基于多元高斯混合模型的离线指纹数据库

针对室内环境下单次采样测量值的波动变化及信号间的相互干扰,该文提出一种基于分区多元高斯混合模型(MVGMM)的室内定位系统.根据信号接入点(AP)铺设位置与空间结构,系统采用一对多支持向量机算法对目标区域做分区操作,以精确信号变化的区域范围.利用狭小分区内信号间的耦合关系,建立基于信号间相互干扰的多元高斯混合模型,以改善信号波动所造成的定位精度下降.当室内环境发生变化时,基于分区多元高斯混合模型的自适应更新算法可对各分区指纹数据的可信度做出判断,并以自适应算法更新信号波动较大分区的模型参数,提高模型与现有环境间的耦合程度.实验结果表明,该文算法可利用相对少量样本数据,构建稳定可维护的室内信号分布模型,相较于其他算法,其定位精度也有一定程度提高.     

Mechanism of lamellar spacing adjustment in directionally frozen agar gels

A theory is presented for predicting the size of ice crystals which result from steady-state, unidirectional growth within aqueous agar gels. Cellular arrays of adjacent ice crystals were separated by an amorphous water-agar membrane at a composition near the vitrification point. Using this vitrification composition and both a steady-state condition and a minimum free energy criterion, the size of ice crystals was predicted for a given solidification velocity and diffusion condition. It was found, however, that this simple model could not predict the trend towards larger crystal sizes that was observed when the initial agar concentration in the gels increased from 3% to 10% by weight agar.     

Facile Total Synthesis of (±)‐Nimbiol

A facile total synthesis of (±)‐nimbiol 1 has been achieved. In order to decrease the dioxo byproduct 2a , an improved oxidation system of CrO₃/H₂O/HOAc/NaOAc was used.     

Studies on Chemical Constituents of Polygonum Ciliinerve Ohwi

Three new apianen lactones Maomailiaoine I ( 1 ), Maomailiaoine II ( 2 ) and Maoimaliaoine III ( 3 ), together with one known apianen lactone, five known flavonoids and three other known compounds were isolated from Polgonum ciliinerve Ohwi. Their structures were deduced from spectroscopic methods and 2D NMR techniques.     

亲脂类分子增溶剂单2－氧一（2一羟基丙基）一β一环糊精（单2一HP一β一CD）的制备及其NMR表征

文中就亲脂类分子增溶剂单２－ＨＰ－β－ＣＤ的合成作了研究，产率从文献报道的５％提高到２８％。文中还给出了产物的ＮＭＲ数据。