A new fast block adaptive algorithm

This paper describes a novel efficient algorithm appropriate for adapting filters of long order. The scheme is an exact block processing counterpart of the fast Newton transversal filtering algorithm. The filters required by the algorithm blocks are much smaller than the filter length, and the obtained estimates are mathematically equivalent to those of the sample-by-sample version. This leads to a substantial saving in computational complexity without sacrificing performance as well as not having to resort to long processing delays, which limit the performance of the adaptive system     

Adaptive non-linear equalisation of digital communications channels

Non-linear distortion introduced by communications channels increases the probability of error. In this paper, an adaptive non-linear canceller is presented which attempts to remove non-linear interference from the output of a feedforward or decision feedback equaliser, improving the error rate. It may be implemented using a memory look-up table architecture, making it suitable for high speed real time operation.     

Kinetics and mechanism of O-O bond cleavage in the reaction of [RuIII(edta)(H2O)]- with hydroperoxides in aqueous solution

The reactions of [Ru(III)(edta)(H(2)O)](-) (1) (edta = ethylenediaminetetraacetate) with tert-butylhydroperoxide ((t)BuOOH) and potassium hydrogenpersulfate (KHSO(5)) were studied kinetically as a function of oxidant concentration and temperature (10-30 degrees C) at a fixed pH of 6.1 using stopped-flow techniques. Kinetic results were analyzed by using global kinetic analysis techniques. The reaction was found to consist of two steps involving the rapid formation of a [Ru(III)(edta)(OOR)](2-) intermediate, which subsequently undergoes heterolytic cleavage to form [(edta)Ru(V)=O](-). Since [(edta)Ru(V)=O](-) was produced almost quantitatively in the reaction of 1 with the hydroperoxides (t)BuOOH and KHSO(5), the common mechanism is one of heterolytic scission of the O-O bond. The water soluble and easy to oxidize substrate 2,2'-azobis(3-ethylbenzithiazoline-6-sulfonate (ABTS), was employed to substantiate the mechanistic proposal. Reactions were carried out under pseudo-first order conditions for [ABTS] > [hydroperoxide] > [1], and were monitored as a function of time for the formation of the one-electron oxidation product ABTS (*+). The detailed suggested mechanism is consistent with the reported rate and activation parameters, and discussed in reference to the results reported for the reaction of [Ru(II)(edta)(H(2)O)](-) with H(2)O(2).     

Novel iron(III) porphyrazine complex. Complex speciation and reactions with NO and H2O2

The complex [iron(III) (octaphenylsulfonato)porphyrazine] (5-), Fe (III)(Pz), was synthesized. The p K a values of the axially coordinated water molecules were determined spectrophotometrically and found to be p K a 1 = 7.50 +/- 0.02 and p K a 2 = 11.16 +/- 0.06. The water exchange reaction studied by (17)O NMR as a function of the pH was fast at pH = 1, k ex = (9.8 +/- 0.6) x 10 (6) s (-1) at 25 degrees C, and too fast to be measured at pH = 10, whereas at pH = 13, no water exchange reaction occurred. The equilibrium between mono- and diaqua Fe (III)(Pz) complexes was studied at acidic pH as a function of the temperature and pressure. Complex-formation equilibria with different nucleophiles (Br (-) and pyrazole) were studied in order to distinguish between a five- (in the case of Br (-)) or six-coordinate (in the case of pyrazole) iron(III) center. The kinetics of the reaction of Fe (III)(Pz) with NO was studied as a model ligand substitution reaction at various pH values. The mechanism observed is analogous to the one observed for iron(III) porphyrins and follows an I d mechanism. The product is (Pz)Fe (II)NO (+), and subsequent reductive nitrosylation usually takes place when other nucleophiles like OH (-) or buffer ions are present in solution. Fe (III)(Pz) also activates hydrogen peroxide. Kinetic data for the direct reaction of hydrogen peroxide with the complex clearly indicate the occurrence of more than one reaction step. Kinetic data for the catalytic decomposition of the dye Orange II by H 2O 2 in the presence of Fe (III)(Pz) imply that a catalytic oxidation cycle is initiated. The peroxide molecule first coordinates to the iron(III) center to produce the active catalytic species, which immediately oxidizes the substrate. The influence of the catalyst, oxidant, and substrate concentrations on the reaction rate was studied in detail as a function of the pH. The rate increases with increasing catalyst and peroxide concentrations but decreases with increasing substrate concentration. At low pH, the oxidation of the substrate is not complete because of catalyst decomposition. The observed kinetic traces at pH = 10 and 12 for the catalytic cycle could be simulated on the basis of the obtained kinetic data and the proposed reaction cycle. The experimental results are in good agreement with the simulated ones.     

