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991.
Multiplex bead-array competitive immunoassay for simultaneous detection of three pesticides in vegetables 总被引:1,自引:0,他引:1
We report on a multiplex bead-based competitive immunoassay using suspension array technology for the simultaneous detection of the pesticides triazophos, carbofuran and chlorpyrifos. Three hapten-protein conjugates were covalently bound to carboxylated fluorescent microspheres to serve as probes. The amount of conjugates and antibodies were optimized. The new multi-analyte assay has dynamic ranges of 0.02–50 ng?mL?1, 0.5–500 ng?mL?1 and 1.0–1000 ng?mL?1 for triazophos, carbofuran and chlorpyrifos, respectively, and the detection limits are 0.024, 0.93 and 1.68 ng?mL?1. This new multiplex assay is superior to the traditional ELISA in possessing a wider detection range, better reproducibility and the feature of multi-target detection. Cross-reactivity studies indicated that the bead-array method is highly selective for the three target pesticides, and that individual analyses have no significant influence between each other, also without cross-reactions from other structurally related pesticides. The method was applied to analyze vegetables spiked with the three pesticides, and the recoveries were in ranges of 78.5–112.1 %, 72.2–120.2 % and 70.2–112.8 %, respectively, with mean coefficients of variation of <15 %. Figure
Schematic illustration of the multiplex bead-based competitive immunoassay 相似文献
992.
An inorganic–organic hybrid compound [Ni4(pzac)4(H2O)8(β-Mo8O26)]·2H2O (1), pzac = 2- pyrazinecarboxylic acid, was synthesized hydrothermally and characterized by IR spectrum, TGA, X-ray single-crystal diffraction. Photoluminescence property has been investigated. In 1 pzac coordinates to Ni1 with a chelating mode and bridges Ni2 forming a one-dimensional undulate chain structure. Ni atom accepts a terminal oxygen atom of [β-Mo8O26]4? anion with a little longer Ni–O distances of 2.685 Å and 2.767 Å. [β-Mo8O26]4? anion links four Ni atoms of four chains, forming a three-dimensional covalent framework. Lattice water molecules fill the vacancies of the framework. 相似文献
993.
Spherical Li-rich lithium manganese oxide(LMO) spinel material was synthesized by an ion implanted method assisted by polyalcohol doped with Niobium and Phosphate simultaneously.The material was characterized by scanning electron microscopy,X-ray diffraction and BET specific surface area analysis.The electrochemical performances were investigated with galvanostatic techniques and cyclic voltammetry.The synthesis process was investigated with TG/DSC.The results show that the lithium ion can be immersed into the pore of manganese dioxide at a low temperature with the ion implanted method.The prepared materials have a higher discharge capacity and better crystallization than those prepared by solid phase method.The doped Nb can improve the capacity of the Li-rich LMO spinel and reinforce the crystal growth along(111) and(400) planes.The crystal grains show circular and smooth morphology,which makes the specific surface area greatly decreased.Phosphate-doped LMO spinel exhibits good high-rate capacity and structure stability.The prepared Li_(1.09)Mn_(1.87)Nb_(0.031)O_(3.99)(PO_4)_(0.021)delivers a discharge capacity of 119mAhg~(-1) at 0.2C(1C=148mAg~(-1)) and 112.8 mAhg~(-1) at 10 C,the discharge capacity retention reaches 98% at 1 ℃ after 50 cycles at 25 ℃ and 94% at 55 ℃. 相似文献
994.
毫米波圆柱波导自由电子激光放大器的数值模拟 总被引:1,自引:0,他引:1
本文以单粒子理论为基础,在不计空间电荷效应的近似条件下推导了带轴向引导磁场的三维圆柱波导非线性模拟方程组。用CAGFEL程序计算、分析了在带入口区、常数摇摆器条件下两组不同物理参数的自由电子激光放大器的物理模型。计算结果可靠,物理图象合理。对于其中的第二组参数还着重考查了光波频率、输入功率和摇摆器场振幅改变对输出功率和效率的影响。上述这些计算结果对0.7MeV 自由电子激光放大器的设计和实验具有一定的参考价值。 相似文献
995.
996.
Differential scanning calorimetry (DSC) and x-ray diffraction (XRD) are employed to investigate the effects of nickel on the crystallization of the amorphous Zr70Cu20Ni10 alloy. We have found that the crystallization process of the amorphous Zr70Cu20Ni10 alloy is strongly influenced by the addition of nickel. Addition of 10 at% Ni to the Zr70Cu30 amorphous alloy makes the crystallization process proceed from a single-stage mode to a double-stage mode. The activation energy for crystallization of the amorphous Zr70Cu20Ni10 alloy is calculated to be about 388kJ·mol-1 on the basis of the Kissinger equation. The effects of nickel on the crystallization of the amorphous Zr70Cu20Ni10 alloy are discussed in terms of the genetics of metals. 相似文献
997.
998.
999.
We present results from a novel variational method for the study of beam propagation in a Kerr medium with nonlinear absorption. This new method combines the variational method and a nonlinear absorption equation and gives a concise expression for the combination. The results obtained with this method show good quantitative agreement with numerical solutions obtained with the finite-difference method. It is shown that the variational method takes much less time than a numerical simulation with the finite-difference method for analysis of beam propagation in a thick medium with nonlinear absorption and nonlinear refraction. The new method makes detailed analysis of beam propagation in a Kerr medium with nonlinear absorption very simple and fast. 相似文献
1000.
Tian Weizhi Ni Bangfa Wang Pingsheng Cao Lei Zhang Yangmei 《Accreditation and quality assurance》2001,6(12):488-492
In a series of three papers, the inherent characteristics of relative instrumental neutron activation analysis (INAA) as a
primary ratio method of measurement, the unique functions of parametric INAA as an ideal back-up method of the relative INAA,
and the valuable role of INAA in characterization of sampling behavior of individual elements in certified reference materials
(CRMs) will be discussed. In this paper, the first of the series, the uncertainty evaluation and the traceability of values
measured by neutron activation analysis (NAA), especially instrumental NAA (INAA), will be described to demonstrate the method
at its ”the state-of-the-art” level can meet CCQM criteria for a primary ratio method. The scope and examples will be given.
Received: 19 March 2001 Accepted: 2 October 2001 相似文献