A novel diacetylenic bilirubin

An etiobilirubin‐IIβ analog with the central C(10) CH₂ group replaced by a diacetylene unit ( 1 ) was synthesized by base‐catalyzed condensation of bis‐[3‐methyl‐4‐ethyl‐5‐formylpyrrol‐2‐yl]‐diacetylene ( 3 ) with 3‐methyl‐4‐ethyl‐5‐p‐toluenesulfonyl‐2‐pyrrolinone ( 10 ). Diacetylenic rubin 1 is a dark red solid, giving orange solutions with uv‐visible absorption maxima near 460 nm.     

On the permutability of Bäcklund transformations: 1 infinitesimal Bäcklund transformations of the sine-Gordon equation

Letu′=B _a u be the Bäcklund transformation of the sine-Gordon equation, we prove that $$B_{a + \varepsilon } B_a^{ - 1} u = u + \varepsilon \sum\limits_{n = 0}^\infty {2D^{ - 1} } \frac{{\delta G_{n + 1} }}{{\delta u}}a^{2n} ,$$ where {G _n} is an infinite set of conserved densities of the sine-Gordon equation and η ⁿ ≡D ^?1δG _n /δu are just the symmetries obtained by Olver [17]. Basing upon this expansion, we prove the equivalence between the permutability of the infinitesimal Bäcklund transformations and the involution of the conserved densities of the sine-Gordon equation.     

A differential pulsewidth control loop for high-speed VLSI systems

For those adopting double data rate technology systems, the precise system timing plays a crucial role since both rising and falling edges of the system clock signal are used to sample the input data. Due to this requirement, it is necessary to accurately maintain the duty cycle of the clock signal at 50%. For a multistage clock buffer, a pulsewidth control loop (PWCL) circuit was therefore proposed to adjust the duty cycle of its output signal. This paper is aimed at introducing a new proposed differential PWCL (DPWCL) together with investigating its mechanism through a comprehensive theoretical analysis. By taking advantage of a differential topology, the dc offset in generating the control voltage can be removed thereby improving the duty cycle control accuracy. Moreover, the proposed DPWCL employs a low-pass filter to generate the reference voltage so that the DPWCL does not necessitate a 50% duty cycle reference clock.     

Cu(ii)/SPDO complex catalyzed asymmetric Baeyer–Villiger oxidation of 2-arylcyclobutanones and its application for the total synthesis of eupomatilones 5 and 6

A novel classical kinetic resolution of 2-aryl-substituted or 2,3-disubstituted cyclobutanones of Baeyer–Villiger oxidation catalyzed by a Cu(ii)/SPDO complex is reported for the first time, producing normal lactones in excellent enantioselectivities (up to 96% ee) and regioselectivities (up to >20/1), along with unreacted ketones in excellent enantioselectivities (up to 99% ee). The current transformation features a wide substrate scope. Moreover, catalytic asymmetric total syntheses of natural eupomatilones 5 and 6 are achieved in nine steps from commercially available 3-methylcyclobutan-1-one.

A novel classical kinetic resolution of Baeyer–Villiger oxidation catalyzed by a Cu(ii)/SPDO complex with excellent enantioselectivity, regioselectivity and wide substrate scope is reported for the first time and explore the synthetic application.     

基于S3F9488与CP2512的电子产品应用设计

运用电容触摸检测芯片CP2512与单片机S3F9488进行电路设计.触摸检测芯片CP2512通过检测电容的变化量来感知外界数据的变化,通过I2C协议把CP2512采集的数据送到S3F9488,S3F9488根据采集到的数据进行相应的功率控制.本文给出了CP2512与S3F9488的硬件设计图.该方案的设计可以使家电产品更加耐用、美观;能有效地提高产品的抗干扰能力,提升产品的品质.该电路的设计为家电产品提够了一种低成本解决方案,最终在电磁炉中得到了实现.     

环形孔径对部分相干光光谱的影响

本文推导了部分相干光在经过环形孔径之后,远场轴上点的光谱S(ω)与环形孔径处光的光谱S~(0)(ω)之间的关系。数值计算结果表明,S(ω)不仅依赖于S~(0)(ω),而且还与环形孔径处光的相干性以及环形孔径的参数有关。     

基于能量中心的电力机车接触导线几何参数视觉检测方法

传统的电力机车接触导线几何参数检测方法存在若干不足。根据检测要求和磨损后接触线的图像特征,提出了基于双目视觉技术的在线、非接触、多参数综合测量方法。对基于LOG 算子的线条边缘图像处理方法的误差进行了深入的理论分析,在此基础上提出了采用图像能量中心算法的边缘定位新方法,并进行了数值模拟。仿真结果表明:能量中心算法的抗干扰和抗模糊能力更强,定位精度更高。以不同高度、拉出值和磨损宽度的圆钢为检测对象进行了验证实验,并与激光测距仪和数显式游标卡尺检测的结果进行了比对。实验表明,能量中心算法的边缘检测精度优于LOG 算法,同时,提出的测量方法示值误差小、重复性较好,能够满足接触线在线、非接触综合检测的需要。