BaCe0.8Ho0.2O3-a陶瓷的性质与应用

Ceramic BaCe0.8Ho0.2O3-α with orthorhombic perovskite structure was prepared by conventional solid state reaction, and its conductivity and ionic transport number were measured by ac impedance spectroscopy and gas concentration cell methods in the temperature range of 600-1000 ℃ in wet hydrogen and wet air, respectively. Using the ceramics as solid electrolyte and porous platinum as electrodes, the hydrogen-air fuel cell was constructed, and the cell performance at temperature from 600-1000 ℃ was examined. The results indicate that the specimen was a pure protonic conductor with the protonic transport number of 1 at temperature from 600-900 ℃ in wet hydrogen, a mixed conductor of proton and electron with the protonic transport number of 0.99 at 1000 ℃. The electronic conduction could be neglected in this case, thus the total conductivity in wet hydrogen was approximately regarded as protonic conductivity. In wet air, the specimen was a mixed conductor of proton, oxide ion and electron hole. The protonic transport numbers were 0.01-0.09, and the oxide-ionic transport numbers were 0.27-0.32. The oxide ionic conductivity was increased with the increase of temperature, but the protonic conductivity displayed a maximum at 900 ℃, due to the combined increase in mobility and depletion of the carriers. The fuel cell could work stably. At 1000 ℃, the maximum short-circuit current density and power output density were 346 mA/cm^2 and 80 mW/cm^2, respectively.     

Study on thermal stability of poled non-linear optical polymers

A logarithmic expression is proposed to describe relaxation of the polar order in side chain polymers,together with a new way of plotting temperature dependent relaxation data.This results in a straight line extending even below the glass transition temperature in the case of poled nonlinear optics (NLO) side chain polymers.A simple procedure to determine the rotational diffusion constant Dr is given and Dr values of several polymer systems have been evaluated and compared with each other.It appears that,starting from the conventional and well known poled polymer system currently applied,a further lowering of Dr by about 3 orders of magnitude is necessary in order to reach an acceptable orientational stability or lifetime of poled polymers for practical applications.Attempts have been made to introduce electron push-pull substituents into high thermostable molecular frameworks and results of preliminary measurements are reported.     

Isolation, Mapping, DNA Sequence and RFLPs Studies of Random Single-Copy DNA Segments on Human X Chromosome

Using the total human/mouse DNA as the probe, screening has been carried out three times with in situ plaque hybridization to obtain the single-copy DNA sequence from the human X chromosome genomic library. The effective rate of screening is 1. 45%. DNAs from clones containing single-copy inserts have been analyzed by a panel of hybrid cells with or without human X chromosome. Three segments, designated by DXFD52,73,75, are mapped to the X chromosome. DXFD52 has been precisely localized on Xq12-q13 with in situ chromosomal hybridization. DXFD52 has been partially sequenced. The results indicate that DXFD52 is a new isolated single-copy segment on the X chromosome. Great progress in the RFLPs study with DXFD52 has been achieved in the population of Chongqing, Sichuan Province. The results show that the DXFD52 can be used to detect the RFLP with Hind Ⅲ, Bgl Ⅱ, and Hinf Ⅰ. DXFD52 will be a potential "landmark" for the construction of the complete linkage map of human genome and the analysis of genomic s     

基于BAS-BP-Bagging模型的光纤陀螺温度补偿

为提高光纤陀螺的输出精度,以天牛须搜索算法(BAS)优化后的BP神经网络模型为基学习器,采用Bagging并行集成学习算法建立了BAS-BP-Bagging温度补偿模型,并对某型号光纤陀螺进行了温度补偿实验。实验结果表明,在-40～+60℃温度变化环境下,该方法补偿后的光纤陀螺温度漂移相较于补偿前减小了近80%,相较于多项式补偿算法减小了55%,相较于BP神经网络补偿算法减小了30%左右。同时该模型在对新鲜样本的补偿过程中表现出了较为优越的泛化性能。     

