Effect of mordenite dealumination on the structure of encapsulated molybdenum catalysts

A series of dealuminated mordenites treated under various conditions of acid leaching was impregnated in an aqueous solution of ammonium heptamolybdate to achieve a loading of 12 wt% Mo. These samples were characterized by XRD, UV-DRS, N(2) adsorption, TGA, and FTIR techniques. Special attention was given to the far-IR measurements and IR study of surface hydroxyl groups before and after dealumination. A polymolybdate species was recognized by the appearance of bands at 344, 319, and 236 (229) cm(-1) due to the vibrational modes of delta(Mo-O) and delta(Mo-O-Mo), respectively. The disappearance of the 236 cm(-1) band as well as that at 344 cm(-1) in favor of the 319 cm(-1) band, with the dealumination, was related to the high dispersion of Mo species in the produced mesopore surface assessed by the N(2) adsorption at 77 K. No bands due to bulk MoO(3) were detected from the IR and XRD results. A strong interaction between Mo species and dealuminated mordenite surfaces (OH groups) was recognized by a decrease in intensity and a marked shift of the band at 3745 to 3727 cm(-1) as well as the appearance of a new band at 3668 cm(-1). The latter band was produced by the interaction of the framework Al-OH with Mo species. The BET surface areas of Mo-dealuminated mordenite samples were higher than the corresponding Mo-free ones. The diffuse reflectance measurements suggested that Mo cations are predominantly present as an octahedrally coordinated Mo(6+), along with some tetrahedral Mo(6+). New spectral features as a consequence of dealumination events in the far-IR range were evaluated and discussed.     

Selective preparation of (E)-3-oxo-1-alkenylphosphonates by insertion of acyl chlorides and nitriles into zirconacycles

Zirconacycles 1, obtained from diethyl 1-alkynylphosphonates, insert either acyl chlorides or nitriles to provide, after acidic workup, (E)-3-oxo-1-alkenylphosphonates, 2, in isolated yields of 55-83%. Insertion produces only one regio- and stereoisomer. The reaction is quite general and proceeds well with both aliphatic and aromatic acyl chlorides. Acetonitrile and p-methoxybenzonitrile also inserted efficiently. Insertion of isobutyl chloroformate produced the vinylphosphonocarboxylate, 2c, the first representative of this class of compounds.     

New CMOS Fully‐Differential Transconductor and Application to a Fully‐Differential Gm‐C Filter

A new CMOS voltage‐controlled fully‐differential transconductor is presented. The basic structure of the proposed transconductor is based on a four‐MOS transistor cell operating in the triode or saturation region. It achieves a high linearity range of ± 1 V at a 1.5 V supply voltage. The proposed transconductor is used to realize a new fully‐differential Gm‐C low‐pass filter with a minimum number of transconductors and grounded capacitors. PSpice simulation results for the transconductor circuit and its filter application indicating the linearity range and verifying the analytical results using 0.35 μm technology are also given.     

Group-Scheduling for Multi-Service Optical Burst Switching (OBS) Networks

We propose a new burst scheduling mechanism for Optical Burst-Switched (OBS) networks. The new approach is made possible by gathering data bursts into groups and performing the scheduling decision for each group collectively. In OBS group-scheduling, bursts will not be considered for scheduling until a pre-defined time period elapses, during which the group of burst header packets would be gathered. By transforming a set of data bursts into a set of corresponding time intervals, the problem of scheduling these bursts is transformed into a combinatorial optimization problem. Graph algorithms are applied to obtain the maximum number of non-overlapping bursts. The proposed OBS group-scheduling scheme is shown to improve the performance of OBS networks over existing scheduling schemes in terms of burst loss probability and channel utilization. With an extension through a sequential optimization, using a Branch-and-Bound technique, the proposed scheme can support multiple classes of service. It is shown that the new scheduling approach has several desired characteristics including fairness and service differentiability among classes in terms of burst loss probability and channel utilization.     

Current Operational Amplifier (COA): CMOS Realization and Active Compensation

A methodology for analysis and synthesis of lowpass sigma-delta () converters is presented in this paper. This method permits the synthesis of modulators employing continuous-time filters from discrete-time topologies. The analysis method is based on the discretization of a continuous-time model and using a discrete simulator, which is more efficient than an analog simulator. In our analysis approach, the influence of the sample and hold block and non-idealities of the feedback DAC can be systematically modeled by discrete-time systems. Finally, a realistic design of a second-order modulator with a compensation of the non-ideal behavior of the DAC is given. Moreover, simulation results show a good agreement with the theoretical predictions.     

Mathematical modelling of diffusion and reaction for gas-solid catalytic systems with complex reaction networks. Negative effectiveness factors

The concept of effectiveness factor (η) as a measure of diffusional limitations for gas-solid catalytic reactions has gone a long way since the time of Thiele. Multiple steady states giving rise to multiple values of (η) for the same bulk conditions, and η values greater than unity have been widely reported in the literature in the last three decades. In this paper an interesting phenomenon associated with the effectiveness factors (η) for industrial gas-solid catalytic reactions is reported, that is the possible occurrence of negative values of η for certain intermediate components. This physically means that diffusional resistance can also reverse the direction of the net production or consumption of intermediate components in consecutive and/or reversible reaction networks. It is shown both numerically and analytically that the results represent real physical phenomenon and not artefacts resulting from numerical problems or model simplifications. Two industrially important reactions are considered, namely, the steam reforming of natural gas which is a highly endothermic reaction and the partial oxidation of O-xylene to phthalic anhydride which is a highly exothermic reaction.     

Colorimetric determination of some pharmaceutical primary aromatic amines

A method for determination of amines of pharmaceutical interest is based on diazotization of the amine and coupling of the product with ethyl acetoacetate.     

Highly selective reduction of acyclic beta-alkoxy ketones to protected syn-1,3-diols

[reaction: see text] The conversion of 1-(2-methoxyethoxy)ethyl-protected beta-hydroxy ketones to syn-1,3-ethylidene acetals is effected by Et(3)SiH and SnCl(4). This reaction is proposed to proceed via a cyclic oxocarbenium ion intermediate and provides the products in yields that range from 69 to 94% and with diastereoselectivities that are >200:1.