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排序方式: 共有584条查询结果,搜索用时 11 毫秒
1.
Contact angle (CA) hysteresis is the difference between the maximum (advancing) and minimum (receding) water CA. Hysteresis is caused by adhesion hysteresis in the solid–water contact area (2D effect) and by pinning of the solid–water–air triple line due to the surface roughness (1D effect). In this work, we show that CA hysteresis is present also in more complex systems, such as an organic liquid (oil) in contact with a solid immersed in water. In order to decouple the 1D and 2D effects, we study CA hysteresis in solid–water–air (droplet), solid–air–water (bubble), solid–water–oil, and solid–water–air–oil systems involving rough and microstructured surfaces. The comparative analysis of these systems allows decoupling the 1D and 2D effects as well as hydrogen bonding and entropic forces (water–air tension) and dispersion forces (oil–air tension). 相似文献
2.
Two new complexes of [Mn(2-MPyzCI)2Cl2].H2O (1) and [Mn(2-MPyzCI)2(H2O)2](NO3)2 (2) were synthesized from the reaction of MnX2.4H2O (X=Cl? and NO3?) with 2-cyanopyrazine in methanolic solution. The chelating methyl pyrazine-2-carboximidate (2-MPyzCI) ligand is formed via the methanolysis of 2-cyanopyrazine. Although coordination environment around manganes(II) ions is similar, but these complexes are different in geometrical position of 2-MPyzCI ligands. As both compounds are synthesized under the same reaction conditions, the only difference between these two complexes are counter ions and changing of geometrical position of ligands can be considered as a result of influence of the counter-anions on the molecular structures. 相似文献
3.
AbstractThis article contains the nonlocal elasticity theory to capture size effects in functionally graded (FG) nano-rod under magnetic field supported by a torsional foundation. Torque effect of an axial magnetic field on an FG nano-rod has been defined using Maxwell’s relation. The material properties were assumed to vary according to the power law in radial direction. The Navier equation and boundary conditions of the size-dependent FG nano-rod were derived by the Hamilton’s principle. These equations were solved by employing the generalized differential quadrature method (GDQM). Presented model has the ability to turn into the classical model if the material length scale parameter is taken to be zero. The effects of some parameters, such as inhomogeneity constant, magnetic field and small-scale parameter, were studied. As an important result of this study can be stated that an FG nano-rod model based on the nonlocal elasticity theory behaves softer and has smaller natural frequency. 相似文献
4.
High resolution capillary electrophoresis of carbon nanotubes 总被引:2,自引:0,他引:2
Doorn SK Fields RE Hu H Hamon MA Haddon RC Selegue JP Majidi V 《Journal of the American Chemical Society》2002,124(12):3169-3174
Purification of single-walled carbon nanotubes by capillary electrophoresis (CE) is demonstrated. Real-time Raman spectroscopy of the separation process and single-wavelength UV/vis detection show the ability of CE to provide high-resolution separations of nanotube fractions with baseline separation. AFM images of collected fractions demonstrate that separations are based on tube length. The separation method is suggested to be based on alignment of the nanotubes along the separation field. 相似文献
5.
Ardeshir Khazaei Mahsa Tavasoli Vahid Jamshidi Fatemeh Gohari Ghalil Ahmad Reza Moosavi‐Zare 《应用有机金属化学》2018,32(7)
Cu ( II ) supported on poly(8‐hydroxyquinoline‐p‐styrenesulfonate) (Cu ( II )@PHQSS) was prepared and fully characterized by the different techniques including fourier transform infrared spectroscopy (FT‐IR), 1H NMR, 13C NMR, thermal gravimetric analysis (TGA), differential thermal gravimetric (DTG), differential thermal analysis (DTA), scanning electron microscope (SEM) and energy dispersive X‐ray analysis (EDS). Afterward, the Cu ( II )@PHQSS as nanostructured catalyst was used as catalyst for the synthesis of hexahydroquinolines. 相似文献
6.
