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151.
Dietrich Braun 《Macromolecular Symposia》1986,4(1):41-42
Methyl methacrylate, benzyl methacrylate, butyl methacrylate, and methacrylic acid can be polymerized by 1, 2, 2-tetraphenyl-1, 2-diphenoxyethane (TPPA), 1, 1, 2, 2-tetraphenyl-1, 2-bis-(trimethylsiloxy) ethane (TPSA), and 1, 1, 2, 2-tetraphenyl-1, 2-dicyanoethane (TPCA) (1–3). The polymerization with these initiators is characterized by three steps; in the first period oligomers from MMA and initiator radicals are formed by primary radical termination. 相似文献
152.
Torsten Enßlin 《Entropy (Basel, Switzerland)》2022,24(3)
Information field theory (IFT), the information theory for fields, is a mathematical framework for signal reconstruction and non-parametric inverse problems. Artificial intelligence (AI) and machine learning (ML) aim at generating intelligent systems, including such for perception, cognition, and learning. This overlaps with IFT, which is designed to address perception, reasoning, and inference tasks. Here, the relation between concepts and tools in IFT and those in AI and ML research are discussed. In the context of IFT, fields denote physical quantities that change continuously as a function of space (and time) and information theory refers to Bayesian probabilistic logic equipped with the associated entropic information measures. Reconstructing a signal with IFT is a computational problem similar to training a generative neural network (GNN) in ML. In this paper, the process of inference in IFT is reformulated in terms of GNN training. In contrast to classical neural networks, IFT based GNNs can operate without pre-training thanks to incorporating expert knowledge into their architecture. Furthermore, the cross-fertilization of variational inference methods used in IFT and ML are discussed. These discussions suggest that IFT is well suited to address many problems in AI and ML research and application. 相似文献
153.
Medium Access Control (MAC) protocols for Wireless Sensor Networks (WSN) are usually designed as random access protocols that apply different kinds of backoff strategies since Time Division Multiple Access (TDMA) based protocols with admission control are very complex and require additional mechanisms for synchronization. Without such mechanisms, fair or priority based medium access with Quality of Service (QoS) guarantees can hardly be achieved by existing protocols. Therefore, we developed a random access protocol which uses a new preamble-based medium access strategy that enables collision-free priority based access without the need of synchronization. In this paper we introduce different QoS strategies and their use cases. All strategies can be easily integrated in our protocol to meet the requirements of different target applications. Furthermore, we compare the performance of the strategies with a typical carrier-sense based protocol. 相似文献
154.
H. Braun 《The European physical journal. Special topics》2009,174(1):33-47
Large-amplitude climate shifts, the so-called Dansgaard-Oeschger events, repeatedly occurred throughout the last ice age.
These events, which are apparently threshold-crossing events, show a reported tendency to recur preferably in near multiples
of about 1470 years. Several non-linear resonance mechanisms were proposed to explain this recurrence pattern in response
to noise and/or periodic forcing. Standard methods of linear time series analysis are not sufficient to distinguish between
these hypotheses, owing to the threshold-crossing dynamics of the events. Recently, new approaches were made by means of null-hypothesis
testing with Monte Carlo methods. A major hurdle in this approach is the need of efficient, but yet simple measures of regularity
that allow to distinguish between the proposed resonance mechanisms. By means of surrogate time series (i.e. by using a large
ensemble of Dansgaard-Oeschger events as simulated with a very simple two-state model) I here test the ability of three standard
measures of periodicity to distinguish between a scenario of solely noise-induced events and a ghost stochastic resonance
scenario. Only one measure is found to be applicable for that purpose. The choice of adequate measures, which is not trivial,
should be given more attention in future studies that focus on the question what triggered threshold-crossing events such
as Dansgaard-Oeschger events. 相似文献
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Inside Back Cover: Circularly Polarized Luminescence from Axially Chiral BODIPY DYEmers: An Experimental and Computational Study (Chem. Eur. J. 45/2016)
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