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81.
Structural Chemistry - In this study, density functional theory (DFT) was employed to predict thermochemical and energetic properties for single-walled carbon nanotubes (SWCNTs) decorated with one... 相似文献
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We study the propagation of regularity of solutions to a three dimensional system of linear parabolic PDE known as the kinematic dynamo equations. The divergence free drift velocity is assumed to be at the critical regularity level with respect to the natural scaling of the equations. 相似文献
85.
The generation of nucleophiles from the combination of aryl boronic acids and catalytic amounts of copper salt allows a reactivity distinct from other organometallic species, such as organolithiums or Grignard reagents. Here we examine how the electronic and steric properties of the boronic acid affect the formation of active nucleophiles and their subsequent reactivity with iminium‐type compounds, showing that electron‐rich substrates display reduced reactivity. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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Susan B. Mackey-Kallis 《Review of Communication》2013,13(3):267-271
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An overall three step preparation of the bis-diimine bridging ligand 4,7-phenanthrolino-5,6:5′,6′-pyrazine (ppz, 1) from 2-methoxy-1,4-phenylenediamine hydrosulfate 4 is reported. 相似文献
89.
Chien-Jung Huang Shao-Ching Huang Susan M. White Sanjay M. Mallya Jeff D. Eldredge 《Theoretical and Computational Fluid Dynamics》2016,30(1-2):87-104
Obstructive sleep apnea (OSA) is a medical condition characterized by repetitive partial or complete occlusion of the airway during sleep. The soft tissues in the airway of OSA patients are prone to collapse under the low-pressure loads incurred during breathing. This paper describes efforts toward the development of a numerical tool for simulation of air–tissue interactions in the upper airway of patients with sleep apnea. A procedure by which patient-specific airway geometries are segmented and processed from dental cone-beam CT scans into signed distance fields is presented. A sharp-interface embedded boundary method based on the signed distance field is used on Cartesian grids for resolving the airflow in the airway geometries. For simulation of structure mechanics with large expected displacements, a cut-cell finite element method with nonlinear Green strains is used. The fluid and structure solvers are strongly coupled with a partitioned iterative algorithm. Preliminary results are shown for flow simulation inside the three-dimensional rigid upper airway of patients with obstructive sleep apnea. Two validation cases for the fluid–structure coupling problem are also presented. 相似文献
90.
Engyodontochones,Antibiotic Polyketides from the Marine Fungus Engyodontium album Strain LF069
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Prof. Dr. Bin Wu Dr. Jutta Wiese Arlette Wenzel‐Storjohann Susan Malien Dr. Rolf Schmaljohann Prof. Dr. Johannes F. Imhoff 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(22):7452-7462
Six new ( 2 , 4 – 8 ) and two known polyketides with a basic structure of an anthraquinone‐xanthone were isolated from mycelia and culture broth of the fungus Engyodontium album strain LF069. The structures and relative configurations of these compounds were established by spectroscopic means, and their absolute configurations were defined mainly by comparison of quantum chemical TDDFT calculated and experimental ECD spectra. Compounds 2 and 4 – 8 were given the trivial names engyodontochone A ( 2 ) and B–F ( 4 – 8 ). Compounds 5 – 8 represent the first example of a 23,28 seco‐beticolin carbon skeleton. The relative and absolute configurations of two known substances JBIR‐97/98 ( 1 ) and JBIR‐99 ( 3 ) were determined for the first time. All isolated compounds were subjected to bioactivity assays. Compounds 1 – 4 exhibited inhibitory activity against methicillin‐resistant Staphylococcus aureus (MRSA) that was 10‐fold stronger than chloramphenicol. 相似文献