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51.
2-chloro-1,3,2-diazastibolenes react with Lewis acids either via Sb-Cl cleavage to yield stable Sb-analogues of an N-heterocyclic carbene, or via an unprecedented oxidative fragmentation to give a diazadiene-SbCl3 complex. 相似文献
52.
Anomalous absorption of bulk shear sagittal acoustic waves in a layered structure with viscous fluid
It is demonstrated theoretically that the absorptivity of bulk shear sagittal waves by an ultra-thin layer of viscous fluid between two different elastic media has a strong maximum (in some cases as good as 100%) at an optimal layer thickness. This thickness is usually much smaller than the penetration depths and lengths of transverse and longitudinal waves in the fluid. The angular dependencies of the absorptivity are demonstrated to have significant and unusual structure near critical angles of incidence. The effect of non-Newtonian properties and non-uniformities of the fluid layer on the absorptivity is also investigated. In particular, it is shown that the absorption in a thin layer of viscous fluid is much more sensitive to non-zero relaxation time(s) in the fluid layer than the absorption at an isolated solid-fluid interface. 相似文献
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Timo Seppä lä inen 《Transactions of the American Mathematical Society》2001,353(12):4801-4829
We prove laws of large numbers for a second class particle in one-dimensional totally asymmetric -exclusion processes, under hydrodynamic Euler scaling. The assumption required is that initially the ambient particle configuration converges to a limiting profile. The macroscopic trajectories of second class particles are characteristics and shocks of the conservation law of the particle density. The proof uses a variational representation of a second class particle, to overcome the problem of lack of information about invariant distributions. But we cannot rule out the possibility that the flux function of the conservation law may be neither differentiable nor strictly concave. To give a complete picture we discuss the construction, uniqueness, and other properties of the weak solution that the particle density obeys.
55.
Jyrki Ari Timo Mika 《AEUE-International Journal of Electronics and Communications》2007,61(2):118-126
In this paper we present a packet scheduling method which guarantees bandwidth of the connection and optimizes revenue of the network service provider. A closed form formula for updating the adaptive weights of a packet scheduler is derived from a revenue-based optimization problem. The weight updating procedure is fast and independent on the assumption of the connections’ statistical behavior. The features of the algorithm are simulated and analyzed with and without a call admission control (CAC) mechanism. We also show in context with the CAC procedure a mechanism for guaranteeing a specified mean bandwidth for different service classes. 相似文献
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57.
Laura Äkäslompolo Ana M. Sánchez Qi Hang Qin Antti Hakola Timo Kajava Sebastiaan van Dijken 《Applied Physics A: Materials Science & Processing》2013,110(4):889-894
We report on the growth of all-oxide SrRuO3/CoFe2O4/La2/3Sr1/3MnO3 and La2/3Sr1/3MnO3/CoFe2O4/SrRuO3 heterostuctures on SrTiO3(001) and MgO(001) substrates by pulsed laser deposition. Structural analyses by X-ray diffraction and transmission electron microscopy clearly indicate the preservation of epitaxial relations when the La2/3Sr1/3MnO3 layer is grown first, whereas trilayers with SrRuO3 at the bottom are more disordered. Both the substrate material and the deposition sequence strongly influence the formation of various structural defects such as interfacial dislocations and sub-grain structures, and this is clearly reflected by a reduction of the saturation magnetization in the top electrode. When the substrate material and the deposition sequence are correctly chosen, however, the magnetic moments of the La2/3Sr1/3MnO3 and SrRuO3 layers reverse independently, and the La2/3Sr1/3MnO3 layer retains bulk-like magnetic properties. 相似文献
58.
Erkki Aitola Kimmo Hakala Hedvig Byman‐Fagerholm Markku Leskelä Timo Repo 《Journal of polymer science. Part A, Polymer chemistry》2008,46(1):373-382
The influence of ligand structure on copolymerization properties of metallocene catalysts was elucidated with three C1‐symmetric methylalumoxane (MAO) activated zirconocene dichlorides, ethylene(1‐(7, 9)‐diphenylcyclopenta‐[a]‐acenaphthadienyl‐2‐phenyl‐2‐cyclopentadienyl)ZrCl2 ( 1 ), ethylene(1‐(7, 9)‐diphenylcyclopenta‐[a]‐acenaphthadienyl‐2‐phenyl‐2‐fluorenyl)ZrCl2 ( 2 ), and ethylene(1‐(9)‐fluorenyl‐(R)1‐phenyl‐2‐(1‐indenyl)ZrCl2 ( 3 ). Polyethenes produced with 1 /MAO had considerable, ca. 10% amount of trans‐vinylene end groups, resulting from the chain end isomerization prior to the chain termination. When ethene was copolymerized with 1‐hexene or 1‐hexadecene using 1 /MAO, molar mass of the copolymers varied from high to moderate (531–116 kg/mol) depending on the comonomer feed. At 50% comonomer feed, ethene/1‐olefin copolymers with high hexene or hexadecene content (around 10%) were achievable. In the series of catalysts, polyethenes with highest molar mass, up to 985 kg/mol, were obtained with sterically most crowded 2 /MAO, but the catalyst was only moderately active to copolymerize higher olefins. Catalyst 3 /MAO produced polyethenes with extremely small amounts of trans‐vinylene end groups and relatively low molar mass 1‐hexene copolymers (from 157 to 38 kg/mol) with similar comonomer content as 1 . These results indicate that the catalyst structure, which favors chain end isomerization, is also capable to produce high molar mass 1‐olefin copolymers with high comonomer content. In addition, an exceptionally strong synergetic effect of the comonomer on the polymerization activity was observed with catalyst 3 /MAO. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 46: 373–382, 2008 相似文献
59.
A simple and general standard-addition method for a single-component determination is presented. The method uses two independent variables for the calculation of the analyte concentration (the amount of sample taken and the amount of analyte added) and one dependent variable, the response. The sensitivity and the response of the blank can also be estimated from the model by changing the amount of the sample and the amount of the analyte addition. In the simples case, a linear equation is assumed to exist between the variables. Geometrically, the model can be expressed by the response plane in the variable-space. The method has all the advantages of the ordinary standard-addition method but also includes automatic blank elimination and versatile matrix-interference control. Two examples of the use of the method are based on graphite-furnace atomic absorption spectrometry of chromium and lead. Standard statistical packages are applied. 相似文献
60.