On Upper Bounds for Minimum Distance and Covering Radius of Non-binary Codes

We consider upper bounds on two fundamental parameters of a code; minimum distance and covering radius. New upper bounds on the covering radius of non-binary linear codes are derived by generalizing a method due to S. Litsyn and A. Tietäväinen lt:newu and combining it with a new upper bound on the asymptotic information rate of non-binary codes. The upper bound on the information rate is an application of a shortening method of a code and is an analogue of the Shannon-Gallager-Berlekamp straight line bound on error probability. These results improve on the best presently known asymptotic upper bounds on minimum distance and covering radius of non-binary codes in certain intervals.     

UWB radio module design for wireless sensor networks

In this paper, we describe an impulse-based ultra wideband (UWB) radio system for wireless sensor network (WSN) applications. Different architectures have been studied for base station and sensor nodes. The base station node uses coherent UWB architecture because of the high performance and good sensitivity requirements. However, to meet complexity, power and cost constraints, the sensor module uses a novel non-coherent architecture that can autonomously detect the UWB signals. The radio modules include a transceiver block, a baseband processing unit and a power management block. The transceiver block includes a Gaussian pulse generator, a multiplier, an integrator and timing circuits. For long range applications, a wideband low noise amplifier (LNA) is included in the transceiver of the sensor module, whereas in short range applications it is simply eliminated to further reduce the power consumption. In order to verify the proposed system concept, circuit level implementation is studied using 1.5 V 0.18 μm CMOS technology. Finally, the UWB radio modules have been designed for implementation in liquid-crystal-polymer (LCP) based System-on-Package (SoP) technology for low power, low cost and small size integration. A small low cost, double-slotted, Knight’s helm antenna is embedded in the LCP substrate, which shows stable characterization and a return loss better than ?10 dB over the UWB band.     

Homogeneous non-competitive bioaffinity assay based on fluorescence resonance energy transfer

A homogeneous non-competitive assay principle for measurement of small analytes based on quenching of fluorescence is described. Fluorescence resonance energy transfer (FRET) occurs between the donor, intrinsically fluorescent europium(III)-chelate conjugated to streptavidin, and the acceptor, quencher dye conjugated to biotin derivative when the biotin-quencher is bound to Eu-streptavidin. Fluorescence can be measured only from those streptavidins that are bound to biotin of the sample, while the fluorescence of the streptavidins that are not occupied by biotin are quenched by quencher-biotin conjugates. The quenching efficiencies of the non-fluorescent quencher dyes were over 95% and one dye molecule was able to quench the fluorescence of more than one europium(III)-chelate. This, however, together with the quadrovalent nature of streptavidin limited the measurable range of the assay to 0.2-2 nmol L⁻¹. In this study we demonstrated that FRET could be used to design a non-competitive homogeneous assay for a small analyte resulting in equal performance with competitive heterogeneous assay.     

Unveiling electronic transitions in three novel chiral azo-compounds using linear and nonlinear circular dichroism: a theoretical-experimental study

Herein, we report on the experimental and theoretically study of the linear absorption, electronic circular dichroism (ECD) spectra, as well as the two-photon absorption circular-linear dichroism measurements of three different chiral azo derivatives in dimethylsulfoxide solution. Using potential energy surfaces and frontier orbital analysis, we established the most stable conformation for each molecule and elucidated their different electronic transitions. Our theoretical calculations allowed us to unambiguously identify the spectral position of such transitions and correlate them with the spectral profiles observed in the two-photon absorption spectra. To further elucidate the characteristics of the main electronic transitions in terms of spectral shape and position, we carried out measurements of the polarization dependent two-photon absorption cross sections and determined the two-photon circular-linear dichroism spectra of these azo dyes.