A surface sensitive optical method for the evaluation of processed ZnO: exploitation of LO phonon interaction

We report on a surface property of bulk ZnO crystals and an optical method to evaluate it. Bulk ZnO crystals have a damaged surface layer due to chemomechanical polishing. We prepared the ZnO crystals by etching, and evaluated the improvement of the surface by high-resolution X-ray diffraction (XRD) and photoluminescence (PL). In PL measurements, the relative intensity of the first order longitudinal optical phonon replica of free exciton (FX-1LO) to second order process (FX-2LO) was compared. The relative intensity becomes weak with increasing etched depth and finally saturates at the etched depth of 5 μm. This result agrees well with XRD results.     

Single-mode yield analysis of partly gain-coupled multiquantum-wellDFB lasers

A transfer-matrix-based single-mode yield analysis of partly-gain-coupled multiquantum-well DFB lasers, has been carried out. It is shown that even a small gain coupling is crucial in improving laser single-mode yields and gain margins. Calculated results are consistent with experiments     

Voltammetric study of the transfer of polyammonium ions at nitrobenzene / water interface.

The transfer of polyammonium ions, poly[(dimethylimino)-1,6-hexanediyl] (n = 140, n being the degree of polymerization) ion and poly[(dimethylimino)(2-oxo-1,2-ethanediyl)imino-alpha,omega-alkanediylimino(1-oxo-1,2-ethanediyl)(dimethylimino)-alpha',omega'-alkanediyl] ([-N+ (CH3)2CH2CONH(CH2)x NHCOCH2N+ (CH3)2(CH2)y-]n, x = 2, 3, 4, or 6, y = 3 or 6, and n = 30-130) ions, at a polarizable nitrobenzene / water interface has been studied by normal pulse voltammetry and cyclic voltammetry. Despite the polydispersity of the preparations, by normal pulse voltammetry, an S-shaped current-potential curve with a well-defined limiting current, and, by cyclic voltammetry, a pair of anodic and cathodic peak currents due to the transfer of polyammonium ions across the interface were observed within the potential window. The voltammetric behavior is described. Also, the effect of ion-pair formation of the polyammonium ions with supporting electrolyte anions in nitrobenzene- and water-phases on the half-wave or midpoint potential of the ion-transfer, and the relation between the structure of the polyammonium ions and the transfer potentials are discussed.     

Amplified spontaneous emission model for quantum-well distributedfeedback lasers

An amplified spontaneous emission model for quantum-well (QW) distributed feedback (DFB) lasers is presented, which takes into account local spontaneous emission, stimulated emission, and real refractive index change which are calculated from the Fermi-Dirac occupancy functions in a self-consistent manner. The local-normal-mode transfer-matrix method is used, which allows a coupling of the local DFB effect with the local QW spontaneous emission and gain. As an example, an analysis is given of a partly gain-coupled DFB laser with periodically etched QWs, which has a large discontinuity of spontaneous emission and gain in high- and low-corrugation regions. It is shown that the side-mode suppression improves with the increase of the number of etched QW's, due to the carrier-density-dependent gain-coupling     

Static and dynamic simulation for ridge-waveguide MQW DFB lasers

An efficient and versatile computer-aided simulator for the design and analysis of ridge-waveguide (RWG) multiple-quantum-well (MQW) distributed-feedback (DFB) lasers has been developed and is presented. This simulator combines spectral index method and Green's function-based transfer-matrix method (TMM) to deal with the transverse RWG MQW structure and longitudinal DFB structure, respectively. It is capable of simulating both static and dynamic behaviors for a variety of RWG MQW DFB lasers. The major difference from most of the existing models and analyses is that this simulator is capable of linking important device characteristics with practical material and geometrical parameters directly and self-consistently. For instance, the effects of lateral ridge width, vertical MQW layers and longitudinal nonuniformity are all explicitly included in the simulator. important laser characteristics, such as L-I curve, effective linewidth enchancement factor, static lasing wavelength shift, spectral linewidth, facet-power spectrum, AM and FM modulation responses, dynamic-wavelength chirping, as well as longitudinal photon and carrier distribution, can be predicted based on material and waveguide parameters. Therefore, this simulator may be used as an efficient and versatile tool for the systematic exploitation and optimization of a wide range of practical RWG MQW DFB lasers. Analysis of a λ/4 shifted SCH RWG MQW DFB laser is performed to illustrate the capability of this simulator     

