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131.
132.
Yi Sun 《IEEE transactions on information theory / Professional Technical Group on Information Theory》1997,43(5):1574-1587
We propose a stochastic iteration approach to signal set design. Four practical stochastic iterative algorithms are proposed with respect to equal and average energy constraints and sequential and batch modes. By simulation, a new optimal signal set, the L2 signal set (consisting of a regular simplex set of three signals and some zero signals), is found under the strong simplex conjecture (SSC) condition (equal a priori probability and average energy constraint) at low signal-to-noise ratios (SNR). The optimality of the L1 signal set, the confirmation of the weak simplex conjecture, and two of Dunbridge's (1967) theorems are some of the results obtained by simulations. The influence of SNR and a priori probabilities on the signal sets is also investigated via simulation. As an application to practical communication system design, the signal sets of eight two-dimensional (2-D) signals are studied by simulation under the SSC condition. Two signal sets better than 8-PSK are found. Optimal properties of the L2 signal set are analyzed under the SSC condition at low SNRs. The L2 signal set is proved to be uniquely optimal in 2-D space. The class of signal sets S(M, K) (consisting of a regular simplex set of K signals and M-K zero signals) is analyzed. It is shown that any of the signal sets S(M, K) for 3⩽K⩽M-1 disproves the strong simplex conjecture for M⩾4, and if M⩾7, S(M, 2) (the L1 signal set) also disproves the strong simplex conjecture. It is proved that the L2 signal set is the unique optimal signal set in the class of signal sets S(M, K) for all M⩾4. Several results obtained by Steiner (see ibid., vol.40, no.5, p.721-31, 1994) for all M⩾7 are extended to all M⩾4. Finally, we show that for M⩾7, there exists an integer K'相似文献
133.
为使高光谱成像技术能够在大幅面绘画类文物研究和保护中充分发挥面分析的优势,研制了大幅面高光谱扫描系统,同时建立了传统颜料数据库。与以往高光谱成像技术对文物进行的局部分析相比,该系统不仅提高了分析效率,而且可对绘画文物整体进行颜料鉴别和相对浓度分布研究,可以为绘画中复杂调色工艺的研究提供巨大的帮助。目前,已使用该系统对故宫博物院东华门天花彩画、纸本书画《丁观鹏画不二尊者图轴》、绢本书画《沈庆兰画贴落》和唐卡《吉祥天母画佛像》进行分析研究,并将其用于文物隐藏病害、隐藏墨迹、底稿线等信息的提取与增强,颜料成分鉴别和混合颜料工艺研究等方面,取得了良好的效果,对绘画类文物的研究与保护具有重要的意义。 相似文献
134.
Feng Xia Yanrong Zhao Meijun Xing Zhenning Sun Yizhou Huang Jianghua Feng Guiping Shen 《Molecules (Basel, Switzerland)》2022,27(9)
The difference of nutrient composition between organic eggs and conventional eggs has always been a concern of people. In this study, 1H nuclear magnetic resonance (NMR) technique combined with multivariate statistical analyses was conducted to identify the metabolite different in egg yolk and egg white in order to reveal the nutritional components information between organic and conventional eggs. The results showed that the nutrient content and composition characteristics were different between organic and conventional eggs, among which the content of glucose, putrescine, amino acids and their derivatives were found higher in the organic eggs yolk, while phospholipids were demonstrated higher in conventional eggs yolk. Organic acid, alcohol, amine, choline and amino acids were higher in conventional eggs white, but glucose and lactate in organic egg were higher. Our study demonstrated that there are more nutritive components and higher nutritional value in organic eggs than conventional eggs, especially for the growth and development of infants and young children, and conventional eggs have more advantages in promoting lipid metabolism, preventing fatty liver, and reducing serum cholesterol. Eggs have important nutritional value to human body, and these two kinds of eggs can be selected according to the actual nutrient needs. 相似文献
135.
136.
