Photoacoustic Spectroscopical Studies on L-Tyrosine and Pd(Tyr)2Cl · H2O Complex Crystal

The complex crystal of Pd(Tyr)₂Cl · H₂O was synthesized and its PA spectra (with L-tyrosine) were determined and explained. A method used to resolve the PA amplitude spectrum was suggested. With the phase spectrum of the complex, the PA absorption peaks were resolved by this method, and the non-radiative relaxation time of all absorption bands were calculated.     

Positron Annihilation Study on the Thermal Fatigue in a Die Steel

Samples of 5Cr2NiMoVSi die steel which underwent thermal fatigue with different fatigue cycles have been studied by using microhardness and positron lifetime measurements. It is found that the microhardness and the positron lifetime parameters increase and decrease alternatively with increasing the number of the fatigue cycles. The experimental results reveal that the fatigue strain, the dynamical recovery, and recrystallization and the precipitation are main causes of variation of the defects in the process of thermal fatigue.     

Secondary Metabolites from Hericium erinaceus and Their Anti-Inflammatory Activities

Hericium erinaceus, a culinary and medicinal mushroom, is widely consumed in Asian countries. Chemical investigation on the fruiting bodies of Hericium erinaceus led to the isolation of one new ergostane-type sterol fatty acid ester, erinarol K (1); and eleven known compounds: 5α,8α -epidioxyergosta-6,22-dien-3β-yl linoleate (2); ethyl linoleate (3); linoleic acid (4); hericene A (5); hericene D (6); hericene E (7); ergosta-4,6,8(14),22-tetraen-3-one (8); hericenone F (9); ergosterol (10); ergosterol peroxide (11); 3β,5α,6α,22E-ergosta-7,22-diene-3,5,6-triol 6-oleate (12). The chemical structures of the compounds were determined by 1D and 2D NMR (nuclear magnetic resonance) spectroscopy, mass spectra, etc. Anti-inflammatory effects of the isolated aromatic compounds (5–7, 9) were evaluated in terms of inhibition of pro-inflammatory mediator (TNF-α, IL-6 and NO) production in lipopolysaccharide (LPS)-stimulated murine RAW 264.7 macrophage cells. The results showed that compounds 5 and 9 exhibited moderate activity against TNF-α (IC₅₀: 78.50 μM and 62.46 μM), IL-6 (IC₅₀: 56.33 μM and 48.50 μM) and NO (IC₅₀: 87.31 μM and 76.16 μM) secretion. These results supply new information about the secondary metabolites of Hericium erinaceus and their anti-inflammatory effects.     

Thermal Catalytic-Cracking Low-Density Polyethylene Waste by Metakaolin-Based Geopolymer NaA Microsphere

Metakaolin-based geopolymer microspheres (MGM) with hierarchical pore structures were prepared by suspension dispersion method in dimethicone at 80 °C. The hydrothermal modification of MGM was carried out at a lower temperature of 80 °C, and a NaA molecular sieve converted from metakaolin-based geopolymer (NMGM) with good crystal structure was prepared and applied in thermal catalytic cracking of low-density polyethylene (LDPE) reaction. The one-pot two-stage thermal catalytic cracking of LDPE was carried out in a 100 mL micro-autoclave under normal pressure. In this work, the optimal proportions and optimal reaction conditions of catalysts for NMGM thermal catalytic cracking of LDPE waste to fuel oil were investigated. The NMGM catalyst showed high selectivity to the liquid product of thermal catalytic cracking of waste LDPE. Under the reaction conditions of reaction time of 1 h and reaction temperature of 400 °C, the liquid-phase yield of thermal catalytic cracking of LDPE reached a high of 88.45%, of which the content of gasoline components was 10.14% and the content of diesel components was 80.97%.     

Current Understanding toward Isonitrile Group Biosynthesis and Mechanism

Isonitrile group has been identified in many natural products.Due to the broad reactivity of N≡C triple bond,these natural products have valuable pharmaceutical potentials.This review summarizes the current biosynthetic pathways and the corresponding enzymes that are responsible for isonitrile-containing natural product generation.Based on the strategies utilized,two fundamentally distinctive approaches are discussed.In addition,recent progress in elucidating isonitrile group formation mechanisms is also presented.     

Two cobalt(II) 5-aminoisophthalate complexes and their stable supramolecular microporous frameworks

Two stable supramolecular microporous cobalt(II) polymers, namely [Co(HAIP)2]n.3nH2O (1) and [Co(AIP)(H2O)]n (2), AIP = 5-aminoisophthalate, were hydrothermally synthesized and characterized by single-crystal X-ray diffraction, IR spectra, thermogravimetric analyses, and variable-temperature magnetic susceptibility measurements. The two complexes are constructed from the same Co2(CO2)2 SBU, which is extended into a 1D chain in 1 and a 2D layer in 2. As a result, 1 and 2 are 2D and 3D coordination polymers, respectively. The 3D supramolecular network of complex 1 is held up by strong hydrogen bonds formed between carboxylate groups and shows very high stability when the free H2O molecules are removed, indicating an extraordinarily stable H-bonding system. Upon water ligands being liberated, complex 2 becomes a stable microporous solid with coordination-unsaturated Co centers. The behavior of the susceptibility curve of 1 suggests the occurrence of an interesting intrachain antiferromagnetic coupling between the Co(II) ions and the presence of a significant orbital contribution, whereas the features of 2 indicate an antiferromagnetic coupling with T(N) = 3.5 K and a long-range antiferromagnetic order with a field-induced magnetic transition.     

