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181.
Hannu Salmela Tapio Kalliohaka Matti Lehtimäki Matti Harkoma 《Journal of Electrostatics》2013,71(3):368-372
This article discusses electrostatic charging of the NH90 medium transport/utility helicopter and assesses the safety of transported products against electrostatic discharges originated from the helicopter. Key questions were to determine charging characteristics of the composite material body NH90 compared to metal body helicopters as well as the charging levels in typical operating situations and climate conditions in Northern Europe. Most attention was paid to a situation where a load was winched to ground from a levitating helicopter at 40–80 feet altitudes. The measurements were supported with a simplified numeric simulation model and calculations of the charging of the helicopter.According to the study, there is no significant difference in electrostatic charging characteristics between composite body NH90 helicopter and metal body helicopters. The tight grounding net of the NH90 helicopter enables the charge currents to discharge in the same manner as in metal body helicopters. In all measured situations, the electrostatic charging of the NH90 or a person moving inside the helicopter is under the transport requirements depicted in the standard STANAG 4235. 相似文献
182.
Pivi Mki-Arvela Narendra Kumar David Kubi
ka Ali Nasir Teemu Heikkil Vesa-Pekka Lehto Rainer Sjholm Tapio Salmi Dmitry Yu. Murzin 《Journal of molecular catalysis. A, Chemical》2005,240(1-2):72-81
Citral transformation to menthols was conducted in liquid phase over Ni supported H-MCM-41 and H-Y. The highest selectivity to four different stereoisomers of menthol and to (±)-menthols over Ni-H-MCM-41 were 54 and 38%, respectively. The effect of different metals (Ni, Ir, Ru, Pd) was studied over H-MCM-41. The selectivity to menthols decreased in the following order: Ni > Pd > Ru > Ir. 相似文献
183.
184.
Wetting behaviour of several plasma sprayed oxide surfaces were characterised using contact angle measurements. Since surfaces contained pores and cracks, the evaluation of wetting angles led only to rough estimation of surface free energies. In order to find out the effect of atmospheric contamination the wetting behaviour of plasma-etched surfaces was followed as a function of time.It was found out that the sample preparation method had great influence on the contact angle of plasma sprayed oxide surfaces. The contact angle of plasma-etched surfaces increased when the surfaces were exposed to air. The probable reason for that was adsorption of low surface free energy contaminants to the sample surfaces. 相似文献
185.
In this article we look at a new algorithm for solving convex mixed integer nonlinear programming problems. The algorithm
uses an integrated approach, where a branch and bound strategy is mixed with solving nonlinear programming problems at each
node of the tree. The nonlinear programming problems, at each node, are not solved to optimality, rather one iteration step
is taken at each node and then branching is applied. A Sequential Cutting Plane (SCP) algorithm is used for solving the nonlinear
programming problems by solving a sequence of linear programming problems. The proposed algorithm generates explicit lower
bounds for the nodes in the branch and bound tree, which is a significant improvement over previous algorithms based on QP
techniques. Initial numerical results indicate that the described algorithm is a competitive alternative to other existing
algorithms for these types of problems. 相似文献
186.
Luosujärvi L Karikko MM Haapala M Saarela V Huhtala S Franssila S Kostiainen R Kotiaho T Kauppila TJ 《Rapid communications in mass spectrometry : RCM》2008,22(4):425-431
Gas chromatography (GC) and ion trap mass spectrometry (MS) were combined with microchip atmospheric pressure chemical ionization (microAPCI) and microchip atmospheric pressure photoionization (microAPPI) sources. Selected polychlorinated biphenyls (PCBs, IUPAC Nos. 28, 52, 101, 118, 138, 153 and 180) were analyzed by GC/microAPCI-MS and GC/microAPPI-MS to demonstrate the applicability of the miniaturized ion sources in negative ion mode analysis. The microAPCI and microAPPI methods were evaluated in respect of detection limit, linearity and repeatability. The detection limits for the PCB congeners were somewhat lower with microAPCI than with microAPPI, whereas microAPPI showed slightly wider linear range and better repeatability. With both methods, the best results were obtained for highly chlorinated or non-ortho-chlorinated PCBs, which possess the highest electron affinities. Finally, the suitability of the GC/microAPPI-MS method for the analysis of PCBs in environmental samples was demonstrated by analyzing soil extracts, and by comparing the results with those obtained by gas chromatography with electron capture detection (GC/ECD). 相似文献
187.
