Investigations of nitrogen diffusion in austenitic CrNi steels

Parameters of the diffusion of N (up to 0.3 wt.%) in austenitic stainless steels (12 to 19 wt.% Cr, 12 to 16 wt.% Ni, up to 2 wt.% Mo) were determined within the temperature range of 1283–1573K. The small concentration gradients of N were successfully investigated using (1) mechanical serial sectioning technique in combination with either chemical N analysis or X-ray precision lattice parameter determination, and (2) measurements on microsections by means of either electron probe microanalysis or Kossel technique.The diffusion coefficients of N were found to be independent of its concentration. The alloying elements Cr and Mo reduce the N diffusivity in austenitic stainless steels which on the other hand is increased by Ni.     

Doubly inelastic collisions with relativistic heavy ions and target recoil momentum spectroscopy

We consider relativistic collisions of heavy hydrogenlike ions with hydrogen and helium atoms in which the ion-atom interaction causes both colliding particles to change their internal states. Concentrating on the study of the longitudinal momentum spectrum of the atomic recoil ions, we discuss the role of relativistic and higher order effects, predict a surprisingly strong influence of the projectile's electron on the momentum transfer, and show that the important information about the doubly inelastic collisions could be obtained in experiment merely by measuring the recoil momentum spectrum.     

„Fouling“-Vorgänge bei der Verdampfung von Argon im waagerecht durchströmten Rohr

Zusammenfassung Bei Messungen des Wärmeübergangs beim Strömungssieden von Argon wurde ein zeitlicher Anstieg der Wandtemperatur beobachtet, während die Einstellparameter Wärmestromdichte, Massenstromdichte, Dampfgehalt und Systemdruck konstant blieben. Dieser Temperaturanstieg endete nach mehreren Stunden bei einer beträchtlich höheren Wandtemperatur oder mit dem Eintreten der Siedekrise. Als Ursache für dieses Phänomen wurde die Ablagerung von im Argon gelöstem CO₂ an der Heizfläche ermittelt, wobei zu beachten ist, daß die Reinheit des verwendeten Argons größer als 99,996 vol-% war. In weiteren Versuchen wurde der Einfluß der CO₂-Konzentration auf diesen Fouling-Vorgang bestimmt und ein Verfahren entwickelt, um das CO₂ aus dem Meßkreislauf zu entfernen. Der Ablagerungsmechanimus und der Einfluß der Betriebsparameter auf die Ablagerungsgeschwindigkeit können mit Modellvorstellungen zur Blasenbildung erklärt werden.

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Fouling-phenomena during the evaporation of argon within a horizontal tube

During heat transfer measurements at flow boiling of argon a transient increase of the wall temperature has been observed, though the parameters such as heat flux, mass velocity, flow quality and system pressure were kept constant. This temperature drifting ended after several hours at a considerably higher wall temperature or with the boiling crisis. Although the purity of the test substance was higher than 99.996 vol-%, this phenomenon was caused by the solidification of CO₂ on the heating surface. Further investigations showed the influence of the CO₂-concentration on the drifting as well as a method to remove the CO₂ out of the test fluid. Both, fouling mechanism and influence of the parameters on the fouling, can be explained satisfactorily by means of bubble-growth mechanisms.

     

Reductive Insertion of Elemental Chalcogens into Boron–Boron Multiple Bonds

The syntheses of sulfur‐ and selenium‐bridged cyclic compounds containing boron stabilized by N‐heterocyclic carbenes (NHCs) have been achieved by the reductive insertion of elemental chalcogens into boron–boron multiple bonds. The three pairs of bonding electrons between the boron atoms in the triply bonded diboryne enabled six‐electron reduction reactions, resulting in the formation of [2.2.1]‐bicyclic systems wherein bridgehead boron atoms are spanned by three chalcogen bridges. A similar reaction using a diborene (boron–boron double bond) resulted in the reductive transfer of both pairs of bonding electrons to three sulfur atoms, yielding a NHC‐stabilized trisulfidodiborolane. The demonstration of these six‐ and four‐electron reductions lends support to the presence of three and two pairs of bonding electrons between the boron atoms of the diboryne and diborene, respectively, a fact that may be useful in future discussions on bond order.     

Differentiation between Shallow and Deep Charge Trap States on Single Poly(3‐hexylthiophene) Chains through Fluorescence Photon Statistics

Blinking of the photoluminescence (PL) emitted from individual conjugated polymer chains is one of the central observations made by single‐molecule spectroscopy (SMS). Important information, for example regarding excitation energy transfer, can be extracted by evaluating dynamic quenching. However, the nature of trap states, which are responsible for PL quenching, often remains obscured. We present a detailed investigation of the photon statistics of single poly(3‐hexylthiophene) (P3HT) chains obtained by SMS. The photon statistics provide a measure of the number and brightness of independently emitting areas on a single chain. These observables can be followed during blinking. A decrease in PL intensity is shown to be correlated with either 1) a decrease in the average brightness of the emitting sites; or 2) a decrease in the number of emitting regions. We attribute these phenomena to the formation of 1) shallow charge traps, which can weakly affect all emitting areas of a single chain at once; and 2) deep traps, which have a strong effect on small regions within the single chains.