Development of a wide range-operable,rich-lean low-NOx combustor for NH3 fuel gas-turbine power generation

Low-NOx NH₃-air combustion power generation technology was developed by using a 50-kWe class micro gas-turbine system at the National Institute of Advanced Industrial Science and Technology (AIST), Japan, for the first time. Based on the global demand for carbon-free power generation as well as recent advances involving gas-turbine technologies, such as heat-regenerative cycles, rapid fuel mixing using strong swirling flows, and two-stage combustion with equivalence ratio control, we developed a low-NOx NH₃-air non-premixed combustor for the gas-turbine system. Considering a previously performed numerical analysis, which proved that the NO reduction level depends on the equivalence ratio of the primary combustion zone in a NH₃-air swirl burner, an experimental study using a combustor test rig was carried out. Results showed that eliminating air flow through primary dilution holes moves the point of the lowest NO emissions to the lesser fuel flow rate. Based on findings derived by using a test rig, a rich-lean low NOx combustor was newly manufactured for actual gas-turbine operations. As a result, the NH₃ single fueled low-NOx combustion gas-turbine power generation using the rich-lean combustion concept succeeded over a wide range of power and rotational speeds, i.e., below 10–40 kWe and 75,000–80,000?rpm, respectively. The NO emissions were reduced to 337?ppm (16% O₂), which was about one-third of that of the base system. Simultaneously, unburnt NH₃ was reduced significantly, especially at the low electrical power output, which was indicative of the wider operating range with high combustion efficiency. In addition, N₂O emissions, which have a large Global Warming Potential (GWP) of 298, were reduced significantly, thus demonstrating the potential of NH₃ gas-turbine power generation with low environmental impacts.     

Chemical etching op fission tracks in ethylene-tetrafluoroethylene copolymer

The chemical etching of fission tracks in ethylene-tetrafluoro-ethylene copolymer was studied. Etched holes 3000–4000 Å in diameter was recognized by electron microscopy for a film bombarded by fission fragments in oxygen and etched in a 12N sodium hydroxide solution at 125°C. The radial etching rate at 125°C was 6–8 Å/hr, which is less than 17 Å/hr for polyvinylidene fluoride in the same sodium hydroxide concentration at 85°C. The smaller rate is a reflection of the larger chemical resistivity of ethylene-tetrafluoro-ethylene copolymer than polyvinylidene fluoride.     

The anomalous behaviour of Gd atoms (Fe1−xMnx)2 compounds

The educed Gd atoms in the X-structure (Th₆Mn₂₃-type) of Gd(Fe_1−xMn_x)₂ were magnetically investigated by comparing with Gd₆(Fe_1−yMn_y)₂₃ whose structure is Th₆Mn₂₃-type. The magnetic properties of Gd(Fe_1−xMn_x)₂ (0.4≤x≤0.7) were observed to be quite similar to those of Gd₆(Fe_1−yMn_y)₂₃ (0.4≤y≤0.7).     

Floating-island TFT leakage caused by process step reduction

The leakage mechanism for a top-gate thin-film transistor (TFT) produced using the fewest process steps in the industry is analyzed in order to achieve a high-contrast liquid crystal display (LCD). Using a T-shaped TFT structure, the OFF and ON channel lengths are defined independently, so that the leakage can be reduced with no ON current decrease     

Escherichia coli-catalyzed bioelectrochemical oxidation of acetate in the presence of mediators

Bioelectrocatalytic oxidation of acetate was investigated under anaerobic conditions by using Escherichia coli K-12 (IFO 3301) cells cultured on aerobic media containing poly-peptone, glucose or acetate as the sole carbon source. It was found that all E. coli cells cultured on the three media work as good catalysts of the electrochemical oxidation of acetate as well as glucose with Fe(CN)6(3-), 2,3-dimethoxy-5-methyl-1,4-benzo-quinone (Q0), 2,6-dichloro-indophenol, or 2-methyl-1,4-naphthoquinone as artificial electron acceptors (mediators). Acetate-grown E. coli cells exhibited the highest relative activity of the acetate oxidation against the glucose oxidation. On the other hand, all the artificial electron acceptors used work as inhibitors for the catalytic oxidation of acetate at increased concentrations. The inhibition phenomenon can be interpreted in terms of competitive substrate inhibition as a whole. Apparent values of Michaelis constant, catalytic constant, and inhibition constant were evaluated by amperometric methods. Q0 is an effective artificial mediator as evidenced by a large reaction rate constant between the cell and Q0 at least at low concentrations (<50 microM). However, Fe(CN)6(3-) is a promising mediator in biosensor applications because the inhibition constant is very large and it works as an electron acceptor even under aerobic conditions.     

Lactate biosensors: current status and outlook

Many research efforts over the last few decades have been devoted to sensing lactate as an important analytical target in clinical care, sport medicine, and food processing. Therefore, research in designing lactate sensors is no longer in its infancy and now is more directed toward viable sensors for direct applications. In this review, we provide an overview of the most immediate and relevant developments toward this end, and we discuss and assess common transduction approaches. Further, we critically describe the pros and cons of current commercial lactate sensors and envision how future sensing design may benefit from emerging new technologies.     

Entanglement Renyi Entropy of Two Disjoint Intervals for Large c Liouville Field Theory

Entanglement entropy (EE) is a quantitative measure of the effective degrees of freedom and the correlation between the sub-systems of a physical system. Using the replica trick, we can obtain the EE by evaluating the entanglement Renyi entropy (ERE). The ERE is a q-analogue of the EE and expressed by the q replicated partition function. In the semi-classical approximation, it is apparently easy to calculate the EE because the classical action represents the partition function by the saddle point approximation and we do not need to perform the path integral for the evaluation of the partition function. In previous studies, it has been assumed that only the minimal-valued saddle point contributes to the EE. In this paper, we propose that all the saddle points contribute comparably but not necessarily equally to the EE by dealing carefully with the semi-classical limit and then the q→1 limit. For example, we numerically evaluate the ERE of two disjoint intervals for the large c Liouville field theory with q∼1. We exploit the BPZ equation with the four twist operators, whose solution is given by the Heun function. We determine the ERE by tuning the behavior of the Heun function such that it becomes consistent with the geometry of the replica manifold. We find the same two saddle points as previous studies for q∼1 in the above system. Then, we provide the ERE for the large but finite c and the q∼1 in case that all the saddle points contribute comparably to the ERE. In particular, the ERE is the summation of these two saddle points by the same weight, due to the symmetry of the system. Based on this work, it shall be of interest to reconsider EE in other semi-classical physical systems with multiple saddle points.     

VT Compensation Circuit for AM OLED Displays Composed of Two TFTs and One Capacitor

In this paper, we propose the threshold-voltage compensation pixel circuit that is composed of two thin-film transistors (TFTs) and one capacitor (2T1C). It not only compensates the deviation of the threshold voltage of the driver TFT but also actualizes the large aperture ratio for organic light-emitting diode (OLED) devices as well as the traditional 2T1C circuit. We show the result of SPICE simulation for the pixel circuit; it indicates that the circuit can allocate the relatively large aperture ratio for OLED devices     

The 59Co nuclear magnetic resonances in the intermetallic compounds

The anisotropic hyperfine fields of the intermetallic compounds have been studied by the spin echo method and were obtained from the NMR spectra of ⁵⁹Co nuclei in ThCo₅ and YCo₅ which have the high anisotropy fields resulting from the orbital moments. The intermetallic compounds, ThCo_5.3 and YCo_5.3, have been also investigated.     

Direct numerical simulation of homogeneous stratified rotating turbulence

The effects of the Prandtl number on stratified rotating turbulence have been studied in homogeneous turbulence by using direct numerical simulations and a rapid distortion theory. Fluctuations under strong stable-density stratification can be theoretically divided into the WAVE and the potential vorticity (PV) modes. In low-Prandtl-number fluids, the WAVE mode deteriorates, while the PV mode remains. Imposing rotation on a low-Prandtl-number fluid makes turbulence two-dimensional as well as geostrophic; it is found from the instantaneous turbulent structure that the vortices merge to form a few vertically-elongated vortex columns. During the period toward two-dimensionalization, the vertical vortices become asymmetric in the sense of rotation. Communicated by S. Obi PACS 47.55.Hd