Nonlinear effects in coherent multichannel transmission throughoptical fibers

Various nonlinear optical interactions in single-mode fibers that are used in coherent FDM (frequency division multiplexed) transmission systems are examined. It is these nonlinearities that lead to crosstalk between channels, power losses, and deleterious fluctuations, which in turn limit the power of the transmitted light and the number of allowed channels, and dictate the channel allocations. It is shown that, for long-haul transmission systems with fiber lengths exceeding 100 km, typical channel separation of 10 GHz, and few channels, the maximum allowed input power per channel, P_max, is limited by SBS (stimulated Brillouin scattering) to about 5 dBm. As the number of channels increases, FWM (four wave mixing) becomes the limiting process with P_max of about -5 dBm, whereas above several hundred channels SRS (stimulated Raman scattering) becomes dominant with P_max of about -5 dBm. For local area networks with shorter lengths, the results are similar, except that the values of P_max are uniformly higher by about 5 dB     

Regioselective Arene Functionalization: Simple Substitution of Carboxylate by Alkyl Groups

Arenes with various alkyl side‐chains were synthesized in high yields and excellent regioselectivities. Starting from toluic and naphthoic acids, the carboxylate group was conveniently substituted by alkyl halides by Birch reduction and subsequent decarbonylation. The method is characterized by inexpensive starting materials and reagents, and methylation of arenes was realized. Besides simple alkyl substituents, the scope of arene functionalization was extended by benzyl, fluoro, amino, and ester groups. We were able to control the alkylation of 1‐naphthoic acid during Birch reduction by the addition of tert‐butanol. This allowed the regioselective synthesis of mono and bis‐substituted naphthalenes from the same starting material.     

Ten-channel coherent optical fibre transmission

A laboratory ten-channel coherent fibre-optic broadband transmission system is reported. The frequency-division-multiplexed optical carriers are separated by 6 GHz and are demultiplexed by a tunable heterodyne receiver having a sensitivity of -46 dBm at a bit error rate of 10-9. In this system a maximum number of 64 channels can be installed.     

Two types of limit cycles of a resonant converter modelled by a three-dimensional system

In this paper, the long-run dynamics of a resonant converter is studied. The modelling of the resonant converter can be done using various approximations and the long-run dynamics of the two dimensional cases were earlier analysed. In this paper, we discuss results that can be extended to the three dimensional case. It seems that limit cycles describe the long-run dynamics in important situations in the three dimensional case, too. Our objective is to relate the limit cycles found previously in the two-dimensional case to those found now in the three dimensional approximation.     

Synthesis of rigid photoswitchable hemithioindigo ω-amino acids

The synthesis of novel N-Boc- and N-Fmoc protected hemithioindigo-based ω-amino acids is described. An approach to modulate the thermal stability of a hemithioindigo subunit is presented. Placing the amino-group in the stilbene part from the para- to meta-position leads to an increase of the half-life of the thermally labile E-form from 19 h to 47 h.     

Synthesis and Structures of Gallium‐β‐Diketiminate Complexes: Isolation of a Dinuclear Gallium(II) Complex

The sterically demanding β‐diketiminate ligand L^dmp [L^dmp = HC{(CMe)N(dmp)}₂, dmp = C₆H₃‐2,6‐Me₂] was used to stabilize various gallium complexes in the formal oxidation states +II and +III. The reaction of in situ generated [L^dmpLi] with gallium chloride affords [L^dmpGaCl₂] ( 1 ), which was used as starting complex to synthesize a variety of gallium(III) compounds [L^dmpGaX₂] [X = F ( 2 ), I ( 3 ), H ( 4 ), and Me ( 5 )]. Synthesis of the dinuclear complex [L^dmpGaI]₂ ( 6 ), with gallium in the formal oxidation state +II was accomplished by converting “GaI” with in situ generated [L^dmpLi] in toluene. All compounds were characterized by elemental analyses, NMR spectroscopy, LIFDI‐TOF‐MS, and single‐crystal X‐ray diffraction. Additionally DFT calculations were performed for analysis of the bonding in 6 .