Sadjadi Samahe Heravi Majid M. Zadsirjan Vahideh Farzaneh Vahid 《Research on Chemical Intermediates》2018,44(11):6765-6785
Research on Chemical Intermediates - SBA/hydrotalcite/heteropolyacid nanocomposite is synthesized via a novel procedure in which the as-prepared heteropolyacid-loaded SBA-15 was impregnated with... 相似文献
7.
Research on Chemical Intermediates - Calcined oyster shell nanoparticles (COS NPs) as a novel heterogeneous nanocatalyst were prepared and fully characterized by X-ray fluorescence analysis,... 相似文献
8.
Faezeh Pourebrahim Mehrorang Ghaedi Kheibar Dashtian Shadi Kheirandish Ramin Jannesar Vahid Pezeshkpour 《应用有机金属化学》2018,32(1)
In this work, functionalized chitosan end‐capped Ag nanoparticles (NPs) and composited with Fe3O4‐NPs was prepared as pH‐responsive controlled release carrier for gastric‐specific drug delivery. The structure of prepared material was characterized by FE‐SEM, XRD, EDS and FT‐IR analysis. The loading behavior of the progesterone onto this novel material was studied in aqueous medium at 25°C and their release was followed spectrophotometrically at 37°C in seven different buffer solutions (pH 1.2, 2.2, 3.2, 4.2, 5.2, 6.2 and 7.2) to simulate intestine and gastric media which experimental results reveal more release rate in pH 1.2 (gastric medium) with respect to other buffers. This observation is attributed to dependency of the CS‐IMBDO‐Ag‐Fe3O4‐NPs and progesterone structure with buffer pH that candidate this new material as prospective pH‐sensitive carrier for gastric‐targeted drug delivery. On the other hand, the antibacterial properties of this material against gram‐negative bacterium pseudomonas aeruginosa (PAO‐1) in agar plates was studied and accordingly based on broth micro dilution the minimum bactericidal concentration (MBC) and minimum inhibitory concentration (MIC) with respect to standard CLSI in different concentrations of CS‐IMBDO‐Ag‐Fe3O4‐NPs was calculated. The results reveal that MIC and MBC values are 50 and 1250 μg/mL, respectively. In addition, extracts of Portulaca oleracea leaves was prepared and its antibacterial activity in single and binary system with CS‐IMBDO‐Ag‐Fe3O4‐NPs as synergies effect against PAO‐1 was tested and results shown that these materials have significant synergistic effect for each other. 相似文献
9.
Integrated Transmission Electron and Single‐Molecule Fluorescence Microscopy Correlates Reactivity with Ultrastructure in a Single Catalyst Particle 下载免费PDF全文
Frank C. Hendriks Sajjad Mohammadian Dr. Zoran Ristanović Dr. Sam Kalirai Dr. Florian Meirer Prof. Dr. Eelco T. C. Vogt Dr. Pieter C. A. Bruijnincx Prof. Dr. Hans C. Gerritsen Prof. Dr. Bert M. Weckhuysen 《Angewandte Chemie (International ed. in English)》2018,57(1):257-261
Establishing structure–activity relationships in complex, hierarchically structured nanomaterials, such as fluid catalytic cracking (FCC) catalysts, requires characterization with complementary, correlated analysis techniques. An integrated setup has been developed to perform transmission electron microscopy (TEM) and single‐molecule fluorescence (SMF) microscopy on such nanostructured samples. Correlated structure–reactivity information was obtained for 100 nm thin, microtomed sections of a single FCC catalyst particle using this novel SMF‐TEM high‐resolution combination. High reactivity in a thiophene oligomerization probe reaction correlated well with TEM‐derived zeolite locations, while matrix components, such as clay and amorphous binder material, were found not to display activity. Differences in fluorescence intensity were also observed within and between distinct zeolite aggregate domains, indicating that not all zeolite domains are equally active. 相似文献
10.
Back Cover: Integrated Transmission Electron and Single‐Molecule Fluorescence Microscopy Correlates Reactivity with Ultrastructure in a Single Catalyst Particle (Angew. Chem. Int. Ed. 1/2018) 下载免费PDF全文