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101.
E. Birckner U.-W. Grummt H. Rost A. Hartmann S. Pfeiffer H. Tillmann H.-H. Hörhold 《Journal of fluorescence》1998,8(1):73-80
The absorption and fluorescence of substituted distyrylbenzene (DSB) derivatives and segmented poly(phenylene vinylene) (PPV)
derivatives are characterized by long-wavelength absorption maxima and absorption coefficients of λa = 380–450 nm, ε = 20,000–60,000 M−1 cm1 and fluorescence maxima, quantum yields, and decay times of λr = 440–530 nm, Φf = 0.2–0.9, and Τ = 0.8–2.5 ns, respectively. Alkoxy substituents at the central phenylene ring of DSB groups increase the
bathochromic shift in the spectra in comparison to DSB, without a significant decrease in the high DSB fluorescence quantum
yield. Both phenyl and cyano substitutions at the vinylene bridge lead to a further bathochromic shift of the fluorescence
and a decrease in the quantum yield to ca. 0.4. The DSB derivatives and the related segmented PPV derivatives show nearly
the same absorption spectra, fluorescence spectra, and radiative rate constantsk
f= Φf/Τ, indicating the efficacy of the segmentation of the polymer chain. The radiative rate constants determined by the Φf and Τ values and by the Strickler/Berg formula are in reasonable agreement. This supports the possibility of interpreting
the properties of the polymers in terms of their DSB units. The decrease in the emission anisotropy can be ascribed to multistep
energy transfer processes between different oriented segments. 相似文献
102.
103.
A. Tillmann S. Buschbaum S. Frigge U. Kreiser D. Lffelmacher T. Theilig P. Schmid 《Materials Science in Semiconductor Processing》1998,1(3-4)
The modelling of a new 300 mm rapid thermal processing (RTP) system is described. Conventional raytracing techniques are used to determine lamp intensity distributions on both 200 and 300 mm wafers. Simulation results are verified using the ‘difference method' (difference between two process parameter distributions such as oxide thickness, where the absolute power of one single lamp is varied). Wafer rotation is incorporated in the model and its influence on the temperature distribution will be discussed. Off-line optimization of the temperature distribution is utilized using model-based control. Experimental results of implant annealing on both 200 and 300 mm are shown and critical parameters influencing the temperature uniformity are discussed. 相似文献
104.
105.
Jan Tillmann Hans‐Wolfram Lerner Michael Bolte 《Acta Crystallographica. Section C, Structural Chemistry》2014,70(12):1092-1095
We have determined the crystal structures of two tetrachloridoaluminate salts. Tetrabutylammonium tetrachloridoaluminate benzene hemisolvate, (C16H36N)[AlCl4]·0.5C6H6, (I), crystallizes with discrete cations, anions and solvent molecules. The benzene molecule is located on a centre of inversion. The structure of the benzene‐free polymorph has been determined previously. Tetraethylammonium tetrachloridoaluminate, (C8H20N)[AlCl4], (II), also crystallizes with discrete cations and anions, and forms crystals which appear trigonal but are actually orthorhombic. With the additional reflections of the second and third domains of this nonmerohedral twin, a trigonal lattice is emulated, although the correct crystal system is orthorhombic. 相似文献
106.
W. Holzer A. Penzkofer T. Pertsch N. Danz A. Bräuer E.B. Kley H. Tillmann C. Bader H.-H. Hörhold 《Applied physics. B, Lasers and optics》2002,74(4-5):333-342
Wave-guided thin-film distributed-feedback (DFB) polymer lasers are fabricated by spin coating a PPV-derived semiconducting
polymer, thianthrene-DOO-PPV, onto oxidised silicon wafers with corrugated second-order periodic gratings. The gratings are
written by reactive ion beam etching. Laser action is achieved by transverse pumping with picosecond laser pulses (wavelength
347.15 nm, duration 35 ps). The DFB-laser surface emission and edge emission are analysed. Outside the grating region the
polymer film is used for comparative wave-guided travelling wave laser (amplified spontaneous emission (ASE)) studies. The
pump pulse threshold energy density for wave-guided DFB-laser action (4–9 μJ cm-2) is found to be approximately a factor of two lower than the threshold for wave-guided travelling wave laser action. The
spectral width of the DFB laser (down to ΔλDFB≈0.07 nm) is considerably narrower than that of the travelling wave laser (ΔλTWL≈14 nm). The DFB-laser emission is highly linearly polarised transverse to the grating axis (TE mode). Only at high pump pulse
energy densities does an additional weak TM mode build up. The surface-emitted DFB-laser radiation has a low divergence along
the grating direction. For both the DFB lasers and the travelling wave lasers, gain saturation occurs at high excitation energy
densities.
Received: 7 January 2002 / Revised version: 15 February 2002 / Published online: 14 March 2002 相似文献
107.
Heinz Günther Tillmann 《Mathematische Annalen》1963,151(5):424-430
Ohne Zusammenfassung 相似文献
108.
Heinz Günther Tillmann 《Archiv der Mathematik》1960,11(1):194-199
Ohne Zusammenfassung 相似文献
109.
110.