Coupled Thermo-Hydro-Mechanical and Chemical Analysis of Expansive Clay Subjected to Heating and Hydration

A fully coupled formulation combining reactive transport and an existing thermo-hydro-mechanical (THM) code is presented. Special attention has been given to phenomena likely to be encountered in clay barriers used as part of containment systems of nuclear waste. The types of processes considered include hydrolysis, complex formation, oxidation/reduction reactions, acid/base reactions, precipitation/dissolution of minerals and cation exchange. Both kinetically-controlled and equilibrium-controlled reactions have been incorporated. The total analytical concentrations (including precipitated minerals) are adopted as basic transport variables and chemical equilibrium is achieved by minimizing Gibbs Free Energy. The formulation has been incorporated in a general purpose computer code capable of performing numerical analysis of engineering problems. A validation exercise concerning a laboratory experiment involving the heating and hydration of an expansive compacted clay is described.     

All-Pole Estimation in Spectral Domain

Autoregressive (AR) modeling is a popular spectral analysis method commonly resolved in the time domain. This paper presents a novel AR analysis framework dealing with the estimation of poles directly from spectral samples. The basis of the method lies on a minimizing functional built with a certain mapping of the spectral residue. The optimization mechanism is based on the multivariate Newton-Raphson algorithm. Two different mappings are considered, namely, linear and logarithmic. The linear case results in a nonquadratic convex functional, whose global minimum is equivalent to that of the time-domain autocorrelation method. The logarithmic case under the maximum likelihood criterion turns out equivalent to the Whittle likelihood, proven here to be suitable for frequency selective estimation. The statistical and convergence performance of the method is demonstrated with simulations on stochastic and deterministic harmonic signals.     

A qualitative investigation of the oscillations of a pendulum with a periodically varying length and a mathematical model of a swing

The behaviour of the amplitude-frequency characteristics of families of periodic solutions, produced from the equilibrium position of a system, is established by a qualitative investigation of the equation of the oscillations of a pendulum, the length of which is an arbitrary periodic function of time. The non-local conditions for their stability and instability, expressed in terms of the amplitude and frequency of the oscillations, are obtained. The results are used when discussing the parametric and self-excited oscillatory model of a swing. In the parametric model the length of a swing is a specified periodic function of time, and in the self-excited oscillatory model it is a function of the phase coordinates of the system. For an appropriate choice of these functions, both systems have a common periodic solution. It is shown that the parametric model leads to an erroneous conclusion regarding the instability of the periodic mode, which is in fact realized in the oscillations of a swing, whereas the self-excited oscillatory model indicates its stability.     

Pressure recovery system for a high-power HF/DF laser: implementation practice

The matter of development of a high-performance pressure recovery system (PRS) for a high-power HF/DF laser is discussed. A sequence of design steps is proposed, which involves estimation of basic characteristics of PRS components with the help of one-dimensional integral and semi-empirical procedures; simulation, to be performed using three-dimensional non-stationary Navier — Stokes equations; experimental modelling aimed at verification of the calculation procedures and at refinement of obtained parameters; and a fullscale experiment. An ejector-type system providing for recovery of pressure from 12 Torr to atmospheric pressure in the gas-dynamic system of an HF/DF laser of several-tens-kilowatt power is developed. Matching conditions for parameters of individual PRS components as well as joint functioning of the PRS with a continuous chemical laser in an integral complex are analysed. Conditions for minimization of mass-dimensional characteristics of the laser-PRS complex necessary for the development of ground-based mobile systems are identified.     

Voltage ‐ Current Study of an Atmospheric Dielectric Barrier Discharge

The discharge behaviour of an atmospheric dielectric barrier parallel plate discharge, used for surface treatment, is studied. Since an uniform plasma is preferable for surface treatment, filaments must be avoided in the discharge. The occurrence of filaments can be detected by measuring the current flowing through the discharge. Current and voltage measurements give an indication of the power consumption by the plasma. The power consumption of the plasma as function of the applied frequency is examined. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Noninterfering optical method of HBT circuit evaluation

The authors report a novel noninterfering and simple approach for evaluation of circuits implemented with AlGaAs/GaAs heterojunction bipolar transistors (HBTs). This method makes use of radiative recombination in the base region of current-carrying HBTs. The infrared radiation emitted is 'visible' to the closed-circuit TV (CCTV) cameras. Therefore, one can view the operation of the HBT circuit under test at normal biases with a TV monitor. This method can be used to determine logic states of gates, as well as collector current of individual HBTs within integrated circuits.<>     

Exploring magnetic properties of ultrathin epitaxial magnetic structures using magneto-optical techniques

We describe magneto-optic Kerr effect studies of ultrathin Fe and Ni films on single crystal surfaces of Ag and Cu. Monolayer Fe films on Ag(100) exhibit the theoretically predicted spin-orbit anisotropy, but also yield some interesting discrepancies between behavior predicted by Kerr effect and by spin-polarized photoemission experiments. Layer-dependent studies of the magnetic moment of Ni on Ag(111) and Ag(100) suggest sp-d hybridization effects quench the first layer magnetic moment on Ag(111) but not on Ag(100). Temperature dependent studies of thin film magnetization obtained from Kerr effect measurements yield thickness dependent Curie temperatures, and critical exponents for several thin film systems.     

Maximal Cluster Sets of L-Analytic Functions Along Arbitrary Curves

Let Ώ be a domain in the N-dimensional real space, let L be an elliptic differential operator, and let (T_n) be a sequence whose members belong to a certain class of operators defined on the space of L-analytic functions on Ώ. This paper establishes the existence of a dense linear manifold of L-analytic functions all of whose nonzero members have maximal cluster sets under the action of every T_n along any curve ending at the boundary of Ώ such that its closure does not contain any component of the boundary. The above class contains all partial differentiation operators ∂^α, hence the statement extends earlier results due to Boivin, Gauthier, and Paramonov, and due to the first, third, and fourth authors.     

Generation of red light at 660 nm by frequency doubling a Nd:YAG laser with periodically-poled stoichiometric LiTaO<Subscript>3</Subscript>

High power red light was generated from a periodically-poled stoichiometric LiTaO₃ (PPSLT) by single-pass frequency doubling of a diode-side-pumped, Q-switched Nd:YAG laser at 1319 nm. An average power of 2.4 W of the 660 nm red light was obtained at the fundamental power of ∼5.4 W with the conversion efficiency up to 44.4% and with low fluctuation down to 2%. The high efficiency and stability at the red output indicate that it is a practical method to construct a reliable compact red laser. PACS 42.70.Mp; 42.79.Nv; 42.55.Xi     

Growth of InAs nanostructures on InP using atomic-force nanolithography

Atomic-force nanolithography was used to control the nucleation sites of InAs nanostructures on InP substrates. Indentations with a wide range of dimensions were produced on InP. InAs nanostructures were selectively grown by metal organic vapor phase epitaxy. It is shown that the number of active nucleation sites depends on the normal force applied during nanoindentation. Crystalline defects introduced by nanoindentation are shown to be nucleation sites for these nanostructures. The presence of screw dislocations within the grown nanostructures further supports this observation. PACS 81.07.-b; 68.37.Ps; 81.16.Nd