全文获取类型
收费全文 | 38745篇 |
免费 | 5773篇 |
国内免费 | 4660篇 |
专业分类
化学 | 19584篇 |
晶体学 | 332篇 |
力学 | 1765篇 |
综合类 | 323篇 |
数学 | 3576篇 |
物理学 | 10555篇 |
无线电 | 13043篇 |
出版年
2024年 | 137篇 |
2023年 | 763篇 |
2022年 | 984篇 |
2021年 | 1352篇 |
2020年 | 1286篇 |
2019年 | 1240篇 |
2018年 | 1145篇 |
2017年 | 1167篇 |
2016年 | 1606篇 |
2015年 | 1838篇 |
2014年 | 2230篇 |
2013年 | 2812篇 |
2012年 | 3111篇 |
2011年 | 3128篇 |
2010年 | 2535篇 |
2009年 | 2544篇 |
2008年 | 2723篇 |
2007年 | 2544篇 |
2006年 | 2421篇 |
2005年 | 2058篇 |
2004年 | 1554篇 |
2003年 | 1353篇 |
2002年 | 1427篇 |
2001年 | 1170篇 |
2000年 | 956篇 |
1999年 | 836篇 |
1998年 | 607篇 |
1997年 | 487篇 |
1996年 | 514篇 |
1995年 | 419篇 |
1994年 | 368篇 |
1993年 | 278篇 |
1992年 | 252篇 |
1991年 | 237篇 |
1990年 | 207篇 |
1989年 | 168篇 |
1988年 | 149篇 |
1987年 | 105篇 |
1986年 | 83篇 |
1985年 | 81篇 |
1984年 | 41篇 |
1983年 | 44篇 |
1982年 | 39篇 |
1981年 | 27篇 |
1980年 | 22篇 |
1979年 | 20篇 |
1978年 | 23篇 |
1977年 | 15篇 |
1976年 | 12篇 |
1973年 | 12篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
141.
142.
This paper proves the optimal estimations of a low-order spatial-temporal fully discrete method for the non-stationary Navier-Stokes Problem. In this paper, the semi-implicit scheme based on Euler method is adopted for time discretization, while the special finite volume scheme is adopted for space discretization. Specifically, the spatial discretization adopts the traditional triangle trial function pair, combined with macro element form to ensure local stability. The theoretical analysis results show that under certain conditions, the full discretization proposed here has the characteristics of local stability, and we can indeed obtain the optimal theoretic and numerical order error estimation of velocity and pressure. This helps to enrich the corresponding theoretical results. 相似文献
143.
The simulation of particle fluidization behavior in a complex geometry with a large number of particles is challenging owing to the complexity of unstructured c... 相似文献
144.
Jie Tang Yang Yang Jingjing Qu Wenhuang Ban Hao Song Zhengying Gu Yannan Yang Larry Cai Shevanuja Theivendran Yue Wang Min Zhang Chengzhong Yu 《Chemical science》2022,13(29):8507
Pyroptosis is a programmed cell death widely studied in cancer cells for tumour inhibition, but rarely in dendritic cell (DC) activation for vaccine development. Here, we report the synthesis of sodium stabilized mesoporous aluminosilicate nanoparticles as DC pyroptosis modulators and antigen carriers. By surface modification of sodium-stabilized four-coordinate aluminium species on dendritic mesoporous silica nanoparticles, the resultant Na-IVAl-DMSN significantly activated DC through caspase-1 dependent pyroptosis via pH responsive intracellular ion exchange. The released proinflammatory cellular contents further mediated DC hyperactivation with prolonged cytokine release. In vivo studies showed that Na-IVAl-DMSN induced enhanced cellular immunity mediated by natural killer (NK) cells, cytotoxic T cells, and memory T cells as well as humoral immune response. Our results provide a new principle for the design of next-generation nanoadjuvants for vaccine applications.Na-IVAl-DMSN acts as both antigen carriers and modulators to “hyperactivate” dendritic cells (DCs) via potassium (K+) efflux dependent pyroptosis, eventually leading to enhanced adaptive and innate immunity. 相似文献
145.
