Scanning tunnelling microscopic images of the surface ordering of the liquid crystal 4-n-octyl-4'-cyanobiphenyl

Images of the surface ordering of 4-n-octyl-4'-cyanobiphenyl, a room temperature smectic liquid crystal deposited upon graphite, have been obtained by scanning tunnelling microscopy. The microscope was operated in air using the constant-current mode. Under certain tunnelling conditions it has been possible to resolve both the aliphatic and aromatic parts of the molecule, and to observe individual benzene rings. Two previously unreported conformations have been observed: an overlapping bilayer structure with spacing 3.7 nm, and a monolayer structure with spacing 2.4 nm. The latter structure may represent the first visual evidence for a surface polar ordered structure.     

Transient behavior of subthreshold characteristics of fullydepleted SOI MOSFETs

It has been found that the subthreshold currents of fully depleted silicon-on-insulator (SOI) MOSFETs show a transient behavior under certain front-gate and back-gate voltage conditions. The cause of this anomaly is explained, and applications for the phenomenon are pointed out. Particularly, a simple way to measure the silicon film thickness is suggested     

Isotopic study of the mechanism of ozone formation

The mechanism of ozone formation has been studied using ¹⁶O and ¹⁸O₂. High-resolution microwave spectroscopy was used to measure the amounts of the isotopomeric ozone species formed. The study is hampered by the very rapid exchange process between the reactants, that tends to scramble the isotopes and hence give a 2:1 statistical ratio between the two possible isotopomers. We have found a strategy to come around this difficulty and conclude that the mechanism is a simple end-on-addition.     

Highly compact AC-AC converter achieving a high voltage transferratio

This paper reports a new, highly integrated modular design approach for pulsewidth-modulation AC-AC converters based on a modular phase-bank structure. Novel high-power 3-in-1 integrated bi-directional power modules (IBPM) rated at 1200-V AC and 150 A and the 3-to-1 phase bank circuits have been successfully developed, fabricated and tested. This enables the modularity design of the multiphase converter systems and reduces the critical parasitic inductance. A theoretical analysis of the IBPM's silicon utilization for this new breed of direct power converters has been outlined. A lab prototype at medium power level has been successfully designed, implemented, and tested with good results. A nearly 460-VRMS out voltage at a 1:0.955 voltage transfer ratio, which, perhaps, is the highest performance reported so far in the literature, has been achieved by the novel two-side modulation control system. The converter-fed AC motor system is able to operate over the 0-240 Hz range with inherent regenerative capability and four-quadrant operation. Potential industrial applications are also briefly highlighted in this paper     

Temperature dependence of the rate constants for reactions of the carbonate radical with organic and inorganic reductants

Rate constants have been measured by pulse radiolysis for the reactions of the carbonate radical, CO₃^·?, with a number of organic and inorganic reactants as a function of temperature, generally over the range 5 to 80°C. The reactants include the substitution-inert cyano complexes of Fe^II, Mo^IV, and W^IV, the simple inorganic anions SO₃^2?, ClO₂^?, NO₂^?, I^?, and SCN^?, several phenolates, ascorbate, tryptophan, cysteine, cystine, methionine, triethylamine, and allyl alcohol. The measured rate constants ranged from less than 10⁵ to 3 × 10⁹ M^?1 s^?1, the activation energies ranged from ?11.4 to 18.8 kJ mol^?1, and the pre-exponential factors ranged from log A = 6.4 to 10.7. The activation energies for the metal complexes and inorganic anions generally decrease with increasing driving force for the reaction, as expected for an outer sphere electron transfer. For highly exothermic reactions, however, the activation energy appears to increase, probably reflecting the temperature dependence of diffusion. For many of the organic reactants, the activation energies were low and independent of driving force, suggesting that the oxidation is via an inner sphere mechanism.     

Modeling of multilevel converters

In this paper, the imbricated cells multilevel converters are studied and modeled from a control viewpoint. These converters make use of several switches connected in a series, which allows using switches with reduced voltage ratings; these low voltage switches have lower conduction losses and can switch at higher frequency. In addition to this feature common to all converters using series connected switches, the control signals of multilevel converters can be phase shifted to increase the apparent switching frequency and improve the dynamic performances of the whole converter. It is shown that a multilevel inverter leg, composed of p pairs of switches and p-1 capacitors, forms a multivariable nonlinear system that cannot be properly modeled by standard methods such as state-space averaging. The transient behavior of this system depends on the current harmonics and their phase shift with the different control signals. A specific model is detailed, studied, and used to illustrate the properties of these converters. In particular, the natural balancing of the voltage across the switches is demonstrated and the time constants involved in this process are determined     

Mössbauer gamma echo

By applying stepwise phase modulation of recoilless gamma radiation in a coincidence experiment, constructive interference is produced in transmission geometry between the source and the absorber fields. The resulting regenerated decay signal is called a gamma echo. Here it is demonstrated that during the decay of the 14.4 keV state of⁵⁷Fe multiple echo signals can be generated.