Effect of in-phase and antiphase gain coupling on high-speedproperties of MQW DFB lasers

Effect of in-phase and antiphase gain-coupling on high-speed properties is studied for MQW DFB lasers with periodically truncated quantum-wells. The enhancement of modulation bandwidth due to antiphase gain-coupling is found significantly suppressed, and gain-coupled DFB lasers with high κL are preferred for large modulation bandwidth due to the presence of linear gain saturation in MQW lasers     

Silver‐Catalyzed Efficient Synthesis of Oxindoles and Pyrroloindolines via α‐Aminoalkylation of N‐Arylacrylamides with Amino Acid Derivatives

α‐Aminoalkylation of N‐arylacrylamides with amino acid derivatives was achieved by silver‐catalysis in moderate to high yields. The reaction provides an efficient strategy for the synthesis of functionalized oxindoles, and is suitable for a wide range of N‐arylacrylamides and amino acids, both of which are inexpensive and readily available. The oxindoles obtained were readily transformed into densely functionalized pyrroloindolines by deprotection and cyclization in one pot.     

Synthesis, spectroscopic, and electrochemical studies of 1,2-naphthalene-ring-fused tetraazachlorins, -bacteriochlorins, and -isobacteriochlorins: the separation and characterization of structural isomers

1,2-Naphthalene-ring-expanded tetraazachlorins (TACs), tetraazabacteriochlorins (TABCs), and tetraazaisobacteriochlorins (TAiBCs) have been synthesized. Procedures for the synthesis of the starting materials, that is, derivatives of 1,2-naphthalenedicarboxylic acid, have been reinvestigated and improved. Nine possible derivatives, including four, two, and three structural isomers of TACs, TABCs, and TAiBCs, respectively, were separated by using thin-layer chromatography (TLC) or high-performance liquid chromatography (HPLC), and the structure of each isomer was determined by (1)H NMR spectroscopy combined with the NOE technique. The formation ratio of each isomer was rationalized in terms of the intramolecular steric repulsion effect, which was predicted by geometry optimizations at the DFT level. The derived compounds were characterized by using IR, electronic, and magnetic circular dichroism (MCD) spectroscopy, and by electrochemical methods. Frequency calculations at the DFT level correctly reproduced the experimental IR spectra and, in particular, distinguished between the three isomers of the TAiBCs. In the electronic absorption and MCD spectra of the TAC and TABC species, the Q-band splits into two intense components similarly to the 2,3-naphthalene-fused derivatives described in our preceding paper, although no significant spectral differences were observed from species to species. On the other hand, the spectra of the TAiBCs showed moderate differences depending on the structure of the isomer. The spectroscopic properties as well as the electrochemical behavior of these chlorins resemble those of the corresponding benzene-fused derivatives rather than the 2,3-naphthalene-fused derivatives. Molecular-orbital and configuration-interaction calculations within the framework of the ZINDO/S method were helpful in the discussions of the above observations.     

Determination of 1-hydroxypyrene in human urine by high-performance liquid chromatography with fluorescence detection using a deuterated internal standard

A high-performance liquid chromatographic method has been developed for the quantification of 1-hydroxypyrene (1-OHP) in human urine using deuterated 1-hydroxypyrene ([2H9]1-OHP) as an internal standard with fluorescence detection. [2H9]1-OHP was prepared enzymatically from deuterated pyrene ([2H10]Pyr) with cytochrome P450 1A1. It eluted immediately prior to non-deuterated 1-OHP on alkylamide-type reversed-phase columns and had nearly the same fluorescence characteristics as non-deuterated 1-OHP. The detection limit was 0.1 microg/L and the calibration range was from 1 to 100 nmol/L. Urine sample treatment involved enzymatic hydrolysis followed by solid-phase extraction using Sep-Pak C18 cartridges. The proposed method was used to determine urinary 1-OHP in smokers and non-smokers.