Phenothiazine-based covalent organic frameworks with low exciton binding energies for photocatalysis
Weitao Wang Haotian Wang Xiaohui Tang Jinlei Huo Yan Su Chuangye Lu Yujian Zhang Hong Xu Cheng Gu 《Chemical science》2022,13(29):8679
Designing delocalized excitons with low binding energy (Eb) in organic semiconductors is urgently required for efficient photochemistry because the excitons in most organic materials are localized with a high Eb of >300 meV. In this work, we report the achievement of a low Eb of ∼50 meV by constructing phenothiazine-based covalent organic frameworks (COFs) with inherent crystallinity, porosity, chemical robustness, and feasibility of bandgap engineering. The low Eb facilitates effective exciton dissociation and thus promotes photocatalysis by using these COFs. As a demonstration, we subject these COFs to photocatalytic polymerization to synthesize polymers with remarkably high molecular weight without any requirement of the metal catalyst. Our results can facilitate the rational design of porous materials with low Eb for efficient photocatalysis.We report the construction of phenothiazine-based covalent organic frameworks, which exhibited diverse structures, the feasibility of bandgap engineering, and unprecedented ultralow exciton binding energy of ∼50 meV for photocatalytic polymerization. 相似文献
146.
Rui Li Xin Gou Xinyan Li Hainuo Wang Haibo Ruan Yuting Xiong Xianlun Tang Yuanyuan Li Ping-an Yang 《Molecules (Basel, Switzerland)》2022,27(15)
Flexible strain sensors, when considering high sensitivity and a large strain range, have become a key requirement for current robotic applications. However, it is still a thorny issue to take both factors into consideration at the same time. Here, we report a sandwich-structured strain sensor based on Fe nanowires (Fe NWs) that has a high GF (37–53) while taking into account a large strain range (15–57.5%), low hysteresis (2.45%), stability, and low cost with an areal density of Fe NWs of 4.4 mg/cm2. Additionally, the relationship between the contact point of the conductive network, the output resistance, and the areal density of the sensing unit is analyzed. Microscopically, the contact points of the conductive network directly affect the sensor output resistance distribution, thereby affecting the gauge factor (GF) of the sensor. Macroscopically, the areal density and the output resistivity of the strain sensor have the opposite percolation theory, which affects its linearity performance. At the same time, there is a positive correlation between the areal density and the contact point: when the stretching amount is constant, it theoretically shows that the areal density affects the GF. When the areal density reaches this percolation threshold range, the sensing performance is the best. This will lay the foundation for rapid applications in wearable robots. 相似文献
147.
148.
在役老旧拱桥的承载力是人们关心的热点问题之一,某些桥梁随着使用年限的不断增加,拱肋以及其他结构部件变形甚至破坏,其承载能力削弱问题会变得尤为突出.以宁波市灵桥为例详细分析了其极限承载力,分析过程中考虑了材料和几何双重非线性,以及涉及到灵桥由于战争、船体碰撞、行车事故和其他意外事故引起的拱肋变形和扭曲情况.计算结果表明:拱肋面外的初始变形极大地削弱了灵桥的极限承载能力;要准确评估该桥的极限承载能力,必须考虑材料非线性和几何非线性的影响. 相似文献
149.
一种多级混沌同步通信系统 总被引:9,自引:1,他引:9
本文了蔡氏混沌同步通信系统的主要性质和局限性,提出了一种多级混沌安全通信系统,证明了该系统对传输信号可以完全重建,在有效带宽,失真特性及安全性和方面获得了改善。文中出了给利用该系统进行语音数据和静止图像数据传输的实例。 相似文献
150.
亚微米垂直硅墙的制备是垂直硅薄膜耦合约瑟夫逊结的关键工艺.本文作者在普通光刻设备基础上,开发了一种在〈100〉硅片上制备亚微米硅墙的刻蚀方法:首先用普通光刻手段刻出较宽的墙区;其次,对非墙区进行迭加注入掺杂;第三,杂质高温横向扩散,第四,掺杂选择性刻蚀;第五,高温氧化减薄.实验结果表明,这种方法可以获得墙宽为0.29μm,墙高为1μm左右的硅墙,而且还有一定的改进潜力. 相似文献