Biomimetic Bottlebrush Polymer Coatings for Fabrication of Ultralow Fouling Surfaces

Demand for long‐lasting antifouling surfaces has steered the development of accessible, novel, biocompatible and environmentally friendly materials. Inspired by lubricin (LUB), a component of mammalian synovial fluid with excellent antifouling properties, three block polymers offering stability, efficacy, and ease of use were designed. The bottlebrush‐structured polymers adsorbed strongly on silica surfaces in less than 10 minutes by a simple drop casting or online exposure method and were extremely stable in high‐salinity solutions and across a wide pH range. Antifouling properties against proteins and bacteria were evaluated with different techniques and ultralow fouling properties demonstrated. With serum albumin and lysozyme adsorption <0.2 ng cm^?2, the polymers were 50 and 25 times more effective than LUB and known ultralow fouling coatings. The antifouling properties were also tested under MPa compression pressures by direct force measurements using surface forces apparatus. The findings suggest that these polymers are among the most robust and efficient antifouling agents currently known.     

The peridynamic differential operator for solving time-fractional partial differential equations

Nonlinear Dynamics - In this paper, the numerical solution of time-fractional convection diffusion equations (TF-CDEs) is considered as a generalization of classical ones, nonexponential relaxation...     

Near Optimum Random Routing of Uniformly Load Balanced Nodes in Wireless Sensor Networks Using Connectivity Matrix

Wireless Personal Communications - Wireless sensor networks (WSNs) are ad hoc networks usually made up of miniaturized autonomous units called sensor nodes that communicate in between by radio...     

Microextraction of phenolic compounds using a fiber coated with a polyaniline-montmorillonite nanocomposite

Microchimica Acta - A highly porous fiber coated polyaniline/montmorillonite clay was prepared for solid-phase microextraction. The nanocomposite was synthesized by in-situ polymerization. The...     

Torsional vibration of functionally graded nano-rod under magnetic field supported by a generalized torsional foundation based on nonlocal elasticity theory

Abstract

This article contains the nonlocal elasticity theory to capture size effects in functionally graded (FG) nano-rod under magnetic field supported by a torsional foundation. Torque effect of an axial magnetic field on an FG nano-rod has been defined using Maxwell’s relation. The material properties were assumed to vary according to the power law in radial direction. The Navier equation and boundary conditions of the size-dependent FG nano-rod were derived by the Hamilton’s principle. These equations were solved by employing the generalized differential quadrature method (GDQM). Presented model has the ability to turn into the classical model if the material length scale parameter is taken to be zero. The effects of some parameters, such as inhomogeneity constant, magnetic field and small-scale parameter, were studied. As an important result of this study can be stated that an FG nano-rod model based on the nonlocal elasticity theory behaves softer and has smaller natural frequency.     

Timeout Period Analysis to Detect Black Hole Attack in Multihop Wireless Ad Hoc Networks

A novel approach is proposed to estimate the timeout period used in wireless ad hoc networks in order to detect misbehaving nodes that make black hole attacks. Timeout period is an acceptable time frame for a node to forward a packet and is used to judge if the node is behaving properly. To avoid misjudgment and false alarms, the accuracy of the estimate of the timeout period is very important. Our method is based on the IEEE 802.11 MAC protocol and Dynamic Source Routing protocol. The main contribution of this paper is proposing a queuing analysis to calculate the mean and maximum delay per hop implementing the 95-percentile of medium access waiting time. In addition, a new technique is introduced that can be applied to determine the mean number of hops in flooding-based ad hoc networks, taking into account edge effects. For each proposed model, analytical results are compared with results obtained from simulations and the validity of the models is confirmed by observing the close relationship between the results.     

A ternary hybrid system based on combination of mesoporous silica,heteropolyacid and double-layered clay: an efficient catalyst for the synthesis of 2,4-dihydro-3H-pyrazol-3-ones and pyranopyrazoles in aqueous medium: studying the effect of the synthetic procedure on the catalytic activity

Research on Chemical Intermediates - SBA/hydrotalcite/heteropolyacid nanocomposite is synthesized via a novel procedure in which the as-prepared heteropolyacid-loaded SBA-15 was impregnated with...     

A new design of optical add/drop filters and multi-channel filters based on hexagonal PhCRR for WDM systems

Photonic Network Communications - In this research, using photonic crystal dielectric rods with a triangular lattice constant, a photonic crystal ring resonator (PhCRR) has been designed in order...