Nissilä T Sainiemi L Sikanen T Kotiaho T Franssila S Kostiainen R Ketola RA 《Rapid communications in mass spectrometry : RCM》2007,21(22):3677-3682
We have developed a lidless micropillar array electrospray ionization chip (microPESI) combined with mass spectrometry (MS) for analysis of drugs and biomolecules. The microPESI chip, made of silicon, contains a sample introduction spot for a liquid sample, an array of micropillars (diameter, height, and distance between pillars in the range of 15-200, 20-40, and 2-80 microm, respectively), and a sharpened tip for direct electrospray formation. The microchips were fabricated using deep reactive ion etching (DRIE) which results in accurate dimensional control. The chip, providing a reliable open-channel filling structure based on capillary forces and a electrospray emitter tip for ionization, allows an easy operation and reliable, non-clogging liquid transfer. The microPESI chip can be used for a fast analysis using single sampling or for continuous infusion measurements using a syringe pump for sample introduction. The microPESI-MS shows high sensitivity, with limit of detection 30 pmol/L (60 amol or 28 fg) for verapamil measured with tandem mass spectrometry (MS/MS) and using a sample volume of 2.5 microL. The system shows also good quantitative linearity (r2 > 0.99) with linear dynamic range of at least six orders of magnitude and good ion current stability (standard deviation <5%) in 1-h continuous flow measurement. The microPESI-MS is shown to be a very potential method for direct analysis of drugs and biomolecules. 相似文献
188.
Pedersen CS Lauritsen FR Sysoev A Viitanen AK Mäkelä JM Adamov A Laakia J Mauriala T Kotiaho T 《Journal of the American Society for Mass Spectrometry》2008,19(9):1361-1366
Ionized acetates were used as model compounds to describe gas-phase behavior of oxygen containing compounds with respect to their formation of dimers in ion mobility spectrometry (IMS). The ions were created using corona discharge at atmospheric pressure and separated in a drift tube before analysis of the ions by mass spectrometry. At the ambient operational temperature and pressure used in our instrument, all acetates studied formed dimers. Using a homolog series of n-alkyl-acetates, we found that the collision cross section of a dimer was smaller than that of a monomer with the same reduced mass. Our experiments also showed that the reduced mobility of acetate dimers with different functional groups increased in the order n-alkyl = branched chain alkyl = cyclo alkyl < aromat. For mixed n-alkyl dimers we found that the reduced mobility of acetate dimers having the same number of carbons, for example a dimer of acetyl acetate and hexyl acetate has the same reduced mobility as a dimer composed of two butyl acetates. The fundamental behavior of acetate monomers and dimers described in this paper will assist in a better understanding of the influence of dimer formation in ion mobility spectrometry. 相似文献
189.
Sikanen T Tuomikoski S Ketola RA Kostiainen R Franssila S Kotiaho T 《Journal of mass spectrometry : JMS》2008,43(6):726-735
We present a detailed optimization and characterization of the analytical performance of SU-8-based emitters for electrospray ionization mass spectrometry (ESI/MS). The improved SU-8 fabrication process presented here enhances patterning accuracy and reduces the time and cost of fabrication. All emitters are freestanding and enable sample delivery by both pressure-driven and spontaneous flows. The optimized emitter design incorporates a sharp, double-cantilevered tip implemented to the outlet of an SU-8 microchannel and provides highly sensitive ESI/MS detection. Moreover, the optimized design allows the use of relatively large microchannel dimensions (up to 200 x 50 microm(2), w x h) without sacrificing the detection sensitivity. This is advantageous with a view of preventing emitter clogging and enabling reproducible analysis. The measured limits of detection for the optimized emitter design were 1 nM for verapamil and 4 nM for Glu-fibrinopeptide B with good quantitative linearities between 1 nM and 10 microM (R(2) = 0.9998) for verapamil and between 4 nM and 3 microM (R(2) = 0.9992) for Glu-fibrinopeptide B. The measured tip-to-tip repeatability for signal intensity was 14% relative standard deviation (RSD) (n = 3; 5 microM verapamil) and run-to-run repeatability 4-11% RSD (n = 4; 5 microM verapamil) for all individual emitters tested. In addition, long-term stability of < 2% RSD was maintained for timescales of 30 min even under free flow conditions. SU-8 polymer was also shown to be chemically stable against most of the tested electrospray solvents. 相似文献
190.
Kauppila TJ Talaty N Jackson AU Kotiaho T Kostiainen R Cooks RG 《Chemical communications (Cambridge, England)》2008,(23):2674-2676
Desorption electrospray ionization mass spectrometry (DESI-MS) is applied to the analysis of carbohydrates and steroids; the detection limits are significantly improved by the addition of low concentrations of salts to the spray solvent. 相似文献