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151.
Ülkü Yılmaz Hasan Küçükbay Nihat Şireci Mehmet Akkurt Selami Günal Rıza Durmaz M. Nawaz Tahir 《应用有机金属化学》2011,25(5):366-373
A mixture of benzimidazole salts (2–7), Pd(OAc)2 and K2CO3 in DMF–H2O catalyzes the Suzuki–Miyaura cross‐coupling reactions promoted by microwave irradiation resulting in high yield within a short time. In particular, the yield of the Suzuki–Miyaura reactions with aryl bromides was found to be nearly quantitative. The synthesized benzimidazole salts (2–7) were identified by 1H‐13C, NMR, IR spectroscopic methods and microanalysis. The molecular structure of 1 was determined by X‐ray crystallography. The antibacterial and antifungal activities of the novel benzimidazole derivatives (1–7) were also tested against standard strains. Copyright © 2011 John Wiley & Sons, Ltd. 相似文献
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Saqib Ali Syed Usman Ahmad Sadiq‐ur‐Rehman Saira Shahzadi Masood Parvez Muhammad Mazhar 《应用有机金属化学》2005,19(1):200-200
A trigonal bipyramidal C2ClS2 coordination geometry for tin is found in Ph2Sn(S2CN(CH2)5)Cl. Copyright © 2005 John Wiley & Sons, Ltd. 相似文献
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We present a new charge conserving capacitance model for Gallium-Arsenide (GaAs) metal semiconductor field effect transistors (MESFET's) based on the quasi-static approximation and a proper partitioning of the channel charge between the source and the drain terminals. A total of nine so-called transcapacitances were determined by taking derivatives of the various terminal charges with respect to the voltages at source, drain, and gate. The transcapacitances are nonreciprocal, i.e., Cij≠Cji when i≠j, and can be organized in a 3×3 matrix incorporating Kirchhoff's current law (charge conservation) and independence of reference. The present capacitance model is valid both above and below threshold, and shows good agreement with experimental data over a wide range of gate and drain biases. The model is analytical and suitable for implementation in circuit simulators 相似文献
156.
Mehwish Iqtedar Mohammad Nadeem Hira Naeem Roheena Abdullah Shagufta Naz Qurat ul Ain Syed 《Natural product research》2015,29(11):1012-1019
The industrialisation of lignocellulose conversion is impeded by expensive cellulase enzymes required for saccharification in bioethanol production. Current research undertakes cellulase production from pretreated Saccharum spontaneum through Trichoderma viride HN1 under submerged fermentation conditions. Pretreatment of substrate with 2% NaOH resulted in 88% delignification. Maximum cellulase production (2603 ± 16.39 U/mL/min carboxymethyl cellulase and 1393 ± 25.55 U/mL/min FPase) was achieved at 6% substrate at pH 5.0, with 5% inoculum, incubated at 35°C for 120 h of fermentation period. Addition of surfactant, Tween 80 and metal ion Mn+2, significantly enhanced cellulase yield. This study accounts proficient cellulase yield through process optimisation by exploiting cheaper substrate to escalate their commercial endeavour. 相似文献
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Jiajia Yang Yun Li Jincheng Wang Xiaoli Sun Syed Mazhar Shah Rong Cao Jiping Chen 《Analytica chimica acta》2015
Bisphenol A (BPA) imprinted sponge mesoporous silica was synthesized using a combination of semi-covalent molecular imprinting and simple self-assembly process. The molecularly imprinted sponge mesoporous silica (MISMS) material obtained was characterized by FT-IR, scanning electron microscopy, transmission electron microscopy, and nitrogen adsorption–desorption measurements. The results show that the MISMS possessed a large specific surface area (850.55 m2 g−1) and a highly interconnected 3-D porous network. As a result, the MISMS demonstrated a superior specific adsorption capacity of 169.22 μmol g−1 and fast adsorption kinetics (reaching equilibrium within 3 min) for BPA. Good class selectivity for BPA and its analogues (bisphenol F, bisphenol B, bisphenol E and bisphenol AF) was also demonstrated by the sorption experiment. The MISMS as solid-phase extraction (SPE) material was then evaluated for isolation and clean-up of these bisphenols (BPs) from sediment samples. An accurate and sensitive analytical method based on the MISMS–SPE coupled with HPLC–DAD has been successfully established for simultaneous determination of five BPs in river sediments with detection limits of 0.43–0.71 ng g−1 dry weight (dw). The recoveries of BPs for lyophilizated sediment samples at two spiking levels (50 and 500 ng g−1 dw for each BP) were in the range of 75.5–105.5% with RSD values below 7.5%. 相似文献
159.
Jahangeer Patujo Amin Badshah Raja Azadar Hussain Muhammad Nawaz Tahir Shaista Tahir Muhammad Khawar Rauf 《中国化学会会志》2015,62(11):1020-1027
In the present work new nitro substituted thioureas, and their copper complexes have been synthesized and characterized by FTIR and multinuclear NMR techniques. Some of the compounds namely 1‐benzoyl‐3‐(4‐chloro‐3‐nitrophenyl) thiourea (A‐1), 1‐benzoyl‐3‐(4‐chloro‐3‐nitrophenyl) thiourea (A‐2) and 1‐benzoyl‐3‐(2‐methoxy‐4‐nitrophenyl) thiourea (A‐2) have also been characterized by single crystal XRD. All the synthesized compounds have been screened for DNA binding potencies (using cyclic voltametry, UV‐vis spectroscopy) and free radical scavanging activities. 相似文献
160.