A new regioselective synthesis and bioactivity of 1H‐pyrazolo[3,4‐d]pyrimidin‐4(5H)‐one derivatives

A series of new 1H‐pyrazolo[3,4‐d]pyrimidin‐4(5H)‐one Derivatives 5 has been designed and regio‐selectively synthesized via a tandem aza‐Wittig reaction. The structures of all compounds prepared have been confirmed by ¹H NMR, IR, EI‐MS spectroscopy and elemental analyses. The results of preliminary bioassay indicate that most compounds 5 possess an inhibition effect against Botrytis cinereapers and Pyricularia oryzae at the concentration of 50 mg/L.     

环氧基的PCB对无铅组装的兼容性

综述了环氧树脂基的PCB与无铅化组装的兼容性问题。经过大量试验表明,常规的FR-4基材和双氰胺固化的高Tg基材是不能满足无铅化组装要求的,而采用酚醛固化的中等-Tg的环氧树脂基材是可能成为无铅化组装用基材的。同时,PCB制造过程也起着重要的作用。PCB设计和再(回)流焊的加热梯度也影响着无铅化的性能。     

基于通信信道的视频传输系统的设计

提出了一种利用PCM基群信道进行视频信号传输的方法,介绍了传输系统的工作原理,对视频编码器进行了较为详细的分析,并采用数字信号处理器作控制器,实现了视频信号的实时传输。     

Phase regression approach for estimating the parameters of a noisy multifrequency signal

A novel approach for estimating the parameters of a multifrequency signal from discrete samples corrupted by additive noise is presented. An established mathematical model indicates that noise influence on the discrete phase and amplitude spectra is equivalent to additive phase and amplitude noise, respectively. On this basis, a simple algorithm is proposed to estimate the frequency and phase of each sinusoid component by linear regression on the phase spectra of segmented signal blocks, while an amplitude estimator is directly derived from the spectrum of the window function. The circular nature of the phase spectrum is thoroughly explored. Also, an algorithmic scheme is presented. The derived variances of the estimators show that for a noisy signal this approach provides superior accuracy over the traditional approaches. Simulations and engineering application confirm the validity of the presented method.     

Synthesis and characterization of white‐light‐emitting polyfluorenes containing orange phosphorescent moieties in the side chain

Two orange phosphorescent iridium complex monomers, 9‐hexyl‐9‐(iridium (III)bis(2‐(4′‐fluorophenyl)‐4‐phenylquinoline‐N,C^2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐PIr) and 9‐hexyl‐9‐(iridium(III)bis(2‐(4′‐fluorophenyl)‐4‐methylquinoline‐N,C^2′)(tetradecanedionate‐11,13))‐2,7‐dibromofluorene (Br‐MIr), were successfully synthesized. The Suzuki polycondensation of 2,7‐bis(trimethylene boronate)‐9,9‐dioctylfluorene with 2,7‐dibromo‐9,9‐dioctylfluorene and Br‐PIr or Br‐MIr afforded two series of copolymers, PIrPFs and MIrPFs, in good yields, in which the concentrations of the phosphorescent moieties were kept small (0.5–3 mol % feed ratio) to realize incomplete energy transfer. The photoluminescence (PL) of the copolymers showed blue‐ and orange‐emission peaks. A white‐light‐emitting diode with a configuration of indium tin oxide/poly(3,4‐ethylenedioxythiophene):poly(styrenesulfonate)/PIr05PF (0.5 mol % feed ratio of Br‐PIr)/Ca/Al exhibited a luminous efficiency of 4.49 cd/A and a power efficiency of 2.35 lm/W at 6.0 V with Commission Internationale de L'Eclairage (CIE) coordinates of (0.46, 0.33). The CIE coordinates were improved to (0.34, 0.33) when copolymer MIr10PF (1.0 mol % feed ratio of Br‐MIr) was employed as the white‐emissive layer. The strong orange emission in the electroluminescence spectra in comparison with PL for these kinds of polymers was attributed to the additional contribution of charge trapping in the phosphorescent dopants. © 2007 Wiley Periodicals, Inc. JPolym Sci Part A: Polym Chem 45: 1746–1757, 2007     

腔靶等离子体辐射温度空间分布测量

本文描述了用膜吸收法测量激光等离子体辐射温度空间分布的原理和方法给出了柱形缝靶轴向辐射温度随空间位置变化的特征,对测量结果进行了分析讨论。     

基于曲率的透视不变性分割

曲线的透视不变性分割在基于二次曲线的三维重建中非常重要。首先给出了连续曲线零曲率点和角点的提取法，在数字图像中曲经是不连续的，曲率的变化受噪声的干扰很大。在这种情况下为了检测出零曲率点和角点，对曲线采用了高斯滤波然后再提到零曲率点和角点。实验证明这种方法效果优于直接求曲率法。     

Dependence of ion-pair induced self-pulsing in Er-doped fiber lasers on emission to absorption ratio

We show theoretically that the ion-pair induced self-pulsing in Er-doped fiber lasers depends largely on the ratio of emission to absorption cross sections, and can be significantly suppressed as this ratio is increased. Our experimental results agree qualitatively with this prediction. This result is important for stabilizing Er-doped fiber lasers where short-cavities and high-gain fibers are required.     

产生特殊聚焦图形的二元光学元件

通过面积编码将伽博（Gabor)波带片的透过率函数的余弦分布等效为二元分布，研制了能产生各种特殊聚焦图形的二元光学元件。根据透镜聚焦的物理原理制作的二元振幅型波带片可以方便地产生多种聚焦线，给出了相应的实验结果，并讨论了改善聚焦效果的优化条件。