首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   225405篇
  免费   2496篇
  国内免费   700篇
化学   107741篇
晶体学   3294篇
力学   7825篇
综合类   4篇
数学   18381篇
物理学   60231篇
无线电   31125篇
  2016年   2511篇
  2015年   1803篇
  2014年   2642篇
  2013年   8325篇
  2012年   5589篇
  2011年   6984篇
  2010年   4954篇
  2009年   5179篇
  2008年   7048篇
  2007年   7541篇
  2006年   7324篇
  2005年   6744篇
  2004年   6179篇
  2003年   5587篇
  2002年   5500篇
  2001年   7038篇
  2000年   5593篇
  1999年   4580篇
  1998年   3804篇
  1997年   3830篇
  1996年   3738篇
  1995年   3464篇
  1994年   3331篇
  1993年   3220篇
  1992年   3717篇
  1991年   3607篇
  1990年   3422篇
  1989年   3446篇
  1988年   3300篇
  1987年   2937篇
  1986年   2757篇
  1985年   3646篇
  1984年   3658篇
  1983年   3071篇
  1982年   3211篇
  1981年   3149篇
  1980年   3013篇
  1979年   3116篇
  1978年   3355篇
  1977年   3146篇
  1976年   3110篇
  1975年   2928篇
  1974年   2874篇
  1973年   2899篇
  1972年   1900篇
  1971年   1608篇
  1968年   2040篇
  1967年   2211篇
  1966年   2018篇
  1965年   1581篇
排序方式: 共有10000条查询结果,搜索用时 894 毫秒
41.
Wireless Personal Communications - Current mobile communications technology relies heavily on efficient design of antennas, where the operational characteristics of the wireless communication...  相似文献   
42.
Exosomes are nanovesicles secreted by most cellular types that carry important biochemical compounds throughout the body with different purposes, playing a preponderant role in cellular communication. Because of their structure, physicochemical properties and stability, recent studies are focusing in their use as nanocarriers for different therapeutic compounds for the treatment of different diseases ranging from cancer to Parkinson's disease. However, current bioseparation protocols and methodologies are selected based on the final exosome application or intended use and present both advantages and disadvantages when compared among them. In this context, this review aims to present the most important technologies available for exosome isolation while discussing their advantages and disadvantages and the possibilities of being combined with other strategies. This is critical since the development of novel exosome‐based therapeutic strategies will be constrained to the effectiveness and yield of the selected downstream purification methodologies for which a thorough understanding of the available technological resources is needed.  相似文献   
43.
Xu  H. J.  Zhang  Q. G.  Debenest  G. 《Transport in Porous Media》2021,140(3):625-627
Transport in Porous Media - The theme of coupling problems for adsorption, absorption and thermochemical transport in porous media is very important for engineering applications. Based on the...  相似文献   
44.
Aliev  A. B.  Shafieva  G. H. 《Differential Equations》2022,58(8):1028-1042
Differential Equations - We study a mixed problem for systems of one-dimensional semilinear hyperbolic equations with variable nonlinearity growth rate and nonlinear boundary conditions. Theorems...  相似文献   
45.
占兴  熊巍  梁国熙 《化学进展》2022,34(11):2503-2516
随着经济的飞速发展,社会对能源的需求日益扩大,对工业废水的无害化处理也提出了更高的要求。光催化燃料电池 (photocatalytic fuel cell, PFC) 在燃料电池中引入半导体光催化材料作为电极,实现了有机污染物高效降解和同步对外产电的双重功能,在废水无害化与资源化利用方面具有潜在的应用价值。半导体光催化电极是PFC系统高效运行的核心组件,增强其可见光响应和光生载流子分离是提高PFC性能的关键策略。反应器结构设计和运行参数优化也有利于改善PFC性能。本文从PFC基本原理和应用入手,综述了PFC在环境污染物资源化处理中的研究进展,并详细阐述了提高PFC的污染控制性能和产电效率的优化手段,为进一步设计高效稳定的PFC系统并实现其在水污染控制和清洁能源生产中的应用提供理论指导。  相似文献   
46.
Monomeric sarcosine oxidase (mSOx) fusion with the silaffin peptide, R5, designed previously for easy protein production in low resource areas, was used in a biosilification process to form an enzyme layer electrode biosensor. mSOx is a low activity enzyme (10–20 U/mg) requiring high amounts of enzyme to obtain an amperometric biosensor signal, in the clinically useful range <1 mM sarcosine, especially since the Km is >10 mM. An amperometric biosensor model was fitted to experimental data to investigate dynamic range. mSOx constructs were designed with 6H (6×histidine) and R5 (silaffin) peptide tags and compared with native mSOx. Glutaraldehyde (GA) cross‐linked proteins retained ~5 % activity for mSOx and mSOx‐6H and only 0.5 % for mSOx‐R5. In contrast R5 catalysed biosilification on (3‐mercaptopropyl) trimethoxysilane (MPTMS) and tetramethyl orthosilicate (TMOS) particles created a ‘self‐immobilisation’ matrix retaining 40 % and 76 % activity respectively. The TMOS matrix produced a thick layer (>500 μm) on a glassy carbon electrode with a mediated current due to sarcosine in the clinical range for sarcosinemia (0–1 mM). The mSOx‐R5 fusion protein was also used to catalyse biosilification in the presence of creatinase and creatininase, entrapping all three enzymes. A mediated GC enzyme linked current was obtained with dynamic range available for creatinine determination of 0.1–2 mM for an enzyme layer ~800 nm.  相似文献   
47.
Saleh  Z. M.  Nasser  H.  Özkol  E.  Günöven  M.  Abak  K.  Canli  S.  Bek  A.  Turan  R. 《Journal of nanoparticle research》2015,17(10):1-12
Journal of Nanoparticle Research - Plasmonic interfaces consisting of silver nanoparticles of different sizes (50–100&;nbsp;nm) have been processed by the self-assembled dewetting...  相似文献   
48.
An innovative volatolomic approach employs the detection of biomarkers present in cerumen (earwax) to identify cattle intoxication by Stryphnodendron rotundifolium Mart., Fabaceae (popularly known as barbatimão). S. rotundifolium is a poisonous plant with the toxic compound undefined and widely distributed throughout the Brazilian territory. Cerumen samples from cattle of two local Brazilian breeds (‘Curraleiro Pé-Duro’ and ‘Pantaneiro’) were collected during an experimental intoxication protocol and analyzed using headspace (HS)/GC–MS followed by multivariate analysis (genetic algorithm for a partial least squares, cluster analysis, and classification and regression trees). A total of 106 volatile organic metabolites were identified in the cerumen samples of bovines. The intoxication by S. rotundifolium influenced the cerumen volatolomic profile of the bovines throughout the intoxication protocol. In this way, it was possible to detect biomarkers for cattle intoxication. Among the biomarkers, 2-octyldecanol and 9-tetradecen-1-ol were able to discriminate all samples between intoxicated and nonintoxicated bovines. The cattle intoxication diagnosis by S. rotundifolium was accomplished by applying the cerumen analysis using HS/GC–MS, in an easy, accurate, and noninvasive way. Thus, the proposed bioanalytical chromatography protocol is a useful tool in veterinary applications to determine this kind of intoxication.  相似文献   
49.
50.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号