Highly stereoselective synthesis of peracylated α-aldopyranosyl chlorides from aldopyranose peracetates and thionyl chloride catalyzed by BiCl3 generated in situ from the procatalyst BiOCl

Aldopyranose peracetates react with thionyl chloride and BiCl₃, generated in situ from a substoichiometric amount of the procatalyst BiOCl, producing the corresponding peracylated aldopyranosyl chlorides in very good to excellent yields (82–97%) with exclusive α-anomeric selectivity.     

Enumeration of minimal cutsets from matrix representation of directed/undirected networks

This paper describes an algorithm for finding the minimal cutsets between a specified source and terminal nodes of directed/undirected networks. Adjacent nodes of a source node/merged node are determined by the collection of node numbers of columns corresponding to non-zero elements of the first row of the adjacency matrix to form the reduced adjacency matrix (RAM) corresponding to merged nodes. Connectivity of RAM has been checked to obtain the minimal cutsets.     

Fluctuation study of pionisation in ultrarelativistic nucleus-nucleus interaction

The scaled factorial moments and the multifractal moments have been investigated in differentη-intervals to study the dynamical fluctuation of pions produced in 200 AGeV³²S-Ag/Br interaction. In order to investigate the detail characteristics of intermittency behaviour, theF-moments are extracted up to the eighth order of moments in differentM-intervals. The analysis indicates a non-thermal phase transition and different regime of particle production during the hadronisation process.     

HotSpot: a compact thermal modeling methodology for early-stage VLSI design

This paper presents HotSpot-a modeling methodology for developing compact thermal models based on the popular stacked-layer packaging scheme in modern very large-scale integration systems. In addition to modeling silicon and packaging layers, HotSpot includes a high-level on-chip interconnect self-heating power and thermal model such that the thermal impacts on interconnects can also be considered during early design stages. The HotSpot compact thermal modeling approach is especially well suited for preregister transfer level (RTL) and presynthesis thermal analysis and is able to provide detailed static and transient temperature information across the die and the package, as it is also computationally efficient.     

Gamma ray photon-induced modifications in Triafol-TN and Triafol-BN polymeric track detectors

Photon induced modifications in Triafol-TN and Triafol-BN polymers have been studied in the dose range of 10¹–10⁶ Gy at room temperature using a ⁶⁰Co source. To monitor the chemical and structural changes induced by gamma rays, UV, IR, and ESR studies were carried out. Thermal studies were also conducted for understanding the effects of gamma irradiations on these polymers. Variation of track etching characteristics and activation energy for bulk etching have been studied at different gamma rays doses. The experimental results are presented and discussed.     

Flicker noise in degenerately doped Si single crystals near the metal-insulator transition

In this paper we report some of the important results of experimental investigations of the flicker noise near the metal-insulator (MI) transition in doped silicon single crystals. This is the first comprehensive work to study low-frequency noise in heavily doped Si over an extensive temperature range (2 K<T<500 K). The measurements of conductance fluctuations (flicker noise) were carried out in the frequency range 10⁻²<f<4 × 10¹ Hz in single crystalline Si across the MI transition by doping with phosphorous and boron. The magnitude of noise in heavily doped Si is much larger than that seen in lightly doped Si over the whole temperature range. The extensive temperature range covered allowed us to detect two distinct noise mechanisms. At low temperatures (T<100 K) universal conductance fluctuations (UCF) dominate and the spectral dependence of the noise is determined by dephasing the electron from defects with two-levels (TLS). At higher temperatures (T>200 K) the noise arises from activated defect dynamics. As the MI transition is approached, the 1/f spectral power, typical of the metallic regime, gets modified by the presence of discrete Lorentzians which arise from generation-recombination process which is the characteristic of a semiconductor.     

DARYN-a distributed decision-making algorithm for railway networks:modeling and simulation

The state of the art in scheduling “point-to-point” trains in a railway network utilizes the principles of centralized decision-making. The major difficulty of this approach is that the execution time and the memory requirements increase nonlinearly as the system grows in size. The present paper introduces a new approach, “DARYN”, wherein the overall decision process is analyzed and distributed onto every natural entity of the system. In DARYN, the decision process for every train is executed by an on-board processor that negotiates, dynamically and progressively, for temporary ownership of the tracks with the respective station controlling the tracks, through explicit processor to processor communication primitives. This processor then computes its own route utilizing the results of its negotiation, its knowledge of the track layout of the entire system, and its evaluation of the cost function. Every station's decision process is also executed by a dedicated processor that, in addition, maintains absolute control over a given set of tracks and participates in the negotiation with the trains. Presently, DARYN utilizes a simple cost function. However, if one chooses to increase the complexity of the cost function, DARYN's advantage over the traditional approach increases due to its enormous available computational power. Given that the current microprocessors such as MC68030, MC88000, Intel 486, and Intel 860 are powerful yet relatively inexpensive, a network of concurrently executing processors may offer superior price-performance quotient over a single high performance computer     

Environment-induced decoherence II. Effect of decoherence on Bell''s inequality for an EPR pair

According to Bell's theorem, the degree of correlation between spatially separated measurements on a quantum system is limited by certain inequalities if one assumes the condition of locality. Quantum mechanics predicts that this limit can be exceeded, making it nonlocal. We analyse the effect of an environment modelled by a fluctuating magnetic field on the quantum correlations in an EPR singlet as seen in the Bell inequality. We show that in an EPR setup, the system goes from the usual ‘violation’ of Bell's inequality to a ‘non-violation’ for times larger than a characteristic time scale which is related to the parameters of the fluctuating field. We also look at these inequalities as a function of the spatial separation between the EPR pair.     

Kinetics and mechanism of the oxidation of acetaldehyde by chromic acid in perchloric acid

Summary The oxidation of MeCHO by chromium(VI) has been studied in HClO₄ medium over a wide range of experimental conditions and has been found to obey the rate law;v=k[MeCHO][HCrO ₄ ^– ][H⁺]. The calculated H and-S values for the reaction are 30±2kJ mol^–1 and 171±7J mol^–1deg^–1, respectively. The mechanism is discussed in terms of carbon-hydrogen bond cleavage.