苄嘧磺隆印迹聚合物的波谱分析及吸附性能研究

以苄嘧磺隆为模板分子, α-甲基丙烯酸为功能单体, 三甲氧基丙烷三甲基丙烯酸酯为交联剂, 二氯甲烷为致孔剂, 在20 ℃温度下, 采用紫外引发沉淀聚合方法制备了苄嘧磺隆分子印迹聚合物. 紫外光谱和核磁共振氢谱实验提示了聚合前模板分子与功能单体之间的相互作用主要是分子间氢键, 分子间氢键相互作用能和双氢键的键距由Hyperchem 7.0和Gaussian 03W软件分别计算为: －28.6163 kJ/mol和0.179～0.181 nm. 制备的印迹聚合物在高效液相色谱和吸附动力学实验中都表现出对模板分子有较强的吸附作用.     

以萘酰亚胺衍生物基荧光高分子为载体和指示剂的 相分离免疫分析方法

以4-甲氧基-N-(2-N’,N’-二甲基氨基乙基-N’-烯丙基)萘二甲酰亚胺氯化铵(DMNAA)为荧光单体, 合成了一种pH敏感荧光高分子聚N-异丙基丙烯酰胺-4-甲氧基-N-(2-N’,N’-二甲基氨基乙基-N’-烯丙基)萘二甲酰亚胺氯化铵-N,N-二甲基氨丙基甲基丙烯酰胺[P(NIP-DMAPM-DMNAA)]. 采用共聚法将日本血吸虫抗原(SjAg)固定在P(NIP-DMAPM-DMNAA)上, 制备P(NIP-DMAPM-DMNAA)-SjAg连接物, 与日本血吸虫抗体(待测, SjAb)发生免疫反应后, 调节pH值, 使荧光高分子相变分离高分子-免疫组分连接物, 最后, 利用蛋白A对抗体的亲和性捕获P(NIP-DMAPM-DMNAA)-SjAg-SjAb, 通过测定高分子自身的荧光信号来定量 SjAb. 该新型高分子具有良好的荧光特性, 对pH响应快速, 37 ℃下相转变pH值为7.2, 分离免疫复合物时造成的损害低. 与传统相分离免疫分析比较, 新方法通过高分子相变分离和蛋白A捕获双重分离作用, 消除了非特异性组分和未反应的特异性免疫成分等的干扰; 利用高分子自身的荧光信号检测, 无须另外的标记物, 大大提高了免疫分析的简便性. 以日本血吸虫抗体为分析对象, 测得线性范围为1～1500 ng/mL, 抗体检出限为1.3 ng/mL, 相对标准偏差为3.6% (n＝10), 结果令人满意.     

穿心莲内酯硫酸酯化反应体系中四个新的衍生物的分离与表征

通过色谱方法, 从复杂的穿心莲内酯硫酸酯化反应体系中分离获得4个新的穿心莲内酯衍生物, 应用谱学方法进行了表征. 主要利用1H NMR, 13C NMR, DEPT, 1H-1H COSY, HSQC, HMBC及NOSEY等1D和2D NMR技术, 并通过与母体化合物NMR数据的对比分析, 鉴定这4个化合物分别为3,19-二羟基-8,11,13-赖百当三烯-15,16-内酯(1), 3-羟基-8,11,13-赖百当三烯-15,16-内酯-19-硫酸酯(2), 8,11,13-赖百当三烯-15,16-内酯-3,19-二硫酸酯(3), 3-羟基- 8(R)-12(S)-8(12)-环氧-13-赖百当烯-15,16-内酯-19-硫酸酯(4).     

Synthesis of fluorinated hyperbranched polymers capable as highly hydrophobic and oleophobic coating materials

A series of coating materials were prepared from two classes of hyperbranched polymers containing short fluorocarbon chains (HPEFs/HPUFs). The obtained hyperbranched polymers were characterized by FT-IR, ¹H NMR, ¹³C NMR, ¹⁹F NMR, GPC and TG analyses. HPEFs/HPUFs exhibited very low surface free energies (13.67-24.49 mJ/m²) which almost are independent of their internal backbone but dependent on the terminal fluorocarbon chains. Highly hydrophobic and/or oleophobic surfaces of cotton woven fabric can be achieved from these polymers by solution-immersion coating method. The static and dynamic wettabilities of the HPEFs/HPUFs treated fabrics have been investigated. The static contact angles reached to 146°, 122° and 102° for water, hexadecane and decane, respectively. The lowest contact angle hysteresis reached to 5.9°.