Biconical horn antennas for near uniform coverage in indoor areasat mm-wave frequencies

A method is presented for designing and dimensioning biconical horn antennas in such way that the level of received power does not depend strongly on the separation distance between a centralized base station and a remote radio terminal within an indoor pico-cell. Results of cell-coverage measurements at 58 GHz are presented using these antennas within eight different indoor environments. The measurement results show that, using biconical horn antennas, an overall uniform coverage can be achieved for both line-of-sight and obstructed line-of-sight topologies     

In-House Networks Using Multimode Polymer Optical Fiber for Broadband Wireless Services

A novel system concept is presented to transport microwave signals over an in-house multimode graded-index polymer optical fiber network, in order to feed the radio access points in high-capacity wireless LANs. By employing optical frequency multiplying, the network's intrinsically limited bandwidth is overcome. The feasibility of this concept to carry data at several hundreds of Mbit/s speed for various microwave signal formats at carrier frequencies in the tens of GHz range is shown. The concept enables cost-effective system implementation, and easy upgrading by offering data signal transparency. It can readily be integrated with other system technologies such as wired Gigabit Ethernet in a single multi-service in-house polymer optical fiber network.     

Asymmetrically Substituted Benzene‐1,3,5‐tricarboxamides: Self‐Assembly and Odd–Even Effects in the Solid State and in Dilute Solution

Molecular organization : Chiral benzene tricarboxamides with methyl substituents at defined positions self‐assemble into supramolecular polymers of preferred helicity by three‐fold α‐helical‐type hydrogen bonding. The odd–even effect is operative and all derivatives are liquid crystalline showing a Col_ho phase (see figure).

     

Lifetimes and branching ratios of excited states of 24Na

The decay of ²⁴Na levels below 4.3 MeV excitation was studied by means of the ²³Na(d, pγ)²⁴Na reaction at E_d = 2.45 MeV. Gamma-ray spectra were measured at three angles, in coincidence with proton groups detected around 180°. Excitation energies, branching ratios and Doppler shifts were determined. Mean lives were obtained for the levels at 1341 keV (62±15 fs), and 1846 keV (200±50 fs). The 1347 keV level has τ >3 ps. For other levels above 1 MeV upper limits of ≈ 60 fs are set. In some cases spin restrictions follow. In particular J = 2 is assigned to the 1341 keV level.     

On the Design of Low-Cost 60-GHz Radios for Multigigabit-per-Second Transmission over Short Distances [Topics in Radio Communications]

This article reviews, discusses, and proposes crucial 60-GHz radio design options. First, it discusses the choice of integrated circuit technology for the radio frequency (RF) part and presents the status quo concerning standardization. Then, it describes the 60-GHz channel-propagation characteristics and proposes antenna solutions, as well as the architecture of the RF part, including a channelization scheme and frequency synthesizer architecture. With regard to the baseband part, we discuss the use of multicarrier modulation and compare it to single-carrier modulation. Finally, we demonstrate the consequences of the various design options as judged from link-budget calculations.     

Molecular recognition controls the organization of mixed self-organized bis-urea-based mineralization templates for CaCO(3)

To investigate the role and importance of nondirectional electrostatic interactions in mineralization, we explored the use of Langmuir monolayers in which the charge density can be tuned using supramolecular interactions. It is demonstrated that, in mixed Langmuir monolayers of bis-ureido surfactants containing oligo(ethylene oxide) and ammonium head groups associated with matching or nonmatching spacers between the two urea groups, the organization is controlled by molecular recognition. These different organizations of the molecules lead to different nucleation behavior in the mineralization of calcium carbonate. The formation of modified calcite and vaterite crystals was induced selectively by different phases of mixed monolayers, and they were characterized by SEM, TEM, and SAED. To understand the influence of the mixed Langmuir monolayers on the crystallization process, we studied the mixtures by means of (pi-A) isotherms and Brewster angle microscopy observations. Infrared reflection-absorption spectroscopy experiments were also performed on Langmuir-Schaefer films. From these results, we conclude that the local organization of the two systems discussed here gives rise to differences in both charge density and flexibility that together determine not only polymorph selection and the nucleation face but also the morphology of the resulting crystals.     

Self‐Assembly of Ureido‐Pyrimidinone Dimers into One‐Dimensional Stacks by Lateral Hydrogen Bonding

Ureido‐pyrimidinone (UPy) dimers substituted with an additional urea functionality self‐assemble into one‐dimensional stacks in various solvents through lateral non‐covalent interactions. ¹H NMR and DOSY studies in CDCl₃ suggest the formation of short stacks (<10), whereas temperature‐dependent circular dichroism (CD) studies on chiral UPy dimers in heptane show the formation of much larger helical stacks. Analysis of the concentration‐dependent evolution of chemical shift in CDCl₃ and the temperature‐dependent CD effect in heptane suggest that this self‐assembly process follows an isodesmic pathway in both solvents. The length of the aggregates is influenced by substituents attached to the urea functionality. In sharp contrast, UPy dimers carrying an additional urethane group do not self‐assemble into ordered stacks, as is evident from the absence of a CD effect in heptane and the concentration‐independent chemical shift of the alkylidene proton of the pyrimidinone ring in CDCl₃.     

Dynamic covalent polymers

This Highlight presents an overview of the rapidly growing field of dynamic covalent polymers. This class of polymers combines intrinsic reversibility with the robustness of covalent bonds, thus enabling formation of mechanically stable, polymer‐based materials that are responsive to external stimuli. It will be discussed how the inherent dynamic nature of the dynamic covalent bonds on the molecular level can be translated to the macroscopic level of the polymer, giving access to a range of applications, such as stimuli‐responsive or self‐healing materials. A primary distinction will be made based on the type of dynamic covalent bond employed, while a secondary distinction will be based on the consideration whether the dynamic covalent bond is used in the main chain of the polymer or whether it is used to allow side chain modification of the polymer. Emphasis will be on the chemistry of the dynamic covalent bonds present in the polymer, in particular in relation to how the specific (dynamic) features of the bond impart functionality to the polymer material, and to the conditions under which this dynamic behavior is manifested. © 2016 The Authors. Journal of Polymer Science Part A: Polymer Chemistry Published by Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2016 , 54, 3551–3577.     

Modelling ARQ for a High-Speed ATM-Based Wireless LAN

An Automatic Repeat Request (ARQ) scheme is proposed for a wireless ATM LAN based on the MEDIAN concept. Simulations have been performed to demonstrate the consequences of ARQ inclusion in terms of required buffer capacity and resulting cell end-to-end delay. In particular, the behaviour of the ARQ-enhanced system for real-time traffic under non error-free conditions has been examined. The main result of the simulations is that, due to specific properties of the MEDIAN wireless ATM LAN, the proposed ARQ scheme is suitable for real-time ATM services, while yielding virtually error-free links. Next to low cell delay, it features low overhead and low processing complexity whereas it can be readily combined with a simple and efficient MAC scheme.