RFID系统防碰撞协议研究——设计与优化

碰撞问题是影响射频识别(RFID)系统读取效率的关键问题。该文提出了两种新的防碰撞协议CDCA协议和CDCA-2D协议,并且对两种协议进行了详细的理论分析和优化。新协议将RFID系统的读取过程分为两个阶段,利用第1阶段的碰撞检测信息实现在第2个阶段的无碰撞通信。仿真结果表明,和目前国际上流行的RFID防碰撞算法相比,两种新协议极大地提高了读取的效率。     

Large deviation principles for Euclidean functionals and other nearly additive processes

We prove a large deviation principle for a process indexed by cubes of the multidimensional integer lattice or Euclidean space, under approximate additivity and regularity hypotheses. The rate function is the convex dual of the limiting logarithmic moment generating function. In some applications the rate function can be expressed in terms of relative entropy. The general result applies to processes in Euclidean combinatorial optimization, statistical mechanics, and computational geometry. Examples include the length of the minimal tour (the traveling salesman problem), the length of the minimal matching graph, the length of the minimal spanning tree, the length of the k-nearest neighbors graph, and the free energy of a short-range spin glass model. Received: 3 April 1999 / Revised version: 23 June 1999 / Published online: 8 May 2001     

Theoretical study of some 1,3-substituted (1,3-diketonato)borondifluorides. Potential energy curve relevant to the barrier crossing reaction

Ab initio Hartree-Fock calculations utilising STO-3G, 3-21G^* and 6-31G^* basis sets have been performed on three neutral and highly polar molecules, (diformylmethine)borondifluoride, (acetylacetonato)borondifluoride and (dibenzylmethine) borondifluoride. The calculated and experimental structures are well correlated when using the HF/3-21G^* basis set, except for the structure parameters involving the boron atom. The HF/6-31G^* basis set does not improve the accuracy in structure calculations. The conformational analysis is in agreement with the experimentally observed C_2v symmetrical structures, where the boron atom is tetrahedrally coordinated. The calculations support a one-dimensional ground state barrier crossing reaction for (dibenzylmethine)borondifluoride, where the phenyl torsion is the most likely reaction coordinate. Both HF/6-31G^* calculations and the second-order Møller-Plesset correction with the 3-21G^* basis set suggest an activation energy of the ground state reaction of about 30 kJ mol⁻¹. The ground state barrier crossing reaction kinetics is evaluated by the Kramers theory. The calculated ground state parameters relevant to the barrier crossing reaction are compared with the experimentally observed excited state values.     

A twisted Laurent series ring that is a noncrossed product

The striking results on noncrossed products were their existence (Amitsur [1]) and the determination of ℚ(t) and ℚ((t)) as their smallest possible centres (Brussel [3]). This paper gives the first fully explicit noncrossed product example over ℚ((t)). As a consequence, the use of deep number theoretic theorems (local-global principles such as the Hasse norm theorem and density theorems) in order to prove existence is eliminated. Instead, the example can be verified by direct calculations. The noncrossed product proof is short and elementary. Supported in part by the DAAD (Kennziffer D/02/00701).     

Conformational analysis XX—13C NMR studies of saturated heterocycles 5—substituent effects on the 13C chemical shifts of methyl substituted 1,3-dithiolanes

The ¹³C NMR chemical shifts for 1,3-dithiolane and 13 methyl substituted derivatives are reported. Substituent effects are derived and compared with those for cyclopentanes and 1,3-dioxolanes. The magnitude and variety of the substituent effects are best explained with the aid of a half-chair conformation where the S-1? C-2? S-3 plane passes between C-4 and C-5.     

Calculation of electric-field gradients based on higher-order generalized Douglas-Kroll transformations

In this paper, the calculation of electric-field-like properties based on higher-order Douglas-Kroll-Hess (DKH) transformations is discussed. The electric-field gradient calculated within the Hartree-Fock self-consistent field framework is used as a representative property. The properties are expressed as an analytic first derivative of the four-component Dirac energy and the nth-order DKH energy, respectively. The differences between a "forward" transformation of the relativistic energy or the "back transformation" of the wave function is discussed in some detail. Detailed test calculations were carried out on the electric-field gradient at the halogen nucleus in the series HX (X=F,Cl,Br,I,At) for which extensive reference data are available. The DKH method is shown to reproduce (spin-free) four-component Dirac-Fock results to an accuracy of better than 99% which is significantly closer than previous DKH studies. The calculations of both the Hamiltonian and the property operator are shown to be essentially converged after the second-order transformation, even for elements as heavy as At. In addition, we have obtained results within the density-functional framework using the DKHZ and zeroth-order regular approximation (ZORA) methods. The latter results included picture-change effects at the scalar relativistic variant of the ZORA-4 level and were shown to be in quantitative agreement with earlier results obtained by van Lenthe and Baerends. The picture-change effects are somewhat smaller for the ZORA method compared to DKH. For heavier elements significant differences in the field gradients predicted by the two methods were found. Based on comparison with four-component Dirac-Kohn-Sham calculations, the DKH results are more accurate. Compared to the spin-free Dirac-Kohn-Sham reference values, the ZORA-4 formalism did not improve the results of the ZORA calculations.     

Exploring k and ? with R–Equation Model Using Elliptic Relaxation Function

An extended version of the isotropic R?Cequation model accompanied by an elliptic relaxation approach to account for the distinct effects of low-Reynolds number (LRN) and wall proximity is proposed. The turbulent kinetic energy k and the dissipation rate ? are evaluated using the R ( $=k^2/\tilde{\epsilon}$ ) transport equation together with some empirical relations. The eddy viscosity formulation maintains the positivity of normal Reynolds stresses and the Schwarz?? inequality for turbulent shear stresses. The model coefficients/functions preserve the anisotropic characteristics of turbulence in the sense that they are sensitized to rotational and nonequilibrium flows. The model is validated against a few well-documented flow cases, yielding predictions in good agreement with the direct numerical simulation (DNS) and experimental data. Comparisons indicate that the present model offers some improvement over the Spalart?CAllmaras one?Cequation model and competitiveness with the SST k?C?? model.     

Active Molybdenum‐Based Anode for Dehydrogenative Coupling Reactions

A new and powerful active anode system that can be operated in 1,1,1,3,3,3‐hexafluoro‐2‐propanol (HFIP) has been discovered. In HFIP the molybdenum anode forms a compact, conductive, and electroactive layer of higher‐valent molybdenum species. This system can replace powerful but stoichiometrically required Mo^V reagents for the dehydrogenative coupling of aryls. This electrolytic reaction is more sustainable and allows the conversion of a broad scope of activated arenes.