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861.
Xue-Chuan Lv Zhi-Cheng Tan Xiao-Han Gao Zhi-Heng Zhang Li-Ni Yang Jun-Ning Zhao Li-Xian Sun Tao Zhang 《Thermochimica Acta》2006,450(1-2):102-104
A metal-organic complex, which has the potential property of absorbing gases, [LaCu6(μ-OH)3(Gly)6im6](ClO4)6 was synthesized through the self-assembly of La3+, Cu2+, glycine (Gly) and imidazole (Im) in aqueous solution and characterized by IR, element analysis and powder XRD. The molar heat capacity, Cp,m, was measured from T = 80 to 390 K with an automated adiabatic calorimeter. The thermodynamic functions [HT − H298.15] and [ST − S298.15] were derived from the heat capacity data with temperature interval of 5 K. The thermal stability of the complex was investigated by differential scanning calorimetry (DSC). 相似文献
862.
在260~380 K范围内, 用DSC法研究液晶HpBAB的相变。实验查明HpBAB在室温还以玻璃性晶体状态存在。它的玻璃转变、熔化和清亮过程的热力学参数准确地被测到。提出对-正烷氧基亚苄基-对-氨基苯腈同系列中熔化熵和烷基碳原子数的线性关系; 改进Aranow统计模型并估算直线斜率为Rln(3/g)(1相似文献
863.
1,8-萘啶氮氧化物(简写napyo)是一种配位能力较强的中性配体,关于它与金属离子形成的配合物已有报道.但工作主要集中在配合物的合成及性质的研究,它与金属离子形成的配合物的晶体结构至今未见报道.本工作旨在探讨1,8-萘啶氮氧化物与铜(Ⅱ)的配合物中配体与金属离子的配位情况以及铜(Ⅱ)的配位构型. 相似文献
864.
T Hoffend Jr. H Price Y.T Tan P.R Baukema A.J Hopfinger 《Journal of colloid and interface science》1989,130(2)
The computation of the interaction energy between an adsorbed dye molecule and the silver halide surface has been accomplished through the use of a new code which is based upon CHEMLAB. The surface interaction energies have been computed for 1,1′-ethylene-2,2′-cyanine, a dye molecule, in both monomeric and aggregated configurations on the (100) surfaces of AgBr and AgCl. The model predicts reasonable configurations for the adsorbed dye monomer and its H- and B-aggregates. At high dye levels, the adsorption of aggregated forms is found to be favored over an adsorbed monolayer of monomeric dye molecules. Using the current interaction potentials, however, it was found that the adsorption of the dye on the AgCl (100) surface was slightly favored over that on the AgBr (100) surface. This finding, although at variance with experimental data, may be attributed to the use of an unrelaxed silver halide surface in these computations. 相似文献
865.
用普通材料自制和组装一套能梯度淋洗和柱后反应光度法连续检测萃取色层柱的流出曲线的设备。详细叙述了淋洗液切换阀、六通样样阀、四通混合器、盘管反应器的制作和将国产原子吸分光光度计改装流动光度计。 相似文献
866.
用非水滴定法和Hammett系列指示剂测定了COS水解碱改性γ-Al_2O_3催化剂的表面碱强度分布.发现表面碱强度分布不均匀与表面能量分布不均匀相呼应.采用零点酸碱强度(H_(0,max))及碱中心区域分析法,Bronsted催化定律,进一步证实COS水解反应具有明显碱催化特征,较高活性催化剂的H_(0,max)一般为10左右,对COS水解反应起主要作用的碱性中心的碱强度(H_0)为4.8≤H_0≤9.8.对碱金属氧化物改性后的γ-Al_2O_3催化剂,Bronsted规律在每个碱强度分区域内是适用的. 相似文献
867.
Cai-yun Wang Fen Xu Li-xian Sun Yu-Jia Sun Shu-jun Qiu Zhong-bao Zhao Hai-dong Tan Shuang Wang 《Journal of Thermal Analysis and Calorimetry》2013,111(1):959-963
A microcalorimetric technique was used to evaluate the influence of both Levofloxacin lactate in sodium chloride injection (drug A) and Levofloxacin hydrochloride in sodium chloride injection (drug B) on the metabolism of Escherichia coli. By means of an isothermal calorimeter and ampoule method at 37 °C, the power-time curves of E. coli growth were obtained under different conditions. The parameters such as the growth rate constant k, maximum power output P m, time t m corresponding to the maximum power output and inhibitory ratio I of these two drugs were obtained. The results reveal that the inhibitory abilities enhance with increasing concentrations of the two drugs. The critical growth concentration and the half-inhibitory concentration IC50 were 0.15 and 0.079 μg mL?1 (for drug A), 0.13 and 0.061 μg mL?1 (for drug B), respectively. These results show the drug A has slightly better inhibitory effect on E. coli than that of drug B. 相似文献
868.
Two pH-sensitive neutral carrier/PVC electrodes are used simultaneously for the measurement of pH by flow injection. One of these is based on the neutral carrier tridodecylamine and the other on octadecyl isonicotinate, and together they allow the pH range 1–13 to be covered. These electrodes have been used in a very low dispersion miniature potentiometric flow cell designed specifically for use in flow injection in conjunction with a multi-channel data acquisition system. The effects of the solution ionic strength and buffer capacity on the pH measurement are discussed. A flow-injection manifold is proposed which can be used for high-accuracy pH measurements without ionic strength adjustment of the sample and for simultaneous pH and ion concentration measurements with ionic strength adjustment. This has been tested on some synthetic samples for the simultaneous determination of potassium and calcium and the measurement of pH. 相似文献
869.
870.
PhenNO—TTA—乳化剂OP荧光光度法测定微量铕 总被引:3,自引:0,他引:3
研究了Eu(Ⅲ)-PhenNO-TTA-乳化剂OP体系的荧光性质及其用于微量铕的测定。该体系具有良好的分析特性,最低检测限可达7.0×10^-14mol/L. 相似文献