ElectroBlocks: A blockchain‐based energy trading scheme for smart grid systems

Smart grid systems are widely used across the world for providing demand response management between users and service providers. In most of the energy distributions scenarios, the traditional grid systems use the centralized architecture, which results in large transmission losses and high overheads during power generation. Moreover, owing to the presence of intruders or attackers, there may be a mismatch between demand and supply between utility centers (suppliers) and end users. Thus, there is a need for an automated energy exchange to provide secure and reliable energy trading between users and suppliers. We found, from the existing literature, that blockchain can be an effective solution to handle the aforementioned issues. Motivated by these facts, we propose a blockchain‐based smart energy trading scheme, ElectroBlocks, which provides efficient mechanisms for secure energy exchanges between users and service providers. In ElectroBlocks, nodes in the network validate the transaction using two algorithms that are cost aware and store aware. The cost‐aware algorithm locates the nearest node that can supply the energy, whereas the store‐aware algorithm ensures that the energy requests go to the node with the lowest storage space. We evaluated the performance of the ElectroBlocks using performance metrics such as mining delay, network exchanges, and storage energy. The simulation results obtained demonstrate that ElectroBlocks maintains a secure trade‐off between users and service providers when using the proposed cost‐aware and store‐aware algorithms.     

Selective Cluster-Based Temperature Monitoring System for Homogeneous Wireless Sensor Networks

Over the past few decades, there has been a revolution in ICT, and this has led to the evolution of wireless sensor networks(WSN), in particular, wireless body area networks. Such networks comprise a specialized collection of sensor nodes(SNs) that may be deployed randomly in a body area network to collect data from the human body. In a health monitoring system, it may be essential to maintain constant environmental conditions within a specific area in the hospital. In this paper, we propose a temperature-monitoring system and describe a case study of a health-monitoring system for patents critically ill with the same disease and in the same environment. We propose Enhanced LEACH Selective Cluster(E-LEACH-SC) routing protocol for monitoring the temperature of an area in a hospital. We modified existing Selective Cluster LEACH protocol by using a fixed-distance-based threshold to divide the coverage region in two subregions. Direct data transmission and selective cluster-based data transmission approaches were used to provide short-range and long-distance coverage for the collection of data from the body of ill patients. Extensive simulations were run by varying the ratio of node densities of the two subregions in the health-monitoring system. Last Node Alive(LNA), which is a measure of network lifespan, was the parameter for evaluating the performance of the proposed scheme. The simulation results show that the proposed scheme significantly increases network lifespan compared with traditional LEACH and LEACH-SC protocols, which by themselves improve the overall performance of the health-monitoring system.     

Tactile internet and its applications in 5G era: A comprehensive review

Over the last few years, communication latency has been a major hurdle for most of the applications deployed in different network domains. During this era, a number of communication protocols and standards were developed and used by the community. However, still, the problem of latency persists keeping in view of the quality of service (QoS) and quality of experience (QoE) for different applications. To mitigate the aforementioned issues, in this paper, we present an in‐depth survey of state‐of‐the art proposals having tactile internet as a backbone for delay mitigation using 5G networks for future ultra‐reliable low‐latency applications such as Healthcare 4.0, Industry 4.0, virtual reality and augmented reality, and smart education. From the existing proposals, it has been observed that tactile internet can provide interactions between virtual objects to give a feel of real environment with maximum latency of 1 millisecond. Also, this paper highlights the key differences between the tactile internet and Internet of Things in context with 5G revolution. Then open issues and challenges of tactile internet for smart applications are analyzed. Finally, a comparison of existing proposals with respect to various parameters is presented, which allows the end users to select one of the proposals in comparison with its merits over the others.     

3T‐FASDM: Linear discriminant analysis‐based three‐tier face anti‐spoofing detection model using support vector machine

In recent years, to solve the problem of face spoofing, momentous work has been done in this field, but still, there is a need for establishing counter measures to the biometric spoofing attacks. Although trained and evaluated on different databases, impressive results have been achieved in existing face anti‐spoofing techniques, but biometric authentication is a very significant problem as imposters are using lots of reconstructed samples or fake synthetic material or structure that can be used for various attack purposes. For the first time, to the best of our knowledge, this paper explains the security for face anti‐spoofing detection using linear discriminant analysis and validates the results by calculating HTER and accuracy on different databases (i.e., REPLAY ATTACK and CASIA). The proposed model, that is, three‐tier face anti‐spoofing detection model (3T‐FASDM), is used for the detection of the fake biometric user and works well for real‐time applications. The proposed methods tested on a set of state‐of‐the‐art anti‐spoofing features for the face mode gives a very low degree of complexity as 26 general image quality measures are applied to differentiate among legitimate and imposter samples. The outcomes obtained from publically available data show that this technique has improved performance and accuracy by analyzing the HTER and machine learning classifiers that are helpful to differentiate among real and fake traits.     

A nonlocal maximum likelihood estimation method for enhancing magnetic resonance phase maps

A phase map can be obtained from the real and imaginary components of a complex valued magnetic resonance (MR) image. Many applications, such as MR phase velocity mapping and susceptibility mapping, make use of the information contained in the MR phase maps. Unfortunately, noise in the complex MR signal affects the measurement of parameters related to phase (e.g, the phase velocity). In this paper, we propose a nonlocal maximum likelihood (NLML) estimation method for enhancing phase maps. The proposed method estimates the true underlying phase map from a noisy MR phase map. Experiments on both simulated and real data sets indicate that the proposed NLML method has a better performance in terms of qualitative and quantitative evaluations when compared to state-of-the-art methods.     

