meso-四(2-羟基-5-磺酸苯基)卟啉的合成及其酸碱平衡的研究

本文对 meso-四(2-H-5-SP)P 的提纯方法进行了改进,同时以光度法研究了该试剂在水溶液中的酸碱平衡、测得其 pKa_1、pKa_2、pKa_3、pKa_4分别为2.99,4.21,8.68,10.28。     

A novel fermentation process for calcium magnesium acetate (CMA) production from cheese whey

Applied Biochemistry and Biotechnology - A novel, anaerobic fermentation process is developed to produce calcium magnesium acetate (CMA) from cheese whey. CMA can be used as a noncorrosive road...     

编队飞行InSAR的平地效应与地形高度效应分析

在编队飞行条件下,推导了InSAR干涉相位特性与平地之间的关系以及相位特性与地形高度之间的关系,定量分析了平地效应对相位的影响以及地形高度对相位的影响.平地与地形高度二者共同影响了InSAR信号的相位,因此相位表达式可以写成二个偏导数的和的形式.以圆锥体为例仿真了地面场景,在不同视角,不同雷达波长,不同基线长度的条件下做了仿真,仿真实验的结果与理论分析的结果一致.     

Heterolytic and Homolytic N-NO Bond Dissociation Energies of N-Nitroso-benzenesulfonylmethylamines in Acetonitrile

Great interests have been accumulated in recent years in the chemistry and biochemistry of nitric oxide (NO) since the remarkable discoveries of its key roles in a wide range of human physiological processes. To elucidate the mechanistic details of NO migration from its donor to its acceptor, it is necessary to determine the Y-NO bind energy that registers the thermodynamic driving force for NO release and capture. In this paper the heterolytic and homolytic N-NO bond dissociation energies [ i. e., △Hhet(N-NO) and △Hhomo(N-NO)] for ten N-nitroso-p-substituted-benzensulfonyl methylamines in acetonitrile are offered, which were obtained from titration calorimetry and thermodynamic cycles, respectively (Scheme 1).     

参数曲面保凸的一个定理

本文讨论了参数曲面的凸性，给出了参数曲面为凸的充要条件．并给出了具体的应用实例．     

矩形片筏基础的挠度分析

工程上对片筏的力学分析，通常采用温克勒地基模型，且假定床基系数是常量。本则认为床基系数是坐标的函数，考虑了具有线性变化床基系数的地基上的片筏，利用伽辽金法求得周边固支片筏在均布荷载作用下的挠度。所得结果颇具一般性且实用价值更高。     

Dialdehyde starch‐crosslinked chitosan films and their antimicrobial effects

For improved mechanical and water‐swelling properties of chitosan films, a series of transparent films were prepared with dialdehyde starch as a crosslinking agent. Fourier transform infrared and X‐ray analysis results demonstrated that the formation of Schiff's base disturbed the crystallization of chitosan. The mechanical properties and water‐swelling properties of the films were significantly improved. The best values of the tensile strength and breaking elongation were 113.1 MPa and 27.0%, respectively, when the dialdehyde starch content was 5%. All the crosslinked films still retained obvious antimicrobial effects toward S. aureus and E. coli, and they showed potential for biomedical applications. © 2003 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 41: 993–997, 2003     

Broadband spectral shaping in a Ti:sapphire regenerative amplifier

A birefringent crystal quartz plate of known thickness has been used as a spectral filter for spectral shaping in a Ti:sapphire regenerative amplifier. The spectral profile of the amplified pulse ejected from the regenerative amplifier was observed while adjusting the birefringent crystal plate in the cavity. By altering the gain spectrum, the bandwidth of the regeneratively amplified pulse was increased from 18 to 35 nm by using a 0.34-mm thick birefringent plate. The output pulse spectrum from the regenerative amplifier neared the bandwidth of the seed pulse. As a comparison, we used a coated filter outside the regenerative amplifier cavity, and the bandwidth of the regeneratively amplified pulse was stretched to 28 nm. When the bandwidth was stretched to 35 nm, the pulse was compressed to 35 fs.     

用于平场光谱仪的非球面全息凹面光栅设计

基于全息凹面光栅理论和ZEMAX软件,设计了一种用于平场光谱仪的消象差平场非球面全息凹面光栅。与采用相同口径、相同相对孔径的全息凹球面光栅构成的平场光谱仪比较,在入射狭缝宽度相同的情况下,该光栅所构成的平场光谱仪的分辨率得到明显提高。同时,利用较大相对孔径非球面全息凹面光栅,可使平场光谱仪的结构更紧凑,从而可实现平场光谱仪的小型化。     

Bio-regeneration of p-complexation desulfurization adsorbents

More and more stringent regulations of gasoline and diesel oil were proposed with the awareness of environmental protection. Hydrodesulfurization (HDS) is a conventional method to remove sulfur compounds for industrial purpose. The main drawbacks of this …