Photonic Network Communications - A low complexity carrier phase estimation (CPE) algorithm for M-ary quadrature amplitude modulation (m-QAM) optical communication systems is investigated in this... 相似文献
Solid-phase linked o-iodoanilines (4) and o-iodophenol (9) reacted with 1,3- and 1,4-dienes in the presence of palladium acetate to generate highly substituted indolines, tetrahydroquinolines, hydrobenzofurans and hydrobenzopyrans, which provided an efficient way for making heterocyclic molecule libraries. 相似文献
A simple and effective method for constructing highly efficient oxygen reduction catalysts with trace amount of isolated cobalt was firstly developed by the pyrolysis of Co-centered polyoxometalate@metalorganic framework (Co-POM@MOF).The Co-centered polyoxometalate ([Co W12O40]6-) was confined in the well-defined void space of ZIF-8 to achieve homogeneous dispersion of polyoxoanions,where the isolated Co centers were well surrounded by the W-O shell and ZIF-8 fra... 相似文献
Journal of Structural Chemistry - A new novel Cu(II) compound formulated as Cu(C4N6H4)2Cl2 (1) (C4N6H4 = 1H-3,4′-bi-1,2,4-triazole) is successfully synthesized by a... 相似文献
Polymers are widely recognized to entail random conformations in good solvent governed by the need for achieving the highest entropy to reach thermodynamic equilibrium. In this context, it remains grand challenging to directly arrange them into ordered conformation as building blocks for further self-assembling into hierarchal structures. Herein, we report a simple yet viable strategy to progressively assemble rationally designed azobenzene-containing alternating copolymer(i.e., poly(binaphthyls... 相似文献
The palladium‐catalyzed reaction of 2‐alkynylanilines with 2‐(2‐bromobenzylidene)cyclobutanone as an efficient route to 7,8‐dihydrobenzo[b]naphtho[2,3‐d]azocin‐6(5 H)‐ones was developed. The fused eight‐membered ring was constructed conveniently. During the reaction process, double carbometalation was involved, which resulted in excellent selectivity with the formation of three new bonds. This transformation is highly efficient and leads to fused polycycles in good to excellent yields with good functional group tolerance. 相似文献
Phosphine‐catalyzed enantioselective annulation reactions involving ketimines are a daunting synthetic challenge owing to the intrinsic low reactivity of ketimine substrates. A highly enantioselective [3+2] cycloaddition reaction that makes use of isatin‐derived ketimines as reaction partners was developed. Notably, both simple and γ‐substituted allenoates could be utilized, and various 3,2′‐pyrrolidinyl spirooxindoles with a tetrasubstituted stereocenter were obtained in excellent yields and with nearly perfect enantioselectivity (>98 % ee in all cases). 相似文献
The title complex [(C12H8N2)2Bi(O2NO)3] was synthesized by reaction of 1,10-phenanthroline (phen) and Bi(NO3)3·5H2O. The structure of the complex was characterized by single-crystal X-ray diffraction, IR spectroscopy, and elemental analysis. An advanced solution-reaction isoperibol microcalorimeter was applied to determine the standard molar enthalpies of formation at 298.15 K of the complex and Bi(NO3)3·5H2O, giving –(798.92 ± 5.99) and –(1986.87 ± 0.20) kJ mol−1, respectively. The biological effect of the complex was evaluated by microcalorimetry on the growth of Schizosaccharomyces pombe (S. pombe). According to thermogenic curves, the corresponding thermokinetics and thermodynamic parameters were derived. The complex had good bioactivity on the growth metabolism of S. pombe, with the value of IC50 being 2.8 × 10−5 mol L−1.