Lingmin Dai Ke Zhong Yan Ma Xiaoqian Cui Yuhang Sun Ang Zhang Guomin Han 《Molecules (Basel, Switzerland)》2022,27(9)
Acetaldehyde is a critical reactant on modifying the phenolic profile during red wine aging, suggesting that the acetaldehyde-mediated condensation can be responsible for the variation of antioxidant activity during the aging of this beverage. The present study employs exogenous acetaldehyde at six levels of treatment (7.86 ± 0.10–259.02 ± 4.95 mg/L) before the bottle aging of Merlot wines to encourage phenolic modification. Acetaldehyde and antioxidant activity of wine were evaluated at 0, 15, 30, 45, 60 and 75 days of storage, while monomeric and polymeric phenolics were analyzed at 0, 30 and 75 days of storage. The loss of acetaldehyde was fitted to a first-order reaction model, the rate constant (k) demonstrated that different chemical reaction happened in wines containing a different initial acetaldehyde. The disappearance of monomeric phenolics and the formation of polymeric phenolics induced by acetaldehyde could be divided into two phases, the antioxidant activity of wine did not alter significantly in the first phase, although most monomeric phenolics vanished, but the second phase would dramatically reduce the antioxidant activity of wine. Furthermore, a higher level of acetaldehyde could shorten the reaction time of the first phase. These results indicate that careful vinification handling aiming at controlling the acetaldehyde allows one to maintain prolonged biological activity during wine aging. 相似文献
137.
138.
采用固相反应法成功制备出一批Y123与Y211的摩尔比为1∶0.47的混合物,并在此混合物的基础上掺入CeO2,掺入的比例x分别为0.5wt%、1.0wt%、2.0wt%、3.0wt%、4.0wt%。采用了X-射线衍射仪对样品的晶格结构进行了分析,测量结果表明:x=1.0wt%时掺杂效果最好,同时也充分说明Y123的晶格结构与其超导电性之间存在着一种内在的必然关联。并通过对其测试临界转变温度以及转变宽度,测量结果也充分验证了上述结论。 相似文献
139.
Density functional theory calculations have been performed to investigate the structural and electronic properties of bulk Co2C and the stability of low index Co2C surfaces. We found that the formation of Co2C is exothermic with the formation energy of ? 0.81 eV/Co2C with respect to Co under the presence of syngas (mixture of CO and H2). While formed Co2C can be decomposed further to metal Co and graphite carbon with modest energy gain of 0.37 eV/Co2C. This suggests that Co2C is only metastable in Fischer–Tropsch synthesis, which agrees well with experimental findings. The density of states (DOSs) reveals that the Co2C is paramagnetic and strong metallic-like. The difference of charge density analysis indicates that the bond of Co2C is of the mixtures of metallic, covalent, and ionic properties. A variety of low index Co2C surfaces with different terminations are studied. We find that the surface energy of low index stoichiometric Co2C highly relies on the surface area, the number of coordination of surface atoms and the surface dipole, with the decreased stability order of (101) > (011) > (010) > (110) > (100) > (001) = (111). Our results indicate that under Co-poor condition, the formation of non ? stoichiometric surface (011) and (111) without terminated cobalt is energetically more favorable, while under Co-rich condition the formation of non ? stoichiometric (111) surface with cobalt overlayer are preferential. 相似文献
140.
Effects of Organic Acids on the Release of Fruity Esters in Water: An Insight at the Molecular Level
It is well known that organic acids (OAs) could affect the flavour of fruit juices and beverages. However, the molecular mechanism of aroma release is still unclear. In this study, the effects of citric acid (CA), L-(-)-malic acid (MA) and L-lactic acid (LA) on the release of six selected esters and their sensory perception were investigated by means of HS-GC-MS analyses and odour detection threshold determination, respectively. Meanwhile, the density functional theory (DFT) calculation was employed to explore the interaction modes between esters and OAs. HS-GC-MS analyses showed that the concentration and the type of OAs regulated the release of esters. The results were basically consistent with the detection threshold change of those esters. The DFT calculation suggested that the main intermolecular interaction was hydrogen bonds, and several esters could form a ternary ring structure with OAs through hydrogen bonds. The interactions can induce the different release behaviours of esters in OAs water solution. The number of carboxyl functional groups in OAs and the spatial conformation of esters appeared to influence the magnitude of the interaction. The above results demonstrated the mechanism of OAs affecting the release of esters and indicated a possible flavour control way by using different OAs and OA concentrations. 相似文献