. The updated candidate list henceforth does not include the least visited FAPs, which in turn leads to lower unnecessary handoffs. Once the BS with the highest number of free RBs and the highest pilot signal power is selected, FAP allocates the RBs with higher SINRs (qualified RBs) to user. In the case of FAP unavailability, the algorithm compels users to connect to the MBS with adequate qualified RBs. The performance of the proposed method was evaluated under a variety of FAPs density, and the number and velocity of users in terms of throughput and Jain’s fairness index. The results evidence affordable improvements in the throughput and Jain’s index in comparison with other methods.