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951.
Wen Sun Guichang Liu Lida Wang Tingting Wu Yang Liu 《Journal of Solid State Electrochemistry》2013,17(3):829-840
In this paper, a model is established to simulate the time-dependent deposition of corrosion product on the metal surface by considering mass transfer, electrochemical reactions and precipitation reaction. The model is also capable of tacking the movement of metal corrosion interface and the growing interface of the corrosion product deposits via arbitrary Lagrangian–Eulerian finite element method. The current model not only can be used to predict the time-dependent metal corrosion but also for investigating the influences of the deposits’ nature on metal corrosion. The numerical results of current density and corrosion rate are in good agreement with experiments. The presented model predicts that an exponential relationship exists between the maximum corrosion depth and the porosity of corrosion product deposits, and it is also predicted that the growth of the corrosion product layer is linear relative with the root of time, which is consistent with the existing theories. 相似文献
952.
953.
Lu Li Shiwei Liu Yanjing Shi Shitao Yu Congxia Xie Chunjie Qi 《Research on Chemical Intermediates》2013,39(5):2095-2105
Terpinyl acetate, an important natural flavor, can be synthesized by esterification of α-pinene with acetic acid under acidic conditions. In this work, seven acidic ionic liquids were first synthesized, using octadecylamine ethoxylates (AC 1810, AC 1815, AC 1820, and AC 1830) as the cations, and characterized by FT-IR, 1H NMR, and 13C NMR spectroscopy. The ionic liquids were then used as catalysts in the synthesis of terpinyl acetate. The effect of preparation conditions on catalyst performance was examined. It was found that the acidic ionic liquid 1-(3-sulfonic acid)propyl-3-poly(ethylene glycol) octadecylamine polyoxyethylene ether tetrafluoroborate ([PAC1815]+[BF4]?) was an excellent catalyst for synthesis of terpinyl acetate. The effects of the conditions used for preparation of terpinyl acetate were examined in detail, and the optimum preparation conditions were obtained. Under the optimum conditions, the yield of terpinyl acetate reached 35.70 %. When the catalyst was reused for the 5th time, the yield of terpinyl acetate was still 32.00 %. The results showed that effective separation and recycling of catalyst could contribute to developing a new strategy for synthesis of terpinyl acetate. 相似文献
954.
Wan-Yue Diao Dan Xie Yan-Fei Li Ru Jiang Fang-Yu Tao Prof. Hai-Zhu Sun Prof. Xing-Long Wu Dr. Xiao-Ying Zhang Prof. Jing-Ping Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(31):8168-8177
Lithium metal anodes (LMAs) with high energy density have recently captured increasing attention for development of next-generation batteries. However, practical viability of LMAs is hindered by the uncontrolled Li dendrite growth and infinite dimension change. Even though constructing 3D conductive skeleton has been regarded as a reliable strategy to prepare stable and low volume stress LMAs, engineering the renewable and lithiophilic conductive scaffold is still a challenge. Herein, a robust conductive scaffold derived from renewable cellulose paper, which is coated with reduced graphene oxide and decorated with lithiophilic Au nanoparticles, is engineered for LMAs. The graphene cellulose fibres with high surface area can reduce the local current density, while the well-dispersed Au nanoparticles can serve as lithiophilic nanoseeds to lower the nucleation overpotential of Li plating. The coupled relationship can guarantee uniform Li nucleation and unique spherical Li growth into 3D carbon matrix. Moreover, the natural cellulose paper possesses outstanding mechanical strength to tolerate the volume stress. In virtue of the modulated deposition behaviour and near-zero volume change, the hybrid LMAs can achieve reversible Li plating/stripping even at an ultrahigh current density of 10 mA cm−2 as evidenced by high Coulombic efficiency (97.2 % after 60 cycles) and ultralong lifespan (1000 cycles) together with ultralow overpotential (25 mV). Therefore, this strategy sheds light on a scalable approach to multiscale design versatile Li host, promising highly stable Li metal batteries to be feasible and practical. 相似文献
955.
