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171.
Summary Using a saturated non-boiling hydrocarbon mixture, the influence of two parameters on the results of field ionization mass spectrometry (FI-MS) measurements was studied: (a) the potential difference between the FI emitter and the counterelectrode; (b) the emitter temperature.Variation of the potential difference had only a minor effect on the average molecular mass measured and had no evident effect on the relative ring number distribution in the sample. In contrast, when the emitter temperature was increased, higher average molecular masses were recorded. Moreover, the average molecular masses shifted to higher ring numbers. In order to control the relationship between the described influences during mixture analysis, measuring instructions have been developed that enable the quantitative analysis of unknown saturated samples. However, average molecular mass of the mixture must be known.
Entwicklung einer quantitativen FI-MS-Methode zur Charakterisierung von gesättigten hoch- und nichtsiedenden Kohlenwasserstoffgemischen相似文献
172.
173.
R. J. Saykally K. M. Evenson D. A. Jennings L. R. Zink A. Scalabrin 《International Journal of Infrared and Millimeter Waves》1987,8(6):653-662
Twenty new cw FIR laser lines in CD3OH, optically pumped by a CO2 laser, are reported. The frequencies of 39 of the stronger laser lines were measured relative to stabilized CO2 lasers with a fractional uncertainty, as determined by the reproducibility of the FIR frequency itself, of 2 parts in 107.Contribution of the U.S. Government, not subject to copyright. 相似文献
174.
Suppose μ is a Radon measure on ℝ
d
, which may be non doubling. The only condition assumed on μ is a growth condition, namely, there is a constant C0>0 such that for all x∈supp(μ) and r>0, μ(B(x, r))⪯C0rn, where 0<n⪯d. We prove T1 theorem for non doubling measures with weak kernel conditions. Our approach yields new results
for kernels satisfying weakened regularity conditions, while recovering previously known Tolsa’s results. We also prove T1
theorem for Besov spaces on nonhomogeneous spaces with weak kernel conditions given in [7]. 相似文献
175.
The authors study the singular integrals under the Hormander condition and the measure not satisfying the doubling condition. At first, if the corresponding singular integral is bounded from L2 to itself, it is proved that the maximal singular integral is bounded from L∞to RBMO except that it is infinite μ-a.e. on Rd. A sufficient condition and a necessary condition such that the maximal singular integral is bounded from L2 to itself are also obtained. There is a small gap between the two conditions. 相似文献
176.
Inspired by the recent work [HHM03], we prove two stability results for compact Riemannian manifolds with nonzero parallel spinors. Our first result says that Ricci flat metrics which also admit nonzero parallel spinors are stable (in the direction of changes in conformal structures) as the critical points of the total scalar curvature functional. Our second result, which is a local version of the first one, shows that any metric of positive scalar curvature cannot lie too close to a metric with nonzero parallel spinor. We also prove a rigidity result for special holonomy metrics. In the case of SU(m) holonomy, the rigidity result implies that scalar flat deformations of Calabi-Yau metric must be Calabi-Yau. Finally we explore the connection with a positive mass theorem of [D03], which presents another approach to proving these stability and rigidity results. Dedicated to Jeff Cheeger for his sixtieth birthday 相似文献
177.
根据环形管通道内流体流动和换热的特点,以Kirillov和Smogalev提出的干涸点理论模型假设为基础,从最基本的质量守恒方程出发,并引入临界液膜厚度等相应的辅助模型,得到了双面加热环形通道内流动沸腾干涸点的理论模型。同时针对间隙为1.0mm和1.5mm的环形窄缝进行了低压低质量流速工况下干涸点的实验研究。比较发现理论模型预测值与实验结果基本相符。说明本文提出的理论模型适用于低压低流量条件下的窄环形通道。实验同时发现:环状流临界热流密度在系统压力为2.2MPa达到最大值,临界含汽量随质量流速的增大呈缓慢下降趋势。 相似文献
178.
K. C. Kumara Swamy E. Balaraman M. Phani Pavan N. N. Bhuvan Kumar K. Praveen Kumar N. Satish Kumar 《Journal of Chemical Sciences》2006,118(6):495-501
The diversity of products in the reaction of diethyl azodicarboxylate (DEAD)/diisopropyl azodicarboxylate (DIAD) and activated
acetylenes with PIII compounds bearing oxygen or nitrogen substituents is discussed. New findings that are useful in understanding the nature
of intermediates involved in the Mitsunobu reaction are highlighted. X-ray structures of two new compounds (2-t-Bu-4-MeC6H3O)P (μ-N-t-Bu)2P+[(NH-t-Bu)N[(CO2]-i-Pr)(HNCO2-i-Pr)]](Cl-)(2-t-Bu-4-MeC6H3OH)(23)and [CH2(6-t-Bu-4-Me-C6H2O)2P(O)C(CO2Me)C-(CO2Me)CClNC(O)Cl] (33) are also reported. The structure of23 is close to one of the intermediates proposed in the Mitsunobu reaction. 相似文献
179.
Kristian Hougaard Frederik D. Nielsen 《Journal of Optical and Fiber Communications Reports》2004,1(1):63-83
In this paper we will present an overview of the use
of photonic crystal fibers as fiber amplifiers. We
will describe the basic concepts of optical
amplification, and how to do numerical modelling of
such components. We will then identify advantages
and disadvantages of amplifiers based on PCF
technology compared to conventional fibers, and then
go into greater detail on some of these specific
applications, such as low pump power amplifiers, and
high-power double-clad amplifiers and lasers. 相似文献
180.
A G 4.0 dendrimer-like poly (amido amine) (PAMAM) based on silica nanoparticles was fabricated via a divergent approach.It was built from γ-aminopropyi silica nanoparfides (APSN) core via repetitive addition of acrylate (MA) and hexylenediamine (HDA). FT-IR and EA were used to monitor the progress of dendrimer during each step. The amino group content of the resulting product increased from 0.49 to 3.72 mmol/g after the 4th generation. In addition, the percentage of grafting increased with increasing generation and reached to 65.9% after 4th generation. It was found that the resulting silica nanoparticles could be dispersed in methanol with a mean hydrodynamic particle diameter of 152.7 nm although the silica nanoparticles had agglomerated during the storage period. 相似文献