Algorithms for extracting motifs from biological weighted sequences

In this paper we present three algorithms for the Motif Identification Problem in Biological Weighted Sequences. The first algorithm extracts repeated motifs from a biological weighted sequence. The motifs correspond to repetitive words which are approximately equal, under a Hamming distance, with probability of occurrence 1/k, where k is a small constant. The second algorithm extracts common motifs from a set of N2 weighted sequences. In this case, the motifs consists of words that must occur with probability 1/k, in 1qN distinct sequences of the set. The third algorithm extracts maximal pairs from a biological weighted sequence. A pair in a sequence is the occurrence of the same word twice. In addition, the algorithms presented in this paper improve previous work on these problems.     

A RISC architecture extended by an efficient tightly coupled reconfigurable unit

In this paper, the architecture of an embedded processor extended with a tightly-coupled coarse-grain reconfigurable functional unit (RFU) is proposed. The efficient integration of the RFU with the control unit and the datapath of the processor eliminate the communication overhead between them. To speed up execution, the RFU exploits instruction level parallelism (ILP) and spatial computation. Also, the proposed integration of the RFU efficiently exploits the pipeline structure of the processor, leading to further performance improvements. Furthermore, a development framework for the introduced architecture is presented. The framework is fully automated, hiding all reconfigurable hardware related issues from the user. The hardware model of the architecture was synthesized in a 0.13?µm process and all information regarding area and delay were estimated and presented. A set of benchmarks is used to evaluate the architecture and the development framework. Experimental results prove performance improvements in addition to potential energy reduction.     

A new approach to the synthesis of substituted 2(1H)-quinolinones

A new synthetic approach for the preparation of substituted 2(1H)-quinolinones 5 from readily available anilines has been developed. The four step procedure resulted in the synthesis of a variety of substituted 2(1H)-quinolinones in good yields and under mild reaction conditions.     

Film cooling and heat transfer with air injection through two rows of compound angle holes.

This paper describes the results of an experimental investigation into the film cooling effectiveness and the heat transfer characteristics of two staggered rows of compound angle holes. The effects of hole spacings and turbulence intensity on film cooling and heat transfer characteristic are investigated for three blowing rates; 0.5, 1.0 and 1.7. An attempt has been made to correlate the film cooling effectiveness results using a two dimensional correlation group. The increase of spanwise hole spacing results in a reduction in the film cooling effectiveness and an increase in the Stanton number. Increasing the freestream turbulence intensity has caused a significant reduction in the local film cooling effectiveness but increased the Stanton number, especially at blowing rate of 0.5.     

Multichannel fast QRD-LS adaptive filtering: new technique andalgorithms

A direct, unified approach for deriving fast multichannel QR decomposition (QRD) least squares (LS) adaptive algorithms is introduced. The starting point of the new methodology is the efficient update of the Cholesky factor of the input data correlation matrix. Using the new technique, two novel fast multichannel algorithms are developed. Both algorithms comprise scalar operations only and are based exclusively oh numerically robust orthogonal Givens rotations. The first algorithm assumes channels of equal orders and processes them all simultaneously. It is highly modular and provides enhanced pipelinability, with no increase in computational complexity, when compared with other algorithms of the same category. The second multichannel algorithm deals with the general case of channels with different number of delay elements and processes each channel separately. A modification of the algorithm leads to a scheme that can be implemented on a very regular systolic architecture. Moreover, both schemes offer substantially reduced computational complexity compared not only with the first algorithm but also with previously derived multichannel fast QRD schemes. Experimental results in two specific application setups as well as simulations in a finite precision environment are also included     

A study of the behaviour of some new column materials in the chromatographic analysis ofCatharanthus alkaloids

Summary New column-packing materials specially designed for the HPLC analysis of basic compounds have been tested for the analysis ofCatharanthus alkaloids. Mobile phase optimization was performed for each column tested. The influence of mobile phase pH, nature and content of the organic modifier and salt concentration on retention, selectivity and resolution was studied. An important factor in the separation proved to be the pH of the eluent, because of the widely different pK _a values of the analytes. Complete separation was easily achieved on ODS columns, but polymeric materials also gave acceptable results. Presented at the 21^st ISC held in Stuttgart, Germany, 15^th–20^th September, 1996