酶催化动力学光度法测定抗坏血酸

基于抗坏血酸对血红蛋白模拟酶催化体系的抑制作用,建立酶催化动力学光度法测定抗坏血酸的新方法。研究了体系的最佳条件及动力学行为,测定的线性范围为2.0×10-7—5.9×10-5mol/L,方法检出限为7.0×10-8mol/L。对6.0×10-6mol/L的抗坏血酸进行11次平行测定相对标准偏差为2.5%。此方法可用于药剂和蔬菜中抗坏血酸含量的测定。     

半导体激光器拍摄全息图的研究

半导体激光器输出的光束为椭圆高斯光束,若直接用于全息照相非常不利.采用梯形棱镜对将半导体激光器输出光束进行整形,并且在输出光束束腰位置进行全息照相,拍摄的全息图效果非常逼真.     

低能N~+注入E.coli诱发的HRS/IRR与抗氧化物酶关系的初探

研究了30keV N+注入E.coli诱发的辐射超敏感效应/增强的辐射性(HRS/IRR)及该效应诱发时E.coli细胞内抗氧化物酶(SOD和CAT)的诱导表达,探讨了细胞内抗氧化物酶的诱导与HRS/IRR诱发之间的关联。研究结果显示,HRS诱发剂量范围内(0—5×1014N+/cm2),E.coli细胞内超氧化物岐化酶(SOD)的酶活基本维持在10Us/mg的较低水平,过氧化氢敏(CAT)酶活也都低于8Us/mg;IRR诱发的剂量范围内(5×1014—10×1014N+/cm2),SOD和CAT活性升高并分别达到了58Us/mg和26Uc/mg的最高水平。研究结果初步表明,低能离子注入E.coli HRS/IRR的诱发与细胞内抗氧化物酶的诱导关系密切。     

Nuclear structure around ~(80)Zr

Recent years have witnessed intense activity concerning the study of nuclei with equal numbers of neutrons and protons (N = Z). Exotic properties have been exhibited in the N = Z nuclei, especially in those with atomic masses around 80. In the present paper, the projected shell model(PSM)together with a relativistic Hartree-Bogoliubov (RHB) theory is used to study the nuclear structure near the N = Z line in the mass A ≈ 80 region. For three Zr isotopes 80,82,84Zr, the projected potential energy surfaces and ground state bands are calculated. It is shown that shape coexistence occurs in all of these nuclei. Moreover, we find that the residual neutron-proton interaction strongly affects the ground state band of 80Zr; however, it slightly modifies those of 82Zr and 84Zr.     

A design strategy of achievable linear optics for a complex storage ring lattice

A design strategy is discussed in this paper,and it provides much convenience for effectively exploring achievable linear optics and globally investigating the flexibility of a complex lattice with superperiodicity.A matching method of fractional steps,which means separately finding the standard cell setting and the matching cell setting,is adopted to simplify the complexity of the linear beam optics design in the complex lattice.The multi-objective genetic algorithm is used to find most of all the stable linear optics,and reach a target solution after multi-generational propagation,both in the standard cell and the matching cell.A fitting algorithm with gradient information is used to restore the periodicity and symmetry of the lattice,and finely adjust the linear optics for further optimization.This design strategy is applied in the Shanghai Synchrotron Radiation Facility(SSRF)storage ring,and the results are presented.     

盐酸普拉克索关键中间体的合成

以1,4-二氧杂螺[4.5]癸-8-酮(2)为起始原料,经三甲基硅烯醚化、碘代反应、酸化后所得的产物,与硫脲发生环合、水解后制得2-氨基-6-氧代-4,5,6,7-氢苯并[1,2-d]噻唑(5,经氨化还原反应合成了2,6-二氨基-4,5,6,7-四氢苯并[1,2-d]噻唑(6)。5和6两种关键中间体的总收率分别为86%和71%,其结构经MS、¹H NMR和¹³C NMR确证,探索了合成盐酸普拉克索的两种关键中间体方法和工艺的影响因素。     

基于矿物质定量热分析的灰熔融反应动力学

利用矿物质定量热分析理论对三种典型煤样灰熔融过程进行了详细分析,借助化学反应动力学相关概念,计算了灰样熔融反应动力学参数,结果表明:灰样熔融过程呈明显的三阶段反应过程,即初始熔融阶段、矿物共熔阶段以及熔融末期;熔融初始阶段反应活化能均大于后面两个阶段,矿物共熔过程活化能较初始阶段明显下降;在理论上证明了灰熔融逐渐加剧的过程。     

Sound absorption characteristics of a thin plate with PZT and shunt circuit I. Theoretical analysis

The feasibility of sound absorbing by a vibrating plate with piezoelectric material and shunt circuits is theoretically investigated. Based on an equivalent compliance of a piezoelectric wafer shunted with RL circuits, the governing equations for the fiexural vibration of the plate with the piezoelectric wafer are derived using Lagrange＇s approach. The equations take into account not only the mass, stiffness and structural damping of the plate and the wafer, but also the electrical resistance and electrical inductance of the RL circuits. By using the governing equations derived, the surface impedance and sound absorption coefficient of the plate backed with a cavity are given. Numerical results show that the sound absorption coefficient of the plate near its first mode can be significantly improved by adjusting the RL parameters.     

Painleve Analysis and Darboux Transformation for a Variable-Coefficient Boussinesq System in Fluid Dynamics with Symbolic Computation

The new soliton solutions for the variable-coefficient Boussinesq system, whose applications are seen in fluid dynamics, are studied in this paper with symbolic computation. First, the Painleve analysis is used to investigate its integrability properties. For the identified case we give, the Lax pair of the system is found, and then the Darboux transformation is constructed. At last, some new soliton solutions are presented via the Darboux method. Those solutions might be of some value in fluid dynamics.     

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开发了氮空心阴极放电PIC/MC二维自洽模型。研究了N2传统空心阴极向微空心阴极放电转变过程中电势和电场的变化。结果表明,不同尺寸的空心阴极放电的电势及电场分布规律几乎类似,但空心阴极孔径减小且气压增加时,电场近似线性增加;典型微空心阴极电场比传统空心阴极放电电场约大3个量级;微空心阴极放电产生的电子,氮分子离子和氮原子离子的密度比传统空心阴极放电约大3个量级,且微空心阴极放电中,N2+密度比N+密度大8倍以上。