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291.
Ranjana Aggarwal Rajiv Kumar Sunil Kumar Gaurav Garg Ritu Mahajan Jitender Sharma 《Journal of fluorine chemistry》2011,132(11):965-972
5-Hydroxy-5-trifluoromethyl-4,5-dihydropyrazol-1-thiocarboxamides 3 and 3-trifluoromethylpyrazol-1-thiocarboxamides 4, regioselectively obtained by the condensation of trifluoromethyl-β-diketones with thiosemicarbazide under neutral and acidic conditions, on further reaction with phenacyl bromides 5 afforded 4-aryl-(5-trifluoromethyl-pyrazol-1-yl)thiazoles 6 and 4-aryl-(3-trifluoromethyl-pyrazol-1-yl)thiazoles 7, respectively. Five 4,5-dihydropyrazoles (3a–e) and two pyrazolylthiazoles (6a and 6c) were tested against one Gram-positive and one Gram-negative bacteria to assess their in vitro antibacterial activity. Compounds 3a, 3b and 3e showed moderate antibacterial activity against Gram-positive bacterium, Bacillus pumilus. 相似文献
292.
G. Chandra Sekhar Reddy A. Uma Ravi Sankar M. Veera Narayana Reddy C. Radha Rani C. Suresh Reddy 《Journal of heterocyclic chemistry》2011,48(6):1229-1233
A series of a new class of phosphorus analogue macrocycles was accomplished by condensation of N‐substituted‐[bis(3,5‐dimethyl‐2‐hydroxybenzyl)]‐amines with various phosphorus dichlorides in dry toluene in the presence of triethylamine at 0–50°C. All the title compounds were evaluated for antimicrobial activity to determine their efficacy and were effective in suppressing the growth of bacteria and fungi. The chemical structures of the title products were characterized by IR, 1H, 13C, 31P‐NMR, mass spectral studies, and elemental analysis. J. Heterocyclic Chem., (2011). 相似文献
293.
Suresh Babu Meruva A. Raghunadh N. Anil Kumar U. K. Syam Kumar R. Vasu Dev P. K. Dubey 《Journal of heterocyclic chemistry》2011,48(3):540-548
A variety of 5‐aryl‐(20S)‐camptothecin derivatives were synthesized by the reaction of 5‐hydroxy‐(20S)‐camptothecin with aromatic hydrocarbons under Friedel‐Craft reaction conditions in moderate to good yield as diastereomeric pairs. The methodology was then extended for the synthesis of 5‐amido‐(20S)‐camptothecin derivatives by reacting 5‐hydroxy‐(20S)‐camptothecin with alkyl and aryl nitriles under Ritter type reaction conditions. The reaction is presumed to proceed through an iminium ion intermediate under Friedel Craft and Ritter type reaction condition, which is further trapped by nucleophile present in the reaction medium. J. Heterocyclic Chem., 00 , 00 (2011). 相似文献
294.
Das P Mandal AK Kesharwani MK Suresh E Ganguly B Das A 《Chemical communications (Cambridge, England)》2011,47(26):7398-7400
A receptor with acidic methylene hydrogens is found to act as an efficient binding mode for F(-). This reagent could as well be used for selective and quantitative extraction of F(-) from the aqueous solution of NaF and sea water. 相似文献
295.
Singh S Aggarwal A Farley C Hageman BA Batteas JD Drain CM 《Chemical communications (Cambridge, England)》2011,47(25):7134-7136
Porphyrins appended with four rigid hydrogen bonding motifs on the meso positions were synthesized and self-assembled into a cofacial cage with four complementary bis(decyl)melamine units in dry solvents. The hydrocarbon chains on the melamine mediate the formation of nanofilms on surfaces as the solvent slowly evaporates. 相似文献
296.
Teow Y Asharani PV Hande MP Valiyaveettil S 《Chemical communications (Cambridge, England)》2011,47(25):7025-7038
Many engineered nanomaterials (NMs) are being synthesized and explored for potential use in consumer and medical products. Already, nanoparticles (NPs) of titanium dioxide (TiO(2)), zinc oxide (ZnO), silver (Ag) and other metals or their oxides are present in commercial products such as sunscreens, cosmetics, wound dressings, surgical tools, detergents, automotive paints and tires. More recent and advanced FDA-approved use of NMs includes quantum dots (QDs) in live cell imaging, zirconium oxides in bone replacement and prosthetic devices and nanocarriers in drug delivery. The benefits from nanotechnology are aplenty, comprising antimicrobial activities, scratch- and water-resistance, long-lasting shine, improved processor speeds and better display resolution, to name a few. While developers of these products often focus on the exciting beneficial aspects of their products, safety and toxicity issues are often not discussed in detail. Long-term effects such as chronic exposure and environmental pollution are even less documented. Along with widespread manufacture and use of NMs, concerns for occupational hazards, proper handling, disposal, storage, shipping and clean up are expected to rise. This review focus on the possible biological impact of engineered NPs, serving as a reminder that nanomaterials can become a double-edged sword if not properly handled. 相似文献
297.
Thermal behaviour of nickel amine complexes containing SO4
2−, NO3
−, Cl− and Br− as counter ions and ammonia and ethylenediamine as ligands have been investigated using simultaneous TG/DTA coupled with
mass spectroscopy (TG/DTA–MS). Evolved gas analyses detected various transient intermediates during thermal decomposition.
The nickel ammonium sulphate complex produces NH, N, S, O and N2 species. The nickel ammonium nitrate complex generated fragments like N, N2, NO, O2, N2O, NH2 and NH. The halide complexes produce NH2, NH, N2 and H2 species during decomposition. The ligand ethylenediamine is fragmented as N2/C2H4, NH3 and H2. The residue hexaamminenickel(II) sulphate produces NiO with crystallite size 50 nm. Hexaammine and tris(ethylenediamine)nickel(II)
nitrate produce NiO in the range 25.5 nm and 23 nm, respectively. The halide complexes produce nano sized metallic nickel
(20 nm) as the residue. Among the complexes studied, the nitrate containing complexes undergo simultaneous oxidation and reduction. 相似文献
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