Effect of adsorbate loading on selectivity during adsorption of C_{14}/C_{15} and C_{15}/C_{16} n-alkane binary mixtures in silicalite

Adsorption experiments of mixtures of long chain alkanes into silicalite under liquid phase conditions show selectivity inversion and azeotrope formation. These effects are due to the subtle interplay between the size of the adsorbed molecules and pore topology of the adsorbent. In this study, the selective uptake of lighter component during liquid phase adsorption of C \(_{14}\) /C \(_{15}\) and C \(_{15}\) /C \(_{16}\) n-alkane binary mixtures in the zeolite silicalite is understood through configurational bias grand-canonical Monte Carlo molecular simulation technique and a coarse-grained siting analysis. The simulations are conducted under conditions of low and intermediate levels of loading. The siting pattern of the adsorbates inside the zeolite pores explain the selectivity as seen in experiments.     

On Kirchhoff's Model of Parabolic Type

In this article, the existence of a global strong solution for all finite time is derived for the Kirchhoff's model of parabolic type. Based on exponential weight function, some new regularity results which reflect the exponential decay property are obtained for the exact solution. For the related dynamics, the existence of a global attractor is shown to hold for the problem when the non-homogeneous forcing function is either independent of time or in L^∞(L²). With the finite element Galerkin method applied in spatial direction keeping time variable continuous, a semidiscrete scheme is analyzed, and it is also established that the semidiscrete system has a global discrete attractor. Optimal error estimates in L^∞(H¹) norm are derived which are valid uniformly in time. Further, based on a backward Euler method, a completely discrete scheme is analyzed and error estimates are derived. It is also further, observed that in cases where f = 0 or f = O(e^?γ₀t) with γ₀ > 0, the discrete solutions and error estimates decay exponentially in time. Finally, some numerical experiments are discussed which confirm our theoretical findings.     

Singlet and triplet excited-state interactions and photochemical reactivity of phenyleneethynylene oligomers

The rigid rodlike character of phenyleneethynylenes and their ability to communicate charge/excitation energy over long distances have made them useful as molecular linkers in the light energy harvesting assemblies and molecular electronics devices. These linker molecules themselves possess rich photochemistry as evident from the relatively large yields of the excited singlet (0.5-0.66) and triplet (0.4-0.5) states of two model oligomers, 1,4-bis(phenylethynyl)-2,5-bis(hexyloxy)benzene (OPE-1) and 1,4-bis((4-phenylethynyl)phenylethynyl)-2,5-bis(hexyloxy)benzene (OPE-2). In particular, the long-lived triplet excited state is capable of undergoing deactivation by self-quenching processes such as ground-state quenching and triplet-triplet (T-T) annihilation. The T-T annihilation occurs with a nearly diffusion-controlled rate (approximately 2 x 10(9) M(-1) s(-1)), and ground-state quenching occurs with a rate constant of approximately 6 x 10(7) M(-1) s(-1). The electron transfer from the excited OPE-1 and OPE-2 to benzoquinone as characterized from the transient absorption spectroscopy illustrates the ability of these molecules to shuttle the electrons to acceptor moieties. In addition, pulse radiolysis experiments confirm the spectroscopic fingerprint of the cation radical (or "trapped hole") with absorption bands in the 500-600 nm region.     

Optical deflection and temporal characterization of an ultrafast laser-produced electron beam

The interaction of a laser-produced electron beam with an ultraintense laser pulse in free space is studied. We show that the optical pulse with a(0)=0.5 imparts momentum to the electron beam, causing it to deflect along the laser propagation direction. The observed 3-degree angular deflection is found to be independent of polarization and in good agreement with a theoretical model for the interaction of free electrons with a tightly focused Gaussian pulse, but only when longitudinal fields are taken into account. This technique is used to temporally characterize a subpicosecond laser-wakefield-driven electron bunch. Applications to electron-beam conditioning are also discussed.     

Synthesis, characterization, and reactivity of mononuclear O,N-chelated vanadium(IV) and -(III) complexes of methyl 2-Aminocyclopent-1-ene-1-dithiocarboxylate based ligand: reporting an example of conformational isomerism in the solid state

Vanadium(IV) and -(III) complexes of a tetradentate N(2)OS Schiff base ligand H(2)L [derived from methyl 2-((beta-aminoethyl)amino)cyclopent-1-ene-1-dithiocarboxylate and salicylaldehyde] are reported. In all the complexes, the ligand acts in a bidentate (N,O) fashion leaving a part containing the N,S donor set uncoordinated. The oxovanadium(IV) complex [VO(HL)(2)] (1) is obtained by the reaction between [VO(acac)(2)] and H(2)L. In the solid state, compound 1 has two conformational isomers 1a and 1b; both have been characterized by X-ray crystallography. Compound 1a has the syn conformation that enforces the donor atoms around the metal center to adopt a distorted tbp structure (tau = 0.55). Isomer 1b on the other hand has an anti conformation with almost a regular square pyramidal geometry (tau = 0.06) around vanadium. In solution, however, 1 prefers to be in the square pyramidal form. A second variety of vanadyl complex [VO(L(cyclic))(2)](I(3))(2) (2) with a new bidentate O,N donor ligand involving isothiazolium moiety has been obtained by a ligand-based oxidation of the precursor complex 1 with iodine. Preliminary X-ray and FAB mass spectroscopic data of 2 have supported the formation of a heterocyclic moiety by a ring closure reaction involving a N-S bond. Vanadium(III) complex [V(acac)(HL)(2)] (3) has been obtained through partial ligand displacement of [V(acac)(3)] with H(2)L. Compound 3 has almost a regular octahedral structure completed by two bidentate HL ligands along with an acetylacetonate molecule. Electronic spectra, magnetism, EPR, and redox properties of these compounds are reported.