基于无人机的空地信道特性测量系统

随着各种飞行器和通信一体化的发展,对空地信道特性的研究变得愈发重要且迫切。针对空地通信场景,本文研制了一套由无人机发射单元和地面接收单元组成的无人机空地信道测量系统。该系统选取具有平坦功率谱特性和大动态范围的ZC序列作为测量序列,利用硬件实现实时提取信道冲激响应(Channel Impulse Response, CIR),并通过采样偏差恢复、系统响应校正等方式,提高信道测量系统的准确性。实测验证结果表明,本文研制的信道测量系统与信道模拟器模拟结果和射线跟踪(Ray Tracing, RT)仿真结果基本一致。最后,开展了校园场景空地实测活动,分析了该场景路径损耗(Path Loss, PL)、莱斯K因子、均方根时延扩展(Root Mean Square-Delay Spread, RMS-DS)等信道特性。     

机关档案管理与信息化建设的路径探索

21世纪是信息技术全面普及的时代,我国机关单位也开始寻求多元化的档案管理储存模式,希望借助先进技术提高档案管理水平,优化信息收集与整合路径。但是在落实档案管理信息化建设的实际过程中,依然暴露出了一些问题,这些问题不仅制约了档案管理信息化建设的落实,还阻碍了机关单位档案管理水平的提升。对此,文中通过结合档案管理信息化建设的意义与存在的问题,探讨了相关建设路径,以有效促进机关单位实现档案管理信息化建设,提高档案管理水平。     

Polymer passivation of defects in inorganic perovskite solar cells

Inorganic perovskite solar cells (IPSCs) have attained attention due to their excellent thermal and phase stability. In this work, we demonstrate a novel approach for fabricating IPSCs, using the strategies of interface passivation and anti-solvent before spin-coating perovskite. Poly(methyl methacrylate) (PMMA) and chlorobenzene (CB) are used as passivator and anti-solvent, respectively. The CB improves the perovskite crystal morphology. Meanwhile, PMMA passivates the defects between poly(3, 4-ethylenedioxythiophene)-poly(styrenesulfonate) (PEDOT:PSS) and perovskite layer, thus increasing the short-circuit current. Excitingly, we find that PMMA benefits the grain boundaries (GBs) of perovskite, which makes it more humidity-resistant, increasing the stability of perovskite film. Especially, PMMA mitigates interfacial charge losses, and the devices based on CsPbI3-xBrx passivated by PMMA exhibit the power conversion efficiency (PCE) much higher than those based on pure CsPbI3-xBrx.     

宽频带圆极化缝隙螺旋天线的设计

研究了一种宽阻抗带宽和宽圆极化轴比带宽的缝隙螺旋天线。天线印制在由FR4 介质基板构建的 方形柱状结构的内外表面,两组长短不同的缝隙螺旋臂印制在介质基板外表面并延伸至天线顶部;一条弯折的微带 线作为馈电网络印制在介质基板内表面,通过对各缝隙耦合馈电,实现天线宽阻抗带宽和轴比带宽。实测结果表 明:天线尺寸为0. 111λ0 ×0. 111λ0 ×0. 221λ0(λ0 为北斗B2 中心频率1. 207 GHz 对应的自由空间波长),S11 ≤ -10 dB 的阻抗带宽为1. 158~1. 778 GHz,轴比≤3 dB 的圆极化带宽为1. 133~1. 918 GHz。该天线采用缝隙螺旋结构,通过 简易的馈电网络实现天线小型化和宽频带特性,在卫星导航系统中具有较好的应用前景。     

无人机载PolInSAR城区散射机制初步分析

极化干涉合成孔径雷达（PolInSAR）在城市遥感领域中扮演着重要角色。它能够提高图像的相干性并提高反演结果的精度,所以对于其散射机制的解释往往受到许多研究人员的关注。相关的研究多从极化分解的角度考虑,却少有人从散射中心高度方面进行分析。本文使用Ku波段无人机载极化干涉SAR系统,实现了使用无人机SAR系统对地面进行成像,比较了极化干涉最优分解与Pauli分解作用在不同人造目标时散射中心的关系。我们初步分析了极化干涉SAR的物理意义,并使用C波段的机载极化干涉SAR系统对结论进行验证。