本文基于第一性原理方法研究了Y,Zr,Nb在Sn位掺杂SnO_2的键长变化、稳定性、能带结构以及态密度.结果表明:Y,Zr,Nb在Sn位掺杂SnO_2使附近的键长发生改变,改变量最大是Y掺杂SnO_2体系;掺杂体系的杂质替换能都为负值,表明体系为稳定结构;掺杂使SnO_2能级增多,能较好的调节带隙值;而Y掺杂SnO_2体系价带顶端有一条能级越过了费米线表明该体系呈现出半导体的特征;同时,Y,Zr,Nb掺杂SnO_2使导带底端的能级出现分离;在低能区的态密度仍主要由Sn、O的s轨道贡献;在高能区态密度的掺杂体系出现sp杂化的现象; Zr掺杂SnO_2的态密度能量向低能区移动. 相似文献
956.
Chen Rixiong Yu Shuhui Sun Rong Yang Wenhu Zhao Yubao 《Journal of Solid State Electrochemistry》2012,16(11):3635-3641
Journal of Solid State Electrochemistry - Graphene with highly flaky state has been successfully prepared through chemical reduction process with the assistance of potassium chloride (KCl) to... 相似文献
957.
A detailed quantum chemical study is performed on the mechanism of ClOO + NO reaction at the B3LYP/6-311+G (2d) level of theory
combined with CCSD (T) single point energy calculation. The possible product channels for the reaction are obtained and discussed
on the basis of the singlet [ClNO3] potential energy surface. The calculation indicates that the dominant product for the title reaction is ClO + NO2 by the direct dissociation of the initial adduct, and the formation of the other products is much less likely since they
are unfavorable kinetically. A comparison is also made between the title reaction and the analogous reaction of FO2 + NO to gain a deeper insight into the mechanism of the XO2 + NO reactions. 相似文献
958.
Yan Sun Nianchen Zhou Wei Zhang Yaowen Li Zhenping Cheng Jian Zhu Zhengbiao Zhang Xiulin Zhu 《Journal of polymer science. Part A, Polymer chemistry》2012,50(18):3788-3796
Two novel and well‐defined polymers, poly[6‐(5‐(diphenylamino)‐2‐((4‐methoxyphenyl)diazenyl)phenoxy)hexyl methacrylate] (PDMMA) and poly[6‐(4‐((3‐ethynylphenyl)diazenyl) phenoxy)hexyl methacrylate] (PDPMMA), which bear triphenylamine (TPA) incorporated to azobenzene either directly (PDMMA) or with an interval (PDPMMA) as pendant groups were successfully prepared via reversible addition‐fragmentation chain transfer polymerization technique. The electrochemical behaviors of PDPMMA and PDMMA were investigated by cyclic voltammograms (CV) measurement. The hole mobilities of the polymer films were determined by fitting the J‐V (current‐voltage) curve into the space‐charge‐limited current method. The influence of photoisomerization of the azobenzene moiety on the behaviors of fluorescence emission, CV and hole mobilities of these two polymers were studied. The fluorescent emission intensities of these two polymers in CH2Cl2 were increased by about 100 times after UV irradiation. The oxidation peak currents (IOX) of the PDMMA and PDPMMA in CH2Cl2 were increased after UV irradiation. The photoisomerization of the azobenzene moiety in PDMMA had significant effect on the electrochemical behavior, compared with that in PDPMMA. The changes of the hole mobility before and after UV irradiation were very small for both polymers. The HOMO energies (EHOMO, HOMO: the highest occupied molecular orbital) of side chain moieties of TPA incorporated with cis‐isomer and trans‐isomer of azobenzene in PDMMA and PDPMMA were obtained by theoretical calculation, which are basically consistent with the experimental results. © 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012 相似文献
959.
960.