Strange baryoniums: Their spectrum,decay and production

Using a quark-gluon model we study exhaustively the states with $\text{qq}\text{q}\text{q}$, where at least one q is a strange quark. The spectrum is extremely rich, but a few trajectories are singled out by their distinctive decay pattern and production mechanism. States of unusual colour content, formed from a diquark in colour-6 and an antidiquark in $\text{6}\text{-}\text{colour}$, are weakly coupled to $\text{B}\text{B}$ or two-meson channels through decay. Instead they prefer to cascade by emitting a π or a K if possible. Narrow $\text{Λ}\text{N}$ states among these are expected to be seen in Kp interactions. States with S = 2 will occur with $\text{K}{}^{\mathrm{?}}\text{Λ}\text{p}\text{or K}{}^{\mathrm{+?}}\text{gL}\text{p}$ final states, but not for example $\text{π}\text{Λ}\text{Λ}$. Some of these can be produced diffractively, with cross sections in the region of 1 μb. Those that require quantum-number exchange for production are expected to have considerably lower cross sections. Some can occur as cascade decay products.     

Chiral amplification in one-dimensional helical nanostructures self-organized from phenylethynyl thiophene with elaborated long-chain dicarboxamides

A bis-phenylethynyl thiophene derivative functionalized with long-chain pyridyl biscarboxamides displayed unique helical morphology in the xerogel form via nicely complementary intermolecular interactions. The helical nanostructures visualized by TEM and AFM remarkably matched well with the computational results. Supramolecular chirality can be amplified by coassembly of a chiral conductor to bias the helical arrangement.     

Synthesis, characterization and catalytic activity of lithium and sodium iminophenoxide complexes towards ring-opening polymerization of L-lactide

A series of lithium and sodium iminophenoxide complexes have been successfully synthesized and characterized by X-ray crystallography and investigated as catalysts for the ring opening polymerization of L-lactide. The nature and steric bulk of the ligands coordinated to the central metal ions greatly influence the catalytic properties. Complexes with bidenate ligands exhibit higher catalytic activity than tridentate counterparts because the third coordination atom contends with L-lactide, which decreases activity. Oxygen is the third atom in the tridentate ligand, providing stronger chelation ability with Li and Na than nitrogen or sulfur and occupies the space with which L-lactide is coordinated.     

Evolutionary Pareto optimizers for continuous review stochastic inventory systems

Multi-objective inventory control has been studied for a long time. The trade-off analysis of cycle stock investment and workload, so called the exchange curve concept, possibly dates back to several decades ago. A classical way to such trade-off analysis is to utilize the Lagrangian relaxation technique or interactive method to search for the optimum in a sequence of single objective optimization problems. However, the field of optimization has been changed over the last few decades since the concept of evolutionary computation was introduced. In this paper, a continuous review stochastic inventory system with three objectives about cost and shortage is resolved by evolutionary computation in order to plan for the control policies under backordering and lost sales. Two evolutionary optimizers, multi-objective electromagnetism-like optimization (MOEMO) and multi-objective particle swarm optimization (MOPSO), are employed to well and fast approximate the non-dominated policies in term of lot size and safety stock. Trade-offs are observed in a non-dominated set that no one excels the others in all objectives. Computational results show that the evolutionary Pareto optimizers could generate trade-off solutions potentially ignored by the well-known simultaneous method. Comparisons between the results of backordering and lost sales indicate that decision makers will make more deliberate choices about lot sizing and safety stocking when unsatisfied demand is completely lost.     

Asymmetric synthesis of dihydroquinazolinones via directed ortho metalation and addition to tert-butanesulfinyl imines

An asymmetric route to dihydroquinazolinones via the addition of ortho metalated substrates to tert-butanesulfinyl imines is reported. The scope of the nucleophile and electrophile components and the absolute stereochemical outcome are presented.     

Advective flow and floc permeability

This work monitored advection flow through a floc by bubble tracking. Close examination of the motion of a swarm of hydrogen bubbles that passed over a free-falling floc allowed the extent of advection flow to be estimated at 53% for the original activated sludge floc, and 12% for the flocculated floc. The interior permeability of the sludge flocs was estimated from this information. The fluid force exerted on the falling floc was also considered.     

Chemistry of platensimycin

Platensimycin is a novel natural product antibiotic that inhibits bacterial growth by inhibiting fatty acid synthesis specifically inhibiting the elongation condensing enzyme FabF. Reaction with diazomethane at controlled temperatures led to selective methylation of the phenolic groups. Methylation, halogenation, reduction, epoxidation, Bayer-Villiger oxidation and details of the conversion of dihydroplatensimycin to the cyclic enamino-amido forms have been described.     

New members of a class of dinitrosyliron complexes (DNICs): interconversion and spectroscopic discrimination of the anionic {Fe(NO)2}9 [(NO)2Fe(C3H3N2)2]- and [(NO)2Fe(C3H3N2)(SR)]- (C3H3N2 = deprotonated imidazole; R = tBu, Et, Ph)

The anionic {Fe(NO)2}(9) DNIC[(NO)2Fe(C3H3N2)2](-) (2) (C3H3N2 = deprotonated imidazole) containing the deprotonated imidazole-coordinated ligands and DNICs [(NO)2Fe(C3H3N2)(SR)](-) (R = (t)Bu(3), Et(4), Ph(5)) containing the mixed deprotonated imidazole-thiolate coordinated ligands, respectively, were synthesized by thiol protonation or thiolate(s) ligand-exchange reaction. The anionic {Fe(NO)2}(9) DNICs 2- 5 were characterized by IR, UV-vis, EPR, and single-crystal X-ray diffraction. The facile transformation among the anionic {Fe(NO)2}(9) DNICs 2- 5 and [(NO)2Fe(S(t)Bu)2](-)/[(NO)2Fe(SEt)2](-)/[(NO)2Fe(SPh)2](-) was demonstrated in this systematic study. Of importance, the distinct electron-donating ability of thiolates serve to regulate the stability of the anionic {Fe(NO)2}(9) DNICs and the ligand-substitution reactions of DNICs. At 298 K, DNIC 2 exhibits the nine-line EPR signal with g = 2.027 (aN(NO) = 2.20 and aN(Im-H) = 3.15 G; Im-H = deprotonated imidazole) and DNIC 3 displays the nine-line signals with g = 2.027 (aN(NO) = 2.35 and aN(Im-H) = 4.10 G). Interestingly, the EPR spectrum of complex 4 exhibits a well-resolved 11-line pattern with g = 2.027 (aN(NO) = 2.50, aN(Im-H) = 4.10 G, and aH = 1.55 G) at 298 K. The EPR spectra (the pattern of hyperfine splitting) in combination with IR nu NO spectra (DeltanuNO = the separation of NO stretching frequencies, DeltanuNO = approximately 62 cm (-1) for 2 vs approximately 50 cm(-1) for 3- 5 vs approximately 43 cm(-1) for [(NO)2Fe(S(t)Bu)2](-)/[(NO)2Fe(SEt)2](-)/[(NO)2Fe(SPh)2](-)) may serve as an efficient tool for the discrimination of the existence of the anionic {Fe(NO)2}(9) DNICs containing the different ligations [N,N]/[